Semi-volatile trace metals (e.g., Cd, Sn, Pb, Zn, Cu, Mo) have been analyzed by using laser ablation ICP-MS in a number of silicate glasses (GSE-1G, GSD-1G, NIST 610, NIST 612, BCR-2G, BHVO-2G). Our work investigates and highlights sources of uncertainty in the analysis of semi-volatile metals using LA-ICP-MS. We identify...
A simplified model of the combined particle convective and
radiative components of heat transfer between large-particle gas-fluidized
beds and immersed surfaces was developed. This analytical
model was based on the single particle formulation of Adams and Welty
[4,9], with the added assumptions of one-dimensional heat conduction
in the particle and...
An analytical model of the radiative contribution to the
total heat transfer between a large-particle (greater
than 1 mm) gas-fluidized bed and an immersed horizontal
tube is discussed. The model is applied to the case of a
bubbling bed and the emulsion phase contribution is obtained from a detailed analysis...
Supervolcanic eruptions are among the most catastrophic phenomena on Earth,
erupting 100s-1000s of cubic kilometers of magma, and producing devastating local effects and global climate perturbations. The largest supervolcanic eruption of the last 28 Ma was the 74 ka Youngest Toba Tuff (YTT) eruption from Sumatra, Indonesia, which erupted 2,800...
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Adam J.R. Kent
Supervolcanic eruptions are among the most catastrophic phenomena on
The spatial and dynamic pattern of landscape changes has a profound effect on the supply of environmental services, including the provision of habitat for fish and wildlife. Spatial heterogeneity is a common feature of landscapes in the Pacific Northwest, most notably in areas important to the production of salmonid fish...
Two distinct strategies were explored for the enantioselective synthesis of α-heteroatom substituted alkyl boronic esters by stereoselective reagent-controlled homologation using transient chiral carbenoid reagents CHYMX (Y = heteroatom, X = nucleofuge, M = electrofuge). In the first case, a stereospecific reagent-controlled homologation (sStReCH) approach to α-alkoxyalkylboronates using α-metalated S,O- and...
A direct numerical simulation of advection-diffusion in a sinusoidal tube was
carried out using the commercial finite-volume code STAR-CD. The Reynolds
numbers varied from Re = 0.1 to Re = 14.5. At the larger Reynolds numbers,
steady-state eddies formed in the diverging sections and significantly influenced
the macroscale dispersion. Long...
Over 54 million people report having disabilities in the United States. In addition, there are 40.3 million people 65 years and older living in America. As the population continues to live longer and problems with obesity continue to increase, the number of people with limited capabilities will escalate as well....