The knowledge about the intensive agricultural irrigation is very limited, but the use of irrigation is rapidly increasing. As an outcome, the sympathetic ecosystem is accepting modern irrigation that will play an essential function in the present and future for agricultural products. My dissertation will display the modification for investigation...
This dissertation is separated into two parts according to the two major distinct research projects. In Part I, the full account of synthetic studies toward C10-functionalized lycopodium alkaloids is described. In Part II, the detailed discussion on the exploration of the Pummerer cyclization methodology and its application to the total...
Background. As part of the nationwide student completion agenda, the Achieving the Dream (ATD) national reform network was established to help community colleges quickly institute sustainable change scaled to impact all students at the institution in a short period of time. Although ATD has been in existence for over a...
Femtosecond stimulated Raman spectroscopy (FSRS) is an ultrafast vibrational technique which allows rapid collection of Raman spectra with simultaneously high temporal and spectral resolution. With the recent development of FSRS methodology, three FSRS techniques (conventional, tunable, and anti-Stokes) have been implemented in our laboratory to dissect the excited state structural...
Polycyclic aromatic hydrocarbons (PAHs) are widespread environmental contaminants that occur in complex mixtures. These environmental mixtures can consist of both parent PAHs and their derivatives. Several parent PAHs are known or suspected mutagens and/or carcinogens, and a handful of PAH derivatives are known to be more potent mutagens and/or carcinogens...
Relationship health has many benefits, from physical and emotional health of the partners to their children’s wellbeing. Early intervention programs protect relationships from decline. These programs represent growing public health initiatives. However, most studies on wellness or early intervention overlook lesbian and gay male couples. Research that assumes lesbian and...
Novel donor-typed ternary graphite intercalation compounds (GICs) are synthesized and characterized containing (1) pyrrolidinium cations with DMSO co-intercalates; (2) alkali metal cations with crown ether co-intercalates; and (3) alkali metal cations with polyethylene glycol co-intercalates. Structural and compositional data are obtained for the stable products. A new ether-amine co-intercalate exchange...
In this work we will analyze branching Brownian motion on a finite interval with oneabsorbing and one reflecting boundary, having constant drift rate toward the absorbingboundary. Similar processes have been considered by Kesten ([12]), and more recently byHarris, Hesse, and Kyprianou ([11]). The current offering is motivated largely by the...
Background: Prior research has shown that distance learning courses have higher failure rates at community colleges then equivalent face-to-face to courses. There are a few programs and courses, however, that consistently achieve completion rates as high as or higher than their equivalent face-to-face courses. The research to date has not...
Significant progress has been made over the past 20 years in developing models to estimate the service-life of reinforced concrete systems. The basic understandings of the mechanisms that control the transport of ions and moisture in concrete systems have been well researched and models for determining corrosion initiation, specifically chloride-induced...
Background: The United States has been under-producing college graduates since at least 1980, with many challenges suppressing students’ self-efficacy. One approach to improving student outcomes is through mentorship. This dissertation applied Bandura’s Social Cognitive Theory (SCT) and Kram’s Mentor Relationship Development Theory (MRD) to discover whether students’ campus mentorship experiences...
The first part of this manuscript is about the total synthesis of the Arundo donax bis(indole) natural products. The A. donax alkaloids were prepared using the first example of an ynindole Diels–Alder reaction. Each were then separated, isolated, and determined to have stable enantiomeric conformations at room temperature (Chen, J.;...
This work is a culmination of a series of published works related to the use of the Material Point Method (MPM) in modeling wood adhesive bonds. The use of wood as construction material has the potential to play a small role in the solution to the current CO2 and climate...
A significant number of Unreinforced Masonry (URM) buildings exist in the Pacific Northwest region of the United States of America that is a region of high seismicity, which could be subjected to both crustal and subduction zone earthquakes. The catastrophic and brittle failures associated with URM buildings in the past...
Atomically-thin graphene sheets have unprecedented characteristics for biosensing applications. These characteristics include mechanical flexibility and strength, optical transparency, electrical sensitivity and biocompatibility. The primary theme of this dissertation is the characterization and application of graphene field-effect transistors (FETs) in biologically-relevant physiological environments.Understanding the interface that forms between an electrolyte and...
Transportation systems are facing safety and operational challenges with a cost of billions of dollars annually in lost production time and wasted fuel. Infrastructure expansion, previously held as a panacea to most transportation challenges has lost its appeal due to financial, land-use and environmental constraints. Interest is surging in intelligent...
The electrical stability of amorphous indium-gallium-zinc oxide (a-IGZO) thinfilmtransistors (TFTs) is investigated for flat-panel display applications. Althoughproducts incorporating a-IGZO TFT backplanes are already commercially available,e.g., iMac with 5K retina display, technical challenges need to be addressed for nextgenerationapplications, e.g., active-matrix organic light-emitting diode displays.Device stability is one crucial issue. The...
The role of ground motion duration on the seismic performance of civil engineering structures remains unclear. Thus, the role of earthquake strong ground motion duration is assessed in a three manuscript thesis, which includes: (1) assessment of the effects of ground motion duration on the seismic performance of a model...
Electrochemical capacitors and batteries are two major electrochemical energy storage technologies, which have been investigated extensively to meet the rapidly-growing demand for higher energy, higher power, lower cost and enhanced safety in the past few decades. With the charge storage mechanism of electrostatic charge adsorption desorption via electrical double layers,...
Biological invasions and climate change represent two preeminent threats to ecological communities and biodiversity, altering the distribution and abundance of species, disrupting existing species interactions and forming unprecedented ones, and creating novel ecological communities. Many of the most successful invasive species are also ecosystem engineers, species that physically modify the...
Physical experimentation in various scientific and engineering areas continues to be a useful and often necessary approach that is applied in research, development, and for general problem solving. The experimental design process however, is iterative and often involves trial and error. Alternative designs are proposed and evaluated on cost and...
Sepsis is an inflammatory reaction occurring throughout the human body to infections caused by bacteria, fungi, and or other forms of pathogens. It is essential to find an alternative treatment method for sepsis, to lessen the dependence on antibiotics. Hemoperfusion is an absorbent device that removes select targets from blood,...
Small Unmanned Aircraft Systems (sUASs) equipped with optical sensors are capableof remotely sensing landscapes and wildlife at spatial and temporal resolutions that werepreviously inaccessible due to technical and budgetary limitations. Conventional remotesensing and photogrammetric workflows can be applied to the resulting high resolution imageryto facilitate new types of scientific inquiry....
The Comprehensive Nuclear-Test-Ban Treaty (CTBT) bans all nuclear explosion tests for military or civilian purposes. The International Monitoring System (IMS) was established to verify compliance with the treaty. It consists of several monitoring stations that detect: seismic activities, hydrocoustic activities, infrasound waves, and radionuclide particles and noble gases. Radioxenon detection...
Polycyclic aromatic hydrocarbons (PAHs) are a group of environmental contaminants consisting of fused benzene rings. Parent-PAHs, methylated-PAHs (MPAHs), and PAHs with molecular weight of 302 a.m.u (MW302-PAHs) are considered as unsubstituted-PAHs. These unsubstituted-PAHs undergo transformation reactions resulting in the formation of PAH-transformation products (PAH-TPs), or substituted-PAHs, including nitrated-, oxygenated-, and...
For spatial data visualization, we approach two problems and provide solutions: heat map resolution selection, and heat map confidence interval presentation. Analysts often present spatial data in gridded heat maps, at some chosen resolution. However, many data types vary in density across the domain. We develop variable-resolution heat maps to...
The photophysical properties of two-dimensional (2D) layered van der Waals (vdW) materials, and their heterostructures are manifestly distinct from crystalline bulk materials. Recently, the discovery of new 2D vdW materials and strongly-bound interlayer excitons in these materials has created a new branch in nanoscience. As such, there are a number...
Lilacs are a group of ornamental trees and shrubs in the Oleaceae family consisting of 22 to 30 species. There are six series within genus Syringa: Pubescentes, Villosae, Ligustrae, Ligustrina, Pinnatifoliae, and Syringa. Fertility and cross-compatibility among cultivars, species, and series have yet to be formally investigated. Over three years,...
Turbines at wind projects pose a threat to birds and bats flying at altitudes within the rotor swept area. These animals die from colliding with the turbine blades. Estimating mortality, or the total number of bird or bat fatalities at a wind project, is critical to understanding environmental impacts of...
The number of women in doctoral programs is increasing each year and women now comprise the majority of doctoral students in America (U.S. Department of Education, 2015). Previous research has shown the high levels of complexities and stresses that female doctoral students face during their studies (Mallinckrodt & Leong,1992) and...
Mathematical modeling plays a pivotal role in understanding the mechanism of radiation-induced cellular effects, and also in quantifying the radiation risk to the cell. However, there are still compelling challenges facing the conventional modeling in radiobiology, such as lacking a generalized theory structure of quantifying target effect and non-target effect...
This thesis is separated into three distinct projects. First, synthetic studies towards the furanosteroid viridin shown in part I. Second, synthetic studies towards the diperene obtusanal shown in part II. Third, the analysis, characterization, and synthesis of coronene derivatives towards their application in organic batteries shown in part III. Significant...
Missing data is one of the major methodological problems in longitudinal studies. It not only reduces the sample size, but also can result in biased estimation and inference. It is crucial to correctly understand the missing mechanism and appropriately incorporate it into the estimation and inference procedures. Traditional methods, such...
This dissertation works towards determining the mechanisms driving the Mo isotopic composition of soils, and how these signals may be used to refine the use of Mo as a proxy of biogeochemical processes. The first step towards quantifying Mo fractionation in soils is to determine the mechanisms controlling Mo accumulation,...
Markov chains have long been used to sample from probability distributions and simulate dynamical systems. In both cases we would like to know how long it takes for the chain's distribution to converge to within varepsilon of the stationary distribution in total variation distance; the answer to this is, called...
The trend towards higher resolution, faster refresh rate active-matrix liquid-crystal displays (AMLCDs) as well as the emergence of active-matrix organic light-emitting diode (AMOLED) displays is driving the demand for amorphous oxide semiconductor thin-film transistors (AOS TFTs) with higher mobility. A physics-based model for carrier transport in an amorphous semiconductor is...
Counselor educators have a responsibility to serve as effective gatekeepers to the counseling profession by graduating only those counselors professionally prepared to serve the public in a myriad of counseling roles. However, despite its importance and the extant literature, gatekeeping still seems poorly understood and inconsistently applied. Although the literature...
Traditional analysis in population genetics evaluates differences among groups of individuals and, in some cases, considers the effects of distance or potential barriers to gene flow. However, many forces may shape genetic variation of organisms in riverine systems. Similarly complex research linking habitat heterogeneity and configuration to genetic structure has...
Soft keyboards come in different shapes, sizes, and layouts. Each layout is designed to help the users in different inputting tasks. Most of these layouts, however, focus on general text entry as opposed to computer programs. This dissertation addresses the problems with current input mechanisms on touchscreen devices. The dissertation...
The Columbia River delivers the greatest amount of freshwater to the coastal ocean along the U.S. Pacific coast. This freshwater forms the Columbia River plume, a mesoscale plume with significant implications on coastal ocean physical, biological, chemical, and geological processes. The plume is transported south and offshore during the upwelling...
In the U.S., childhood overweight and obesity has grown to epidemic levels. The National Survey of Children’s Health (NSCH) found that nationwide, approximately 32% of children 10–17 years old are identified as overweight, over half of them (nearly 17%) are obese. This is a concern because these rates continue to...
The contribution of delayed adaptive reiteration to crown maintenance was explored across a wide range of adjacent open space conditions in early-mature (approximately 60 year old) Douglas-fir located on the eastern slope of Oregon’s Coast Range. The stands had experienced uniform thinning in 1964-65 and 1980-81 to release dominant and...
Tropical peatlands play an important role in global climate system by storing an immense of carbon that had been accumulated over thousands of years. Peatlands provide another important ecosystem service by regulating the hydrology. It is believed that peatlands act like a giant sponge by absorbing substantial amounts of water...
This dissertation seeks to understand Yi farmers’ livelihoods in the midst of an agricultural transition in Yunnan, Southwest China. This dissertation examines a community’s traditional knowledge related to wild edible plants (WEPs), analyzes socio-ecological vulnerability and resilience in the face of agricultural transition from subsistence farming to cash cropping, and...
Life on Earth intimately depends on the function of countless proteins. For the majority of studied proteins, function absolutely depends on conformation (i.e. 3-dimensional shape in solution). The exact nature of how a protein goes from an unfolded linear polypeptide chain to an organized folded molecule is still not known,...
Pyroprocessing is an advanced technology for recycling used nuclear fuel. Pyrochemical processes encompass a wide range of chemical, physical, and electrochemical methods to partition fission products and other components from used nuclear fuel, which allows for the reuse of the actinides in nuclear fuel. This dissertation investigates two chemical systems...
Most of today’s Internet of Things (IoT) applications assume that data will be moved offdevices into centralized cloud platforms. While existing IoT systems leverage cloud-based analytics for meaningful data reasoning, the assumption that data should always be moved off the devices is problematic. The amount of data to be moved...
This dissertation presents a different approach to understanding how amphibians are responding to disease through ontogeny. Although numerous efforts have been conducted to understand host responses to the fungus Batrachochytrium dendrobatidis (Bd), studies have been restricted to distinct developmental stages. This dissertation provides information on host response to Bd across...
In the study of any developmental process, whether in plants, animals, or other models, it is prudent to consider the developmental position of the subjects being measured. This is generally not taken into consideration in grapevine studies despite a growing body of literature documenting that fruits within clusters develop and...
Nitric oxide (NO) is a signaling molecule that regulates blood pressure and vascular tone. Humans produce NO by endothelial nitric oxide synthase (eNOS), which is impaired in patients with cardiovascular disease leading to increased blood pressure, endothelial dysfunction, and an increased risk of adverse cardiovascular outcomes. Maintaining optimal levels of...