Many important policy problems entail linkages among multiple economic sectors, and require the use of a general equilibrium economic modeling framework. This economic approach is appropriate when the market for any one good or service is linked to numerous other goods and services, and back to fundamental inputs such as...
Simultaneous translation, which translates concurrently with the source language speech, is widely used in many scenarios including multilateral organizations. However, it is well known to be one of the most challenging tasks for humans due to the simultaneous perception and production in two languages. On the other hand, simultaneous translation...
For mmWave Integrated Circuit (IC) design, co-integration of passives can reduce size and power consumption, increase reliability, and reduce overall cost. However, skin and proximity effects in the metallization are aggravated at mmWave frequencies, resulting in increased attenuation and degradation of overall performance. Furthermore, tight integration of passive components (to...
There are growing interests in designing polynomial-time approximation schemes (PTAS) for optimization problems in planar graphs. Many NP-hard problems are shown to admit PTAS in planar graphs in the last decade, including Steiner tree, Steiner forest, two- edge-connected subgraphs and so on. We follow this research line and study several...
The level of reactive oxygen species (ROS) is tightly regulated in biological systems as overproduction can lead to oxidative stress and result in a number of diseases. Due to its negative effects, antioxidants are studied and used against ROS in medicine, pharmaceuticals and therapeutics. Because of issues with the uptake...
In this dissertation, multi-rate array (MRA) architecture and its synthesis are proposed
and developed. Using multi-coordinate systems (MCS), a unified theory for mapping
algorithms from their original algorithmic specifications onto multi-rate arrays is
developed.
A multi-rate array is a grid of processors in which each interconnection may have its
own...
Pseudomonas butanovora, Mycobacterium vaccae, and Nocardioides sp. CF8 utilize distinctly different butane monooxygenases (BMOs) to initiate degradation of recalcitrant chlorinated ethenes (CEs) that pollute aquifers and soils. BMO-dependent degradation of CEs such as trichloroethylene (TCE) can lead to cellular toxicities. The type and severity of TCE transformation-dependent damage can have...
A molecular approach to metal oxides allows to the study to fundamental bonding and formation behavior for such metals. Moreover, the molecular nature of such oxides or metal-oxo clusters allows the possibility of exploitation of the properties of the parent oxides. The tetravalent metals, in specific, (M=Zr, Hf, Ce, Th,...
There has been a tremendous growth in interest in carbon nanodots (C-dots) in the past several years. As a nascent nanomaterial, C-dots have shown great promise in applications that benefit from their superior water dispersibility, low toxicity, non-blinking fluorescent output, chemical and biological compatibility, ease of functionalization and resistance to...
Investigating the structure-property relationships of solid state materials can help improve many of the materials we use each day in life. It can also lead to the discovery of materials with interesting and unforeseen properties. In this work the structure property relationships of newly discovered layered oxypnictide phases are presented...
During the Canterbury Earthquake Sequence (CES) in Christchurch, NZ, an estimated $15B in damages occurred due to liquefaction-induced phenomena, illustrating the importance of understanding site-specific responses to seismic ground motions, as well the importance of accurately predicting liquefaction severity. One potential method for improving the understanding of how a site...
Porphyry Cu-(Au-Mo) deposits are critical sources of several economically important metals. The processes governing the total metal endowment and relative proportions of ore metals at these large magmatic-hydrothermal deposits remain uncertain. The Sulphurets porphyry district, in northwestern British Columbia, Canada, contains four porphyry Au-Cu-Mo deposits that each feature distinct Cu/Au...
Analytical chemistry is an area of chemistry primarily focused on the study and use of instruments for separation, identification, and quantification of an analyte of interest. Specifically, separation science within analytical chemistry often refers to the process of dividing mixtures into their small component parts based on differences in their...
Widespread installation of renewable energy sources, such as wind and solar, has been delayed by the lack of suitable stationary energy storage solutions. Current large-scale technologies, such as pumped hydro and compressed air, are geographically restricted. This is where electrochemical energy storage - batteries or hybrid capacitors can play a...
The design of a switched capacitor successive approximation A/D converter is discussed in this thesis. This design adopts a novel capacitance mismatch error cancellation algorithm proposed in references [25, 27]. Detailed charge domain analysis is given in this thesis, which results in an improvement of the proposed algorithm by tracing...
Autonomous robotic agents are on their way to becoming in-home personal assistants, construction assistants, and warehouse workers. The degree of autonomy of such systems is reflected by the manner in which we specify goals to them; the abstraction of low-level commands to high-level goals goes hand-in-hand with increased autonomy. In...
Over the past several years, increases in the Supplemental Nutrition Assistance Program (SNAP) have coincided with the 2007-2008 recession and the higher rates of unemployment in the U.S. With SNAP being the largest program, in terms of spending embedded in the farm bill, it is likely to see some spending...
This thesis investigates the influence of early diagenesis on trace metal and
molybdenum isotope behavior in marine and lacustrine environments. Chapter one is a
synthesis of previous research in all the marine environments investigated, providing an
essential geochemical context for interpreting the observed behavior of Mo in these settings.
Chapter...
A Cu/Fe-spinel-based oxygen carrier designed at the National Energy Technology Laboratory was studied in order to characterize its physical and chemical behavior with cyclic oxidation and reduction treatments at 800°C for applications in chemical looping combustions. Observations were made on individual particles of the oxygen carrier in-situ using a confocal...
The objective of this dissertation is to enhance the monitoring of forest ecosystems through the utilization of remotely sensed data to address the exigencies posed by the Anthropocene. On a global scale, rising temperatures and fluctuating precipitation patterns have strained forests and produced shifts in natural disturbance regimes. Additionally, the...
Humanities have been craving more freedom and conveniences in whatever form. Carriages evolved to cars and ultimately to aircraft so that one can reach any place in the globe within a day. The mobile phone has enabled people to make a phone call without a need to find a phone...
Rhizopus microsporus is a globally ubiquitous opportunistic human and plant pathogen that is known to harbor endosymbiotic bacteria. Differences between populations of clinical and environmental R. microsporus isolates have yet to be assessed on a global scale. Whole-genome sequence data were used to explore fungal biology and to assess potential...
Anaerobic ammonium oxidation (anammox) has recently appeared as a promising approach for removing nitrogen from landfill leachates because it requires less oxygen and no organic carbon compared to traditional nitrification-denitrification system, and it produces low sludge volumes, thereby reducing operating and biological sludge disposal costs by over 60%. Anammox bacteria...
As the link between human microbiomes and health has become more established, the interest in applying statistical approaches to microbiome data to understand the mechanisms behind these links has grown. However, microbiome data is often of unmanageable size, and consequently, producing quality lower dimensional representations of samples is a significant...
Anammox (anaerobic ammonium oxidation) bacteria are capable of providing low-cost nitrogen removal for numerous types of wastewaters. However, low growth rates cause long startup-times and inhibition by oxygen and metabolic substrates necessitate close process control to maintain performance. Incorporation of Simultaneous Anammox and Denitrification (SAD) into constructed wetlands could provide...
We describe a series of novel computational models, CERENKOV (Computational Elucidation of the REgulatory NonKOding Variome) and its successors CERENKOV2, CERENKOV3, and Convolutional CERENKOV3, for discriminating regulatory single nucleotide polymorphisms (rSNPs) from non-regulatory SNPs within non-coding genetic loci. The CERENKOV models are designed for recognizing rSNPs in the context of...
Novel donor-type graphite intercalation compounds (GICs) containing tetra-n-alkylammonium (TAA) cations have been synthesized by using both ion-exchange and electrochemical methods. Structural and compositional data of the resulting TAA-GICs are investigated by using powder X-ray diffraction (PXRD), one-dimensional electron density calculations, thermogravimetric and elemental analyses, and capillary zone electrophoresis (CZE). A...
The intriguing size- and shape dependent properties of nanoparticles have garnered recent attention in many science and engineering areas. When the particle size is in the nanometer size range, the material exhibits very different properties such as surface plasmon resonance (of gold nanoparticles) and superparamagnetism (of iron oxide nanoparticles). The...
The increase in the demand for energy is estimated to be 28 TW by a year of 2050, which is twice of the energy produced in 2010, in response to the unprecedented growth of the global population. Current energy market is heavily relying on the fossil fuel, which brings the...
Hyporheic Exchange Flow (HEF) is driven by head gradients defined by the hydro-topography of the stream surface, which is controlled by the particular geomorphology of the stream. We quantified the impact of large wood, which typically exerts a strong control on stream morphology, on HEF in a second order, low...
Deep learning is becoming the latest trend in sensitive applications, such as healthcare, criminal justice, and finance. As these new applications emerge, adversaries are circumventing them.
Further, there have been concerns about the possibility of bias and discrimination in predictive applications.
In order to address these issues, we propose an...
Food waste (FW), brewery waste (BW), and fats, oils, and greases (FOG), are prevalent waste streams in municipalities across the country, particularly in the Pacific Northwest (PNW). Anaerobic digestion (AD), the microbial-mediated transformation of organic waste into methane-rich biogas, offers a sustainable, energy-generating, waste management solution for these wastes. Anaerobic...
In the 21st century, environmental deterioration is now an indisputable fact. Reliable and economically viable electricity systems based on renewable sources are urgently needed to replace the environmentally detrimental fossil fuels. The feasibility of incorporating renewable-but-intermittent solar and wind energy heavily depends on the development of cost-effective and safe technologies,...
Urban forests are fundamental to the health and sustainability of urban communities. In 2012, the U.S. Forest Service launched the Vibrant Cities, Urban Forests: A National Call to Action initiative which posed a variety of recommendations to advance urban forest management and programs throughout the country. In response to that...
Environmental archives provide records of natural and anthropogenic variation in the environment at different temporal and spatial scales. Lead (Pb) concentrations and isotopic ratios are useful tracers of anthropogenic emissions from industrial activities including mining, smelting, and leaded gasoline use, however, methods of measuring Pb are largely limited in low...
Wine is known to have been enjoyed since ancient times. Although early civilizations where unaware of scientific mechanisms of the properties of wine, empirical methods allowed them knowledge of its intoxicating effects as well as its healthful properties. These properties lead the ancients to use wine for many purposes including...
While water scarcity and energy demand are continuously increasing in the world, alternative sources are needed to meet the requirement of a growing population. Microbial Fuel Cell (MFC) is a sustainable technology that converts organic matter in wastewater into electricity, thus it can be a potential alternative source for water...
Novel donor-typed ternary graphite intercalation compounds (GICs) are synthesized and characterized containing (1) pyrrolidinium cations with DMSO co-intercalates; (2) alkali metal cations with crown ether co-intercalates; and (3) alkali metal cations with polyethylene glycol co-intercalates. Structural and compositional data are obtained for the stable products. A new ether-amine co-intercalate exchange...
Nanoparticles (NPs), defined by their size (1-100 nm), are increasingly incorporated into commercial and industrial products due to their high surface area and unique properties. They can be designed for specific applications by manipulating composition, size, shape, and surface functionalization. As NP production and complexity increases, there is a need...
The grand plan of carbon neutralization and COP26 in Glasgow require a quick shift of energy sources from conventional fossil fuel to a more renewable substitute such as wind, or solar energy. However, the intermittency of those renewable energy sources does not meet the demand of the energy, which requires...
The electrical performance of on-chip interconnects has become a limiting factor to the performance of modern integrated circuits including RFICs, mixed-signal circuits, as well as high-speed VLSI circuits due to increasing operating frequencies, chip areas, and integration densities. It is advantageous to have fast and accurate closed-form expressions for the...
Proteins are essential to all biological systems. Proteins participate in numerous cellular processes by interacting with other proteins, other metabolites and membranes in a dynamic environment. Studying the structural and conformational properties of proteins in the solution phase is necessary to understand their protein folding and interaction dynamics. This research...
Microtechnology was used to study the chemical reduction of dissolved carbon dioxide into useful products. A novel TiO₂ photocatalyst was used to activate the reaction under ultraviolet irradiation. CO₂ was dissolved in aqueous and 50% BMIM-BF₄ (ionic liquid) solutions. The introduction of an ionic liquid increased the solubility of CO₂...
The research presented in this thesis seeks to further our understanding of the geochemical signatures that can be used to trace and quantify non-ferrous smelting emission inputs into the environment. Strong evidence suggests that emissions from the non-ferrous smelter in Trail, BC are the primary source of metals deposited from...
The deglacial behavior of the sub-Arctic North Pacific is poorly constrained, with many published records suffering from limited age control due to extensive post- depositional biogenic carbonate dissolution. Potential alternative dating methods could include the correlation of stable-isotopic and/or paleomagnetic secular variation records to an independently-dated regional template, however no...
The diffusion of divalent nickel (Ni²⁺) from wet silica gels was investigated.
Silica gel is gaining interest as an encapsulation matrix for biological components.
The transport of biologically relevant species within the gel is determined by the
structural characteristics of the gel, which are in turn governed by synthesis
parameters....
Standard larval Pacific oyster (Crassostrea gigas) rearing systems can be described as either static or continuous flow. While rearing oyster larvae in static cultures can be a low-cost and simple method, static systems require significant husbandry effort, floorspace and can produce highly variable results due to environmental variance among cultures....
Barley (Hordeum vulgare L.) is one of the oldest known domesticated crops. Originally cultivated for human consumption, other end-uses have gained importance over the millennia. Barley is the fourth most important cereal crop in the world (FAO-STAT, 2011), and today it is mainly used as animal feed or malted for...
The issue of chloride-induced corrosion of reinforcing steel in concrete and its economic impacts are well-known. Chlorides that cause reinforcement corrosion can be from constituent materials used to prepare concrete or can enter the hardened concrete when the structure is exposed to chloride environments. To minimize the risk of reinforcement...
Electrochemical capacitors and batteries are two major electrochemical energy storage technologies, which have been investigated extensively to meet the rapidly-growing demand for higher energy, higher power, lower cost and enhanced safety in the past few decades. With the charge storage mechanism of electrostatic charge adsorption desorption via electrical double layers,...