Lycopodium alkaloids have generated enormous amounts of interest from the scientific community, both as synthetic targets and for their medicinal properties. Herein is described work towards a unifying approach to large segments of the Lycopodium family. An organocatalyzed intramolecular heteroatom Michael reaction method, for the construction of piperidine and piperizine...
Effective methods for the enantiopure formation of substituted piperidine rings are significantly important due to their presence in alkaloid products. A valuable method to form these ring systems would be via an intramolecular heteroatom Michael addition from the corresponding enone or enal. Described herein is a methodolgy that has been...
On February 9th, 2014 Michael Sam stated in an interview with ESPN's "Outside the Lines" that he is gay. Since he was drafted, Sam will become the first ever openly gay player in NFL history. The following study aims to explore ESPN's coverage of Michael Sam, with a goal of...
The collapse of the I-35W Bridge in Minneapolis, MN in 2007 prompted an investigation into the design and inspection of the steel truss bridges. Further investigation into the collapse revealed that a gusset plate experienced sway buckling, causing the bridge failure. This bridge failure motivated research into the analysis and...
The fact that measuring a quantum system reduces it to apparently classical behavior, eliminating the interference patterns that are a hallmark of quantumness, cries out for an explanation. That explanation has been provided by the recognition of decoherence,whereby the interference is destroyed by the very interaction that acquires information.We begin...
This research addresses the perception of leadership attributes in light of evaluator and target gender. It specifically investigates whether there is a difference in language usage when the evaluator is female versus when the evaluator is male. Two studies were conducted. A pre-test used instrumental development drawing from studies conducted...
Potato varieties characterized by non-conventional skin and flesh colors (purple, red, yellow) have the potential to revitalize consumer demand for fresh market potatoes because of their unique appearance and health benefits. Red and purple potatoes contain anthocyanins, which are flavonoids responsible for red, blue, and purple pigments in plants. Yellow...
Rockfish Conservation Areas (RCAs) are large areas closed to fishing in federal waters off the Washington, Oregon and California coasts. The Pacific Fisheries Management Council (PFMC) was responsible for the creation and regulation of the RCAs. The RCA boundaries were defined in 2002 to rebuild rockfish species declared as overfished...
Cereal and commercial grass-seed straws are abundant plant biomass materials that are currently being considered for application in industrial processes aimed at the production of biofuels, biomaterials, and biochemicals. The carbohydrate fraction of these straws is of particular interest in this context due to its chemical functionality and relative ease...
The bi-directional relationships within the personal and contextual environments of adolescents are critical to the development of adolescents and their transition into adulthood. Opportunities for youth to participate in and provide leadership in meaningful programs, gain life skills, and interact with adults in sustained relationships are key features leading to...