Perdeutero-spiropentane (C₅D₈) has been synthesized and infrared and Raman spectra are reported for the first time. Wavenumber assignments are made for most of the fundamental vibrational modes. Gas phase infrared spectra were recorded at a resolution (0.002 cm⁻¹) sufficient to resolve individual rovibrational lines and show evidence of strong Coriolis...
This paper is a continuation of earlier work in which the high resolution infrared spectrum of [1.1.1]propellane was measured and its k and l structure resolved for the first time. Here we present results from an analysis of more than 16,000 transitions involving three fundamental bands v₁₀ (E' - A'₁),...
Perdeutero-spiropentane (C₅D₈) has been synthesized, and infrared and Raman spectra are reported for the first time. Wavenumber assignments are made for most of the fundamental vibrational states. Gas phase infrared spectra were recorded at a resolution (0.002 cm⁻¹) sufficient to resolve individual rovibrational lines and show evidence of strong Coriolis...
High-resolution infrared absorption spectra have been analyzed for two bicyclo[111]pentane isotopologues, C₅H₈ (-d₀) and C₅H₇D (-d₁), where in the latter the D-atom replaces a hydrogen on the C₃ symmetry axis such that the molecular symmetry is reduced from D₃ₕ to C₃ᵥ. Two (a"₂) parallel bands, v₁₇ and v₁₈, of bicyclopentane-d₀...
The rip current field resulting from the transformation of surface gravity waves over
offshore submarine canyons is studied. Employing a wave transformation model and a
wave-induced circulation model over observed bathymetry we find that wave height
variations associated with undulations in the canyon contours cause rip current circulation
cells with...
The dynamics of vorticity motions forced by wave groups incident on an
alongshore-uniform barred beach are analyzed. For both normally and obliquely incident
wave groups, the potential vorticity and enstrophy equations reveal that the temporal
variability of wave group–forced vortices is directly linked to the variability in the
incoming wave...
This study examined the potentially stressful
effects of tagging juvenile rainbow trout Oncorhynchus mykiss
with passive integrated transponder (PIT) tags by measuring
short-term (<120-h) changes in plasma concentrations of
cortisol and hepatic heat shock protein 70 (hsp70). In a
laboratory experiment, plasma cortisol levels were measured
in fish before they...
It has generally been assumed by historians and anthropologists that the indigenous groups living to the west and northwest of the Colorado River were non-horticultural with three or four exceptions: some horticulture among the eastern-most Kamia, among the Chemehuevi who settled at a late date along the Colorado River, and...
Diseased and healthy Douglas-fir (Pseudotsuga menziesii (Mirb.) Franco) were identified at two black-stain root disease centers, caused by Leptographium wageneri var. pseudotsugae Harrington & Cobb, in the Oregon Coast Range near Coos Bay. Phloem and sapwood near the root collar were sampled monthly for 1 year, whereas roots were sampled...
Beauveria sinensis sp. nov. was isolated from a larva of Geometridae (Lepidoptera) collected from Tiantangzhai, Anhui province, China. It is characterized by elongated ellipsoidal to cylindrical conidia, solitary conidiogenous cells that are cylindrical or with slightly swollen bases, white to pale pink colony in culture, and small mycelial pellets consisting...