Index Catalog // ScholarsArchive@OSU

The preparation and reactions of 1-(2-pyridyl)-3-menthyl-3-butene-2-ol and 1-(2-pyridyl)-4-methyl-3-butene-2-ol

Creator:: Janposri, Sompong
Abstract:: 1-(2-pyridyl)-3-methyl-3-butene-2-ol was prepared by allowing 2-picolyllithium to react with methacrolein. In the reaction of picolyllithium with crotonaldehyde, two products 1-(2-pyridyl)-4-methyl-3-butene-2-ol and 1-(2-pyridyl)-4-methyl-2-butene-4-ol were formed. 1-(2-pyridyl)-3-methyl-3-butene-2-ol was subjected to the low pressure hydrogenation, using methanol as solvent and PtO₂ as catalyst. A red yellow liquid 1-(2-pyridyl)-3-methyl-2-butanol was obtained. Derivatives of the...
Resource Type:: Masters Thesis
Full Text:: THE PREPARA TION AND REACTIONS OF 1 -(2 -PYRIDYL) -3-METHYL-3-BUTENE-Z-OL AND 1-(2-PYRIDYL)-4

Reactions of certain purin-8-ols with phosphorus oxychloride in the presence of N,N-diethylaniline

Creator:: Ladwig, Laurence Gene
Abstract:: The reaction of certain purin-8-ols with phosphorus oxychloride and N,N-diethylaniline are described. 9-Amino-6-chloropurin-8-ol monohydrate reacted with phosphorus oxychloride and N, N-diethylaniline to yield the phosphorus oxychloride adduct. Other purin-8-ols were prepared and the production of analogs similar to the previously mentioned adduct was attempted. 6-Chloropurin-8-ol and 6, 9-diaminopurin-8-ol hydrochloride monohydrate...
Resource Type:: Masters Thesis
Full Text:: and N,N- diethylaniline are described. 9- Amino -6- chloropurin -8 -ol monohydrate reacted with

Oxy-Cope, and Siloxy-Cope rearrangement of cis-1-vinylcyclooct-3-en-1-ol

Creator:: Chin, Alice Wai-lee
Abstract:: Both oxy-Cope and siloxy-Cope rearrangements involve (1, 3) and (3, 3) sigrnatropic shifts. Both the concerted mechanism, and the stepwise mechanism via a diradical intermediate are possible. In a cyclic system such as cis-l-vinylcyclooct-3-en-l-ol, the thermal rearrangement takes place preferably through a diradical intermediate. At high temperature, the reaction also...
Resource Type:: Masters Thesis
Full Text:: -vinylcyclooct-3-en-1-ol AN ABSTRACT OF THE THESIS OF ALICE -WAI LEE CHIN for the M. S. (Name of student

Siloxy-cope rearrangements of the trans-l-vinylcyclotridec-3-en-l-ol system

Creator:: Bolesta, Richard Edward
Abstract:: The thermolysis of trans-1 -trimethylsiloxy- 1-vinylcyclotridec- 3-ene (VI-OTMS) led to the formation of two major products: 4-vinylcyclotridecanone (VII) and cyclopentadec-5-en-l-one (VIII) after hydrolysis. Ketone VII is produced by a concerted [3, 3] sigmatropic shift, while ketone VIII is formed by a [1, 3] sigmatropic shift with a concerted or diradical...
Resource Type:: Masters Thesis
Full Text:: THE TRANS-1- VINYLCYCLOTRIDEC- 3-EN-1- OL SYSTEM Abstract approved: Redacted for privacy Dr. Richard

Synergism of the oriental fruit moth pheromone blend with (E,E)-8,10-dodecadien-1-OL

Creator:: Riedl, Helmut W., Barnett, William W., and Gaggero, J.
Resource Type:: Conference Proceeding
Full Text:: ,E)-8,10-dodecadien-l-ol, on the other hand, had the opposite effect on the pheromone response of OFM

Reactions of 1-phenyl-4-(2-pyridyl)-1-butene-3-ol

Creator:: Pojanagaroon, Pairoje
Resource Type:: Masters Thesis
Full Text:: Reactions of 1-Phenyl-4-(2-Pyridyl)-1-Butene-3-OL. AN

Substituent control in the oxy-Cope rearrangements of 1-vinyl-trans-cyclotridec-3-en-1-ol systems

Creator:: Daruwala, Khushroo Peshotan
Abstract:: The thermal and anionic rearrangements of substituted 1-vinyltrans- cyclotridec-3-en-l-ol compounds have been studied to determine what effects substituents would have on the sigmatropic shift when placed on the two positions of the 1-vinyl group. For the thermal rearrangements, the a-substituted vinyl-trans-cyclotridecenols gave both the [3,3] and [1,3] shift products of...
Resource Type:: Dissertation
Full Text:: -vinyl-trans-cyclotridec-3-en-1-ol systems AN ABSTRACT OF THE THESIS OF Khushroo Peshotan Daruwala for

Responses of males to a pheromone blend of female Oriental fruit moth with and without E8, E10-dodecadien-1-ol, a pheromone component of codling moth (Lepidoptera: Tortricidae)

Creator:: Allred, Darin B.
Abstract:: E8,E10-dodecadien-1-ol, the primary component of the female sex pheromone of codling moth, Cydia pomonella L., has no attraction to male Oriental fruit moth (OFM), C. molesta (Busck). However, this compound when added to the OFM pheromone blend of Z8-dodecenyl acetate (85.5%), E8-dodecenyl acetate (5.5%), and Z8- dodecen -1 -ol (9.0%),...
Resource Type:: Dissertation
Full Text:: Pheromone Blend of Female Oriental Fruit Moth With and Without E8.E10-dodecadien-l-ol. a Pheromone

Composition of flavonoid phenolic polymers isolated from red wine during maceration and significance of flavan-3-ols in foods pertaining to biological activity

Creator:: Aron, Patricia M.
Abstract:: Representing the most common flavonoid consumed in the American diet, the flavanols and their polymeric condensation products, the proanthocyanidins, are regarded as functional ingredients in various beverages, whole and processed foods, herbal remedies and supplements. Their presence in food affects food quality parameters including astringency, bitterness, sourness, sweetness, salivary viscosity,...
Resource Type:: Masters Thesis
Full Text:: status of the C-ring: flavan, flavanone, flavone, flavonol, dihydroflavonol, flavan-3-ol, flavan-4-ol

Siloxy-cope and oxy-cope rearrangements of the cis- and trans-1-vinylcyclodec-3-en-1-ol systems ; Acid-catalyzed rearrangement of cis-bicyclo [6.1.0] nonane-cis- and trans-9-methanols ; An effective two-carbon ring-expansion

Creator:: Billigmeier, James Earl
Resource Type:: Dissertation
Full Text:: trans-1-vinylcyclodec-3-en-1-ol systems ; Acid-catalyzed rearrangement of cis-bicyclo [6.1.0] nonane-cis

ScholarsArchive@OSU

The preparation and reactions of 1-(2-pyridyl)-3-menthyl-3-butene-2-ol and 1-(2-pyridyl)-4-methyl-3-butene-2-ol

Reactions of certain purin-8-ols with phosphorus oxychloride in the presence of N,N-diethylaniline

Oxy-Cope, and Siloxy-Cope rearrangement of cis-1-vinylcyclooct-3-en-1-ol

Siloxy-cope rearrangements of the trans-l-vinylcyclotridec-3-en-l-ol system

Synergism of the oriental fruit moth pheromone blend with (E,E)-8,10-dodecadien-1-OL

Reactions of 1-phenyl-4-(2-pyridyl)-1-butene-3-ol

Substituent control in the oxy-Cope rearrangements of 1-vinyl-trans-cyclotridec-3-en-1-ol systems

Responses of males to a pheromone blend of female Oriental fruit moth with and without E8, E10-dodecadien-1-ol, a pheromone component of codling moth (Lepidoptera: Tortricidae)

Composition of flavonoid phenolic polymers isolated from red wine during maceration and significance of flavan-3-ols in foods pertaining to biological activity

Siloxy-cope and oxy-cope rearrangements of the cis- and trans-1-vinylcyclodec-3-en-1-ol systems ; Acid-catalyzed rearrangement of cis-bicyclo [6.1.0] nonane-cis- and trans-9-methanols ; An effective two-carbon ring-expansion

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