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Creator:: Kirkpatrick, Robynne
Abstract:: Interesting rovibrational characteristics of two D_(3h) oblate symmetric top molecules were studied. Hamiltonian models for the fine rovibrational level structure of [1.1.1]propellane (propellane) were obtained for many low-lying modes. Ground state parameters (GSP) that are not exclusively K^(2n) dependent were obtained. Initially, the GSP were used in conjunction with density...
Resource Type:: Dissertation
Full Text:: Robynne Kirkpatrick for the degree of Doctor of Philosophy in Chemistry presented October 15, 2010

Creator:: Kirkpatrick, Robynne, Masiello, Tony, Martin, Matthew, Nibler, Joseph W., Maki, Arthur, Weber, Alfons, and Blake, Thomas A.
Abstract:: This paper is a continuation of earlier work in which the high resolution infrared spectrum of [1.1.1]propellane was measured and its k and l structure resolved for the first time. Here we present results from an analysis of more than 16,000 transitions involving three fundamental bands v₁₀ (E' - A'₁),...
Resource Type:: Article
Full Text:: , and m18 levels of [1.1.1]propellane Robynne Kirkpatrick a, Tony Masiello b, Matthew Martin a, Joseph

Creator:: Martin, Matthew A.
Abstract:: The strained carbon ring, bicyclo[1.1.1]pentane, was synthesized by a reaction between 1-(phenylsulfanyl)bicyclo[1.1.1]pentane, prepared from propellane, and Raney nickel. Infrared spectra were recorded at a resolution of 0.0015 cm-1, a resolution significantly better than previous measurements, 0.06 cm-1. A single fundamental band was analyzed to determine the ground state and excited...
Resource Type:: Honors College Thesis
Full Text:: the synthetic work, Robynne Kirkpatrick for her guidance on the poster and writing, and everyone who

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