Understanding structural evolution in solids as composition changes is essential to materials properties prediction. Such structure-properties relationships are the theme of solid state chemistry. Materials scientists and chemists have utilized an abundance of simple crystal structures to enhance understanding of chemical and structural origins of properties in materials for decades....
This dissertation presents a study of structure-property relationships within 3d/4d metal oxides containing precious metals through detailed structure refinements using high-resolution neutron and X-ray diffraction data along with exploration of the resultant properties.
Oxides of 4d or 5d transition metals tend to show new topological phases due to significant spin-orbit...
Solid state inorganic oxides play an important role in next generation electronics based on their stability, versatility, and enhanced properties over other materials. However, in order to design or tune these materials for a desired functionality it is necessary to fully understand the structure behind the properties exhibited. This dissertation...
The abundance of copper was determined in four to six one-gram
specimens separated by a distance of several inches from each
of 23 large chondritic fragments (greater than 1 kg) via instrumental
neutron activation analysis and counting of the annihilation N-rays of
⁶⁴Cu. It is believed that an accuracy of...
Due to the high cost of precursor materials, complex oxides of 4d and 5d transition metals are under-studied compared to their 3d counterparts. Recent studies have shown that oxides containing heavier transition metals can exhibit exotic electronic states due to presence of strong spin-orbit coupling. The goal of this dissertation...
In the most challenging nuclear power plant accidents, transient critical heat flux (CHF) is a primary phenomenon that drives peak cladding temperature and ultimately fuel failure. It is not yet determined whether the use of steady-state CHF methods can accurately predict transient CHF under the conditions of a blowdown due...
The bioavailability of vitamin B₆ in four selected foods
(bananas, filberts, soybeans and beef) was determined in five men,
aged 22 to 25 years, who were saturated with pyridoxine. The study
consisted of a five-day adjustment period followed by a 28-day experimental
period. All subjects consumed a constant diet containing...
Prerigor pressurization of bovine semimembranosus muscle at 103.5
MNm⁻² (15,000 psi) for two min at 35°C significantly decreased
(P<0.01) muscle pH, and significantly (P<0.01) increased the rate of
glycogen degradation during the first 4 hr postmortem.
Glycogen levels of pressurized muscle were significantly
(P<0.01) lower than those of the control...