To obtain a mechanistic understanding of the chemical processes, techniques that offer a frame-by-frame visualization of molecular structure during a reaction are of vital importance. Numerous efforts and advances have been made in order to acquire such vivid molecular “movies”, especially in the electronic excited state. Ultrafast molecular spectroscopy method...
The specific objectives of this dissertation are to determine subsurface flow
behaviors across different antecedent wetness conditions from a top-down perspective
and to mechanistically assess the hydrological controls on DOC and N transport at the
hillslope and catchment scale. The study area is a small catchment where hillslopes
issue directly...
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4.3.5. End member mixing analysis (EMMA) ............................................109
4.4
The development of a transient electric birefringence (TEB) apparatus for macroparticle characterization is herein discussed. The experimental difficulties encountered were related largely to poor data resolution. Misalignment and strain birefringence in optical components further complicated results. Improved data digitization methods were developed, and precise mathematical models were derived in order...
New transparent p- and n-type semiconductors and luminescent materials have been prepared and characterized. Synthesis, structures, optical and electrical properties of new chalcogenide fluoride p-type transparent semiconductors MCuQF (M=Ba, Sr; Q=S, Se, Te) are described. Band-gap tuning and improvement in conductivity through p-type doping are demonstrated in the family. The...
Turbulent flows over rough surfaces are encountered in many engineering and geophysical applications. Flows of this nature, due to their increasing technological interests, have been a subject of rigorous investigation in recent years. Of the particular interest to the oceanographic community is the study of turbulent oscillatory flow over rough...
Aromatic hydrocarbons represent a large class of environmental contaminants that have a broad range of structures, physicochemical properties, and toxicities. Arising from the burning of organic matter, particularly fossil fuels, they are both widespread and abundant in all environmental compartments. Both monoaromatic hydrocarbons (BTEX) and polycyclic aromatic hydrocarbons (PAHs) are...
Since 2007, electronic cigarette (e-cigarette) sales in the U.S. have surpassed those of tobacco cigarettes. This is due, in part, to manufacturer’s claims that they are a safer alternative to tobacco cigarettes. However, formaldehyde, acrolein, and diacetyl have been detected in e-cigarettes and public knowledge of e-cigarette composition and potential...
Small mountainous watersheds are disproportionate sources of land-derived particulate organic matter (POM) to long-term sinks like lake bottoms and the ocean. As such, these ecosystems are an essential component of the global carbon cycle. The burial of POM in lacustrine and marine sediments contributes to the drawdown of atmospheric CO2...
Humpback whales (Megaptera novaeangliae) are vocal baleen whales that exhibit complex social interactions that vary spatially and seasonally. Across their range, humpback whales produce a wide array of vocalizations including ‘song’, foraging vocalizations, and a range of vocalizations known as social calls -- unclassified non-song vocalizations. This study investigates the...
Humpback whales (Megaptera novaeangliae) are a widely distributed baleen whale species, well known for their diverse acoustic behavior. On high-latitude foraging grounds, humpback whales produce a suite of non-song vocalizations (“calls”) in concert with foraging and social behavior. In this dissertation I investigated the role of calls in the acoustic...