Lycopodium alkaloids have generated enormous amounts of interest from the scientific community, both as synthetic targets and for their medicinal properties. Herein is described work towards a unifying approach to large segments of the Lycopodium family. An organocatalyzed intramolecular heteroatom Michael reaction method, for the construction of piperidine and piperizine...
Effective methods for the enantiopure formation of substituted piperidine rings are significantly important due to their presence in alkaloid products. A valuable method to form these ring systems would be via an intramolecular heteroatom Michael addition from the corresponding enone or enal. Described herein is a methodolgy that has been...
Releasing hatchery reared salmon and steelhead to supplement threatened and endangered populations is a widely used conservation tool. One issue with this strategy is hatchery fish have lower reproductive fitness than wild fish when spawning in the wild. One of the drivers of fitness loss in steelhead is adaptation to...
At its inception in 1946, the United States’ National School Lunch Program (NSLP) was promoted as a success story; a boon for families navigating poverty, a means of buoying food prices by absorbing farm surplus, and a treatment for hunger in some of our country’s most vulnerable populations. Government subsidies...
On September 12th 1960, just two months prior to one of the closest
Presidential elections in American history, John F. Kennedy faced the Houston
Ministerial Association and delivered a powerful speech on religion and
Americanism. The "religious issue" of the 1960 campaign drew immense interest
and trumped other issues pertinent...
Carboxylic acids have played an important role in the field of actinide (An) and lanthanide (Ln) separations and the reprocessing of irradiated nuclear fuel. Recent bench-scale experiments have demonstrated that 3-carboxy-3-hydroxypentanedioic acid (citric acid) is a promising aqueous complexant that can effectively aid in the separation of transition metals from...
Contamination events at Oak Creek, which runs through Oregon State University Research lands, prompted investigations into alternate transport mechanisms for moving liquid effluent from OSU Diary lands to Oak Creek. Magnetometer surveys conducted at the Diary identified magnetic signatures spatially associated with sub-surface locations of drain tiles, a 12-inch pipe,...
We monitored larval Lost River and shortnose suckers from natal beds in the Williamson and Sprague rivers to nursery grounds in Upper Klamath Lake. Downstream movements occurred at night, in the middle of the channel, and on the falling limb of the hydrograph. Ages, sizes, and developmental stages of larvae...
How complex traits evolve continues to be a major focus of evolutionary
investigation. A current topic of debate is the hypothesis that the phenotypic
integration of complex traits gives rise to evolutionary constraints. I studied two color
traits in the common garter snake, Thamnophis sirtalis, that show a high level...
Marine sediments are one of the largest habitats for microbial life on earth. These microorganisms play critical roles in biogeochemical cycling both within the subsurface and between the sediment and water columns. However, microbial communities in sediments are highly heterogeneous and the factors defining microbial community structure and metabolic function...