Future quantum technologies will require high-efficiency, on-demand sources of entangled photons. A possible route to building such light sources employs two-dimensional (2D) semiconductors interfaced with a source of Cooper pairs. To investigate the possibility of such devices, we are testing methods to make high transparency n-type contacts, p-type contacts, and...
This work investigates the effect of cation substitution on the properties of the lead-free, solid solution (Na₀.₅Bi₀.₅)TiO₃-BaTiO₃ (NBT-BT). Substitution into NBT-BT increases disorder and increases the relaxor ferroelectric properties. These relaxor ferroelectric materials show large piezoelectric strains that can be utilized in actuator applications. Ceramic samples were prepared using standard...
Cobalt germanides have been widely studied as semiconductor contact materials, but recent theoretical studies suggest that they may also be excellent catalysts for methane steam reforming with stabilities and activities comparable to noble metal catalysts. In order to study the catalytic activity of cobalt germanides, it is critical to first...
Materials with a strong spin Hall effect and Rashba-Edelstein effect have the potential to improve the efficiency of solid-state magnetic memory technologies and other magnetic logic devices. Heavy metals have been identified as having these properties, including the beta crystal phase of tungsten. In this work, we determine the strength...
This thesis will cover work that I have completed relating to the field of terahertz (THz) science. My work has consisted of generating tunable, narrowband THz pulses in a table-top optical setup and using both narrow- and broadband THz pulses to study various material systems. Broadband THz pulses were used...
The continued development of organic semiconductor materials relies on an understanding of the relationship between optoelectronic properties, molecular structure, and molecular interaction. Several detailed studies of electronic properties in functionalized polyacene materials are presented. A computational model which allows the extraction of charge generation and transport properties from experimental data...
Spontaneous quasicrystal (QC) formation has not been observed in pure metals either in computation or in experiments (excluding epitaxial growth of thin atomic layers on a QC template). In this thesis work, dodecagonal QC (DDQC) grains are first discovered to spontaneously form during thermal devitrification of pure tantalum (Ta) metallic...
The optical and electronic properties of amorphous oxide thin films depend crucially on chemical composition, and deposition process variations which give rise to sub-gap defect states. Consequently, there is a need for a reliable, high-throughput method to extract sub-gap defect densities of states in amorphous oxide thin films. We present...
Low-dimensional electronic materials offer a platform to observe biological processes with unprecedented spatial and temporal resolution. Carbon nanotubes (CNTs) are the closest physical analog to an ideal 1D system and can be scaled and integrated into multiplexed electronic circuitry. The molecular structure of a CNT is also biocompatible, making them...
We found unexpected complexities resulting from the miscible displacement of a non-Newtonian fluid for both convergent and divergent flow as observed by displacing a miscible shear-thinning fluid (xanthan gum) in a radial Hele-Shaw cell. Such complex patterns have not been described before for either Newtonian or non- Newtonian fluids. A...