Phytochemical profiles and antioxidant activity of four historical
grape accessions (‘Kuzu Kuyrugu’, ‘Miskali’, ‘Erkek Miskali’, and
‘Kirmizi Kismis’) grown in Igdir province located in Eastern Anatolia
Region of Turkey were examined. The amount of vitamin C,
organic acids (citric acid, tartaric acid, malic acid, succinic acid and
fumaric acid), sugars...
Recent publications about the rising cost of college textbooks by the Public Interest Research and the US Government Accountability Office have caused student groups across the country to explore novel ways to address the problem. Students, publishers, bookstores and academic libraries, because of their role of managing course reserves, are...
Our ability to assess the continental impacts of woody encroachment remains compromised by the paucity of studies quantifying regional encroachment rates. This knowledge gap is especially apparent when it comes to quantifying the impact of woody encroachment on large-scale carbon dynamics. In this study, we use a combination of aerial...
Insects are important forest disturbance agents, and mapping their effects on tree mortality and surface fuels represents a critical research challenge. Although various remote sensing approaches have been developed to monitor insect impacts, most studies have focused on single insect agents or single locations and have not related observed changes...
Post-fire snags provide important resources for cavity nesting communities as well as being subject to timber removal through salvage logging practices. Tools that can characterize their distributions along with other features important as wildlife habitat, such as woody shrub cover, would be useful for research and management purposes. Three dimensional...
The cohesion-tension theory of water transport states that hydrogen bonds hold water molecules together and that they are pulled through the xylem under tension. This tension could cause transport failure in at least two ways: collapse of the conduit walls (implosion), or rupture of the water column through air-seeding. The...
n Oregon’s Willamette Valley, remaining wetlands are at high risk to loss and degradation from agricultural activity and urbanization. With an increased need for fine temporal-scale monitoring of sensitive wetlands, we used annual Landsat MSS and TM/ETM+ images from 1972 to 2012 to manually interpret loss, gain, and type conversion...
Lidar is currently the most accurate method for remote estimation of forest structure, but it has limited spatial and temporal coverage. Conversely, Landsat data are more widely available, but exhibit a weaker relationship with structure under medium to high leaf area conditions. One potentially valuable means of enhancing the relationship...
Improved monitoring of forest biomass and biomass change is needed to quantify natural and anthropogenic effects on the terrestrial carbon cycle. Landsat's temporal and spatial coverage, moderate spatial resolution, and long history of earth observations provide a unique opportunity for characterizing vegetation changes across large areas and long time scales....
Hatchery supplementation of anadromous salmon is extensive across the Pacific Northwest region with millions of juvenile salmon stocked annually. The influence of hatchery-origin fish as prey items in recipient ecosystems has been explored, but influences of these fish on broader stream nutrient dynamics has not been well-studied. Salmon-derived nutrients (SDN)...
Grasslands account for a large proportion of global terrestrial productivity and play a critical role in carbon and water
cycling. Within grasslands, photosynthetic pathway is an important functional trait yielding different rates of productivity
along environmental gradients. Recently, C₃-C₄ sorting along spatial environmental gradients has been reassessed by
controlling for...
Knowledge of nutrient pathways and their resulting ecological interactions can alleviate numerous environmental problems associated with nutrient increases in both natural and managed systems. Although not unique, coastal systems are particularly prone to complex ecological interactions resulting from nutrient inputs from both the land and sea. Nutrient inputs to coastal...
Cultivated potato crops are sensitive to
drought stress, reducing yield and tuber quality when the soil water potential drops to -0.3
MPa. However, drought not only affects plant growth and physiological activity, but this
stress also induces biochemical and molecular changes in the cellular gene expression profile,
triggering genes that...
This study investigated the mechanisms involved in the
regulation of stomatal closure in Douglas-fir and evaluated
the potential impact of compensatory adjustments in
response to increasing tree height upon these mechanisms.
In the laboratory, we measured leaf hydraulic conductance
(Kleaf) as leaf water potential (Yl) declined for comparison
with in...
Chile’s open trade policy, implemented during the last few decades, has greatly transformed Chilean farmers and their production systems. As a result, farmers can be grouped into three categories based on their market-production orientation: domestic, transitional or export producers. The objective of this paper is to analyze the factors underlying...
AIM: C₄ photosynthesis is an adaptation that maintains efficient carbon assimilation in warm and low-CO₂ conditions. Due to the importance of C₄ grasses for carbon and surface energy fluxes numerous models have been proposed to describe their spatial distribution and forecast responses to climate change. These models often rely on...
Understanding fine-grain patterns of forest disturbance and regrowth at the landscape scale is critical for effective management, particularly in forests in western Washington, Oregon, and California, U.S., where the policy known as the Northwest Forest Plan (NWFP) was imposed in 1994 over > 8 million ha of forest in an...
A previous study showed that ammonia oxidation by the Thaumarchaeota Nitrosopumilus maritimus (group 1.1a) was resistant
to concentrations of the C₈ 1-alkyne, octyne, which completely inhibits activity by ammonia-oxidizing bacteria. In this study, the
inhibitory effects of octyne and other C₂ to C₁₀ 1-alkynes were evaluated on the nitrite production...
Traumatic brain injury (TBI) is a significant public health issue due to the incidence,
complexity, and cost associated with treatment. The purpose of this study was to
determine physical activity (PA) knowledge, attitudes, intentions, and barriers
among individuals with a TBI undergoing outpatient rehabilitation. Seventeen
participants completed a series of...
Research progress to understand the role of vitamin C (ascorbic acid) in human health has been slow in coming. This is predominantly the result of several flawed approaches to study design, often lacking a full appreciation of the redox chemistry and biology of ascorbic acid. In this review, we summarize...
Chemical and microbial soil properties were assessed in paired unfertilized and urea fertilized (>89 g N·m–2) plots in 13 second-growth Douglas-fir (Pseudotsuga menziesii (Mirb.) Franco) stands distributed throughout western Washington and Oregon. A decade following the termination of fertilization, fertilized plots averaged 28% higher total N in the O layer...
The accuracy of DNA synthesis depends on the accuracy of the polymerase as well as the quality and concentration(s) of the available 5'-deoxynucleoside-triphosphate DNA precursors (dNTPs). The relationships between dNTPs and error rates have been studied in vitro, but only limited insights exist into these correlations during in vivo replication....
Stream restorations that increase geomorphic stability can improve habitat quality, which should benefit selected species and local aquatic ecosystems. This assumption is often used to define primary restoration goals; yet, biological responses to restoration are rarely monitored or evaluated methodically. Macroinvertebrate communities were inventoried at 6 study reaches within 5...
Understanding local and geographic factors influencing species distributions is a prerequisite for conservation planning. Our objective in this study was to model local and geographic variability in elevations occupied by native and nonnative trout in the northwestern Great Basin, USA. To this end, we analyzed a large existing data set...
Plant wax lipids and lignin phenols are the two most common classes of molecular markers that are used to trace vascular plant-derived OM in the marine environment. However, their ¹³C and ¹⁴C compositions have not been directly compared, which can be used to constrain the flux and attenuation of terrestrial...
Increasing forest stress and tree mortality has been directly linked to combinations of drought and high temperatures. The climatic changes expected during the next decades – large increases in mean temperature, increased heat waves, and significant long-term regional drying in the western USA – will likely increase chronic forest stress...
The development of hybrids with enhanced expression of heterosis depends on the genetic background of the source population and the effectiveness of a breeding scheme used to identify and use divergent inbred lines with good combining ability. The present study was conducted to examine the potential of improved tropical reciprocal...
The placement of ‘Pseudomonas butanovora’ in the genus Thauera was proposed previously, based on 16S rRNA gene sequence analysis, upon further studies of taxonomical characteristics. In this study, physiological characteristics and DNA–DNA reassociation data are presented and the transfer of ‘P. butanovora’ to the genus Thauera is proposed. The original...
To consider the regional scale effects of forest management requires complete and consistent data over large areas. We used Landsat Thematic Mapper and Multispectral Scanner (TM and MSS) imagery to map forest cover and detect major disturbances between 1975 and 1992 for a 4.2 x 106 ha area of interior...
Automated cloud and cloud shadow identification algorithms designed for Landsat Thematic Mapper (TM) and Thematic Mapper Plus (ETM+) satellite images have greatly expanded the use of these Earth observation data by providing a means of including only clear-view pixels in image analysis and efficient cloud-free compositing. In an effort to...
PURPOSE:
Little research has analyzed mistrust and discrimination influencing receipt of health care services among Latinos, particularly those living in rural areas. The present study examined the associations between medical mistrust, perceived discrimination, and satisfaction with health care among young-adult rural Latinos.
RESEARCH DESIGN:
This cross-sectional study analyzed data from...
As we contemplate the future of forest landscapes under changing climate conditions and land-use demands, there is increasing value in studying historic forest conditions and how these landscapes have changed following past disturbances. Historic landscape paintings are a potential source of data on preindustrial forests with highly detailed, full-color depictions...
Despite renewed interest in the nature of limitations on maximum tree height, the mechanisms governing ultimate and species-specific height limits are not yet understood, but likely involve water transport dynamics. Tall trees experience increased risk of xylem embolism from air-seeding because tension in their water column increases with height due...
The Northwest Forest Plan (NWFP), which aims to conserve late-successional and old-growth forests (older forests) and associated species, established new policies on federal lands in the Pacific Northwest USA. As part of monitoring for the NWFP, we tested nearest-neighbor imputation for mapping change in older forest, defined by threshold values...
Disturbance events strongly affect the composition, structure, and function of forest ecosystems; however, existing US land management inventories were not designed to monitor disturbance. To begin addressing this gap, the North American Forest Dynamics (NAFD) project has examined a geographic sample of 50 Landsat satellite image time series to assess...
The Genome-Wide Association Studies approach was used to detect Quantitative Trait Loci associated with tocochromanol concentrations using a panel of 1,466 barley accessions. All major tocochromanol types- α-, β-, δ-, γ-tocopherol and tocotrienol- were assayed. We found 13 single nucleotide polymorphisms associated with the concentration of one or more of...
Mangroves provide a wide range of ecosystem services, including nutrient cycling, soil formation, wood production, fish spawning grounds, ecotourism and carbon (C) storage¹. High rates of tree and plant growth, coupled with anaerobic, water-logged soils that slow decomposition, result in large long-term C storage. Given their global significance as large...
Carbon sequestration is increasingly recognized as an ecosystem service, and forest management has a large potential to alter regional carbon fluxes − notably by way of harvest removals and related impacts on net ecosystem production (NEP). In the Pacific Northwest region of the U.S.,
the implementation of the Northwest Forest...
The first direct measurement of electron neutrino quasielastic and quasielasticlike scattering on hydrocarbon in the few-GeV region of incident neutrino energy has been carried out using the MINERvA detector in the NuMI beam at Fermilab. The flux-integrated differential cross sections in the electron production angle, electron energy, and Q² are...
Charged pion production via charged-current nu[subscript]μ interactions on plastic scintillator (CH) is studied using the MINERvA detector exposed to the NuMI wideband neutrino beam at Fermilab. Events with hadronic invariant mass W<1.4 GeV and W<1.8 GeV are selected in separate analyses: the lower W cut isolates single pion production, which is expected...
Wood is a key structural element in aquatic ecosystems. Wood provides habitat complexity, alters geomorphology, retains organic and inorganic material, promotes hyporheic flow, and acts as substrate for biofilms and invertebrates. Fire is an important disturbance promoting wood recruitment into inland waters, but most studies have focused on streams in...
Perdeutero-spiropentane (C₅D₈) has been synthesized and infrared and Raman spectra are reported for the first time. Wavenumber assignments are made for most of the fundamental vibrational modes. Gas phase infrared spectra were recorded at a resolution (0.002 cm⁻¹) sufficient to resolve individual rovibrational lines and show evidence of strong Coriolis...
Perdeutero-spiropentane (C₅D₈) has been synthesized, and infrared and Raman spectra are reported for the first time. Wavenumber assignments are made for most of the fundamental vibrational states. Gas phase infrared spectra were recorded at a resolution (0.002 cm⁻¹) sufficient to resolve individual rovibrational lines and show evidence of strong Coriolis...
Current compression perpendicular-to-grain (C⊥) design values for wood members are based on mean stress obtained from ASTM D143 specimen. The standard ASTM test with metal on wood bearing has limited applicability in modern construction assemblies with C⊥ loading scenarios. Previous work has shown that end-bearing conditions and wood-on-wood C⊥ bearing...
Light availability strongly influences stream primary production, water temperatures and resource availability at the base of stream food webs. In headwater streams, light is regulated primarily by the riparian forest, but few studies have evaluated the influence of riparian forest stand age and associated structural differences on light availability. In...
In some cases a canopy height model (CHM) is the only available source of forest height information. For these cases it is important to understand the predictive power of CHM data for forest attributes. In this study we examined the use of lidar-derived CHM metrics to predict forest structure classes...
Using the counterflow virtual impactor, a new instrument for sampling cloud droplets, measurable levels of light-absorbing material were found to exist inside droplets in stratocumulus clouds off the coast of southern California. Eighty percent of the samples of droplet residue material had light absorption coefficients ranging from 6 to 20...
Nech Sar National Park (NSNP) is one of the most important biodiversity centers in Ethiopia. In recent years, a widespread decline of the terrestrial ecosystems has been reported, yet to date there is no comprehensive assessment on degradation across the park. In this study, changes in landcover were analyzed using...
The ability to estimate and monitor standing dead trees (snags) has been difficult due to their irregular and sparse distribution, often requiring intensive sampling methods to obtain statistically significant estimates. This study presents a new method for estimating and monitoring snags using neighborhood attribute filtered airborne discrete-return lidar data. The...
Declining abundance of Chinook Salmon Oncorhynchus tshawytscha across the Pacific Northwest is an issue of great concern ecologically, culturally, and economically. Growth during the first summer is vitally important for juvenile Chinook Salmon, as it influences not only life history decisions (to smolt or not to smolt) but also subsequent...
Worldwide measurements of nearly 130C3 species covering all
major plant functional types are analysed in conjunction with
model simulations to determine the effects of mesophyll
conductance (gm) on photosynthetic parameters and their
relationships estimated from A/Ci curves. We find that an
assumption of infinite gm results in up to 75%...
Worldwide measurements of nearly 130C3 species covering all major plant functional types are analysed in conjunction with model simulations to determine the effects of mesophyll conductance (gm) on photosynthetic parameters and their relationships estimated from A/Ci curves. We find that an assumption of infinite gm results in up to 75%...
Benthic foraminiferal δ¹³C data from site 502 in the Caribbean Sea (sill depth 1800 m) indicate that throughout the past 2.6 m.y., glacial δ¹³C values in the middepth Atlantic were higher during glaciations than interglaciations. This is interpreted as indicating a greater proportion of Upper North Atlantic Deep Water (UNADW)...
The isotopic composition of the dissolved inorganic carbon (DIC) collected at sites of active methane discharge on Hydrate Ridge, Oregon, reveals anaerobic methane oxidation mediated by bacteria, with δ13CDIC reaching values as low as –48‰ in the upper 4 cm of the sediment. In spite of the high sulfide levels...
N-methyl-D-aspartate (NMDA) receptors are calcium-permeable ion channels
assembled from four subunits that each have a common membrane topology. The
intracellular carboxyl terminal domain (CTD) of each subunit varies in length, is least
conserved between subunits, and binds multiple intracellular proteins. We defined a
region of interest in the GluN2A CTD,...
In 2004-2005, 2007 and 2009, three major drought disasters occurred in Guangdong
Province of southern China, which caused serious economic losses. Hence, it has recently become
an important research subject in China to monitor surface soil moisture (SSM) and the drought
disaster quickly and accurately. SSM is an effective indicator...
Estimation of belowground carbon stocks in tropical wetland forests requires funding for laboratory analyses and suitable facilities, which are often lacking in developing nations where most tropical wetlands are found. It is therefore beneficial to develop simple analytical tools to assist belowground carbon estimation where financial and technical limitations are...
Dissolved C, N, P, and Si budgets for Tomales Bay, California, have been used to solve simultaneous stoichiometric equations which describe a plausible material balance for net organic matter reactions in the bay. Dissolved Si and P were both exported hydrographically. Dissolved C and fixed N were imported hydrographically. If...
Oceanic iron (Fe) fertilization experiments have advanced the understanding of how Fe regulates biological productivity and air–sea carbon dioxide (CO₂) exchange. However, little is known about the production and consumption of halocarbons and other gases as a result of Fe addition. Besides metabolizing inorganic carbon, marine microorganisms produce and consume...
Academic and public libraries have begun to purchase e-book readers and make them available for check-out to their users. The nature of the e-books on these devices necessitates new approaches to workflow for acquisitions and cataloging departments. In addition, the application of cataloging rules and conventions presents a number of...
We report zero kinetic energy (ZEKE) photoelectron spectroscopy via resonantly enhanced multiphoton ionization (REMPI) for benzo[e]pyrene. Extensive vibronic coupling between the first electronically excited state and a nearby state allows b₂ symmetric modes to be observed which would normally be Franck-Condon (FC) disallowed. These vibronic modes are comparable in intensity...
In August 2011, a cohort of 30 Oregon State University Libraries and Press librarians and staff received free e-readers (Kindle Keyboards, Nook Simple Touches, Kobo Touches, and Sony PRS-350 Reader Pocket Editions) to use and adopt as they wished. In return, they were asked to participate in a year-long study...
Hepatitis E virus (HEV) infection is a cause of hepatitis in humans worldwide. Recently, persistent and chronic HEV infections have been recognized as a serious clinical problem, especially in immunocompromised individuals. To date, there are no FDA-approved HEV-specific antiviral drugs. In this study, we designed and evaluated antisense peptide-conjugated morpholino...
Because of the intangible nature of online shopping, consumers perceive online shopping as being risky. This study examined how this risk can be reduced specifically by using a more effective online product presentation method. A combination of the number of product views (one and four) and size (small and large)...
Ebola viruses (EBOV) cause severe disease in humans and nonhuman primates with high mortality rates and continue to emerge in new geographic locations, including several countries in West Africa, the site of a large ongoing outbreak. Phosphorodiamidate morpholino oligomers (PMOs) are synthetic antisense molecules that are able to target mRNAs...
With earth's surface temperature and human population both on the rise a new emphasis has been placed on
monitoring changes to forested ecosystems the world over. In the United States the U.S. Forest Service Forest
Inventory and Analysis (FIA) program monitors the forested land base with field data collected over...
The myeloid-specific transcription factor, CCAAT/enhancer-binding protein epsilon (C/EBPε) is a critical mediator of myelopoiesis. Mutation of this gene is responsible for neutrophil-specific granule deficiency in humans, a condition that confers susceptibility to Staphylococcus aureus infection. We found that C/EBPε-deficient mice are severely affected by infection with S. aureus, and C/EBPε...
Endogenous small RNAs (endo-siRNAs) interact with Argonaute (AGO) proteins to mediate
sequence-specific regulation of diverse biological processes. Here, we combine deep-sequencing and
genetic approaches to explore the biogenesis and function of endo-siRNAs in C. elegans. We describe
conditional alleles of the dicer-related helicase, drh-3, that abrogate both RNA interference and...
Marine and freshwater food webs are strongly structured by size-dependent predator−prey interactions. Predator−prey body mass ratios (PPMR) are important parameters in size-based food-web models, but studies evaluating the temporal stability of PPMR or its relationship to predator feeding modes are scant. Using a large data set of predator−prey pairs from...
Atmospheric and surface ocean temperatures in the Antarctic Peninsula region have increased by a few degrees Celsius over the last few decades, and they are the most rapid changes recorded in the Southern Hemisphere during this time period (Cook et al., 2005; Meredith and King, 2005). Associated with this ongoing...
Forest understory communities are important components in forest ecosystems providing wildlife habitat and influencing nutrient cycling, fuel loadings, fire behavior and tree species composition over time. One of the most widely utilized understory component metrics is understory vegetation cover, often used as a measure of vegetation abundance. To date, understory...
Ceratonova gasterostea n. gen. n. sp. is described from the intestine of freshwater Gasterosteus aculeatus L. from the Klamath River, California. Myxospores are arcuate, 22.4 +/- 2.6 μm thick, 5.2 +/- 0.4 μm long, posterior angle 45 +/- 24°, with 2 sub-spherical polar capsules, diameter 2.3 +/- 0.2 μm, which...
Dibenzo(def,p)chrysene (DBC), (also known as dibenzo[a,l]pyrene), is a high molecular weight polycyclic aromatic hydrocarbon (PAH) found in the environment, including food, produced by the incomplete combustion of hydrocarbons. DBC, classified by IARC as a 2A probable human carcinogen, has a relative potency factor (RPF) in animal cancer models 30-fold higher...
Mulberries (Morus spp) are historically grown in particular microclimatic regions in Eastern Anatolia, including Aras valley. In the valley, mulberries are one of the ancient crop and used for several purposes by local people. The aim of the present study was to first time evaluate organic acids, sugars, vitamin C,...
The down‐regulation of dominant oncogenes, including C‐MYC, in tumor cells often leads to the induction of
senescence via mechanisms that are not completely identified. In the current study, we demonstrate that MYC‐depleted
melanoma cells undergo extensive DNA damage that is caused by the underexpression of thymidylate synthase (TS) and
ribonucleotide...
This manuscript describes the role of non-classical hydrogen bonds (NCHBs), specifically C–H···O interactions, in modern synthetic organic transformations. Our goal is to point out the seminal examples where C–H···O interactions have been invoked as a key stereocontrolling element and to provide predictive value in recognizing future and/or potential C–H···O interactions...
We present double-differential measurements of antineutrino charged-current quasielastic scattering in the MINERvA detector. This study improves on a previous single-differential measurement by using updated reconstruction algorithms and interaction models and provides a complete description of observed muon kinematics in the form of a double-differential cross section with respect to muon...
The ¹⁴C-uptake method is the most common approach employed for estimating primary production in the ocean. Normalizing ¹⁴C-uptake to chlorophyll a and time yields a value termed the assimilation number, which is thought to reflect phytoplankton physiology. It is often assumed that the measured rate of ¹⁴C-uptake is between net...
The recommended dietary allowance (RDA) of vitamin C has traditionally been based on the prevention of the vitamin C deficiency disease, scurvy. While higher intakes of vitamin C may exert additional health benefits, the limited Phase III randomized placebo-controlled trials (RCTs) of vitamin C supplementation have not found consistent benefit...
We demonstrate a novel synthetic route to fabricate a one-dimensional
peapod-like Sb@C structure with disperse Sb
submicron-particles encapsulated in carbon submicron-tubes.
The synthetic route may well serve as a general methodology
for fabricating carbon/metallic fine structures by thermally
reducing their carbon-coated metal oxide composites.
Current compression perpendicular-to-grain (C-perpendicular to) design values for wood members are based on mean stress obtained from ASTM D143 specimen. The standard ASTM test with metal on wood bearing has limited applicability in modern construction assemblies with C-perpendicular to loading scenarios. Previous work has shown that end-bearing conditions and wood-on-wood...
Basal melting of ice shelves around Antarctica contributes to formation of Antarctic Bottom Water and can affect global sea level by altering the offshore flow of grounded ice streams and glaciers. Tides influence ice shelf basal melt rate (w(b)) by contributing to ocean mixing and mean circulation as well as...
The fatigue crack growth rates for nickel-based superalloy Haynes 282 were measured at temperatures of 550, 650, and 750 °C using compact tension specimens with a load ratio of 0.1 and cyclic loading frequencies of 25 Hz and 0.25 Hz. Increasing the temperature from 550 to 750 °C caused the...
We present a new method developed for measuring radiocarbon of methane (¹⁴CH₄) in ancient air samples
extracted from glacial ice and dating 11,000–15,000 calendar years before present. The small size (~20 μg CH₄ carbon), low
CH₄ concentrations ([CH₄], 400–800 parts per billion [ppb]), high carbon monoxide concentrations ([CO]), and low...
The fatigue crack growth rates for nickel-based superalloy Haynes 282 were measured at 550, 650, and 750 °C using compact tension specimens with a load ratio of 0.1 and cyclic loading frequencies of 25 and 0.25 Hz. The crack path was observed to be primarily transgranular for all temperatures, and...
By taking advantage of the electron pathway through the heme group in cytochrome c (CytoC) electrochemists
have built sensors based upon CytoC immobilized onto metal electrodes. Previous studies have shown that the
electron transfer rate through the protein is a function of the position of this heme group with respect...
Information on land cover at global and continental scales is critical for addressing a range of ecological, socioeconomic and policy questions. Global land cover maps have evolved rapidly in the last decade, but efforts to evaluate map uncertainties have been limited, especially in remote areas like Northern Eurasia. Northern Eurasia...
Zonal and meridional Seasoar sections centered at 1°50’S, 156°06’E were repeated >30 times in three 20-day periods between November 13, 1992, and February 15, 1993. Both sections were 130 km long, and sampling depth was 0–280 m, with a vertical resolution of ~2 dbar (2 x 104 Pa) and a...
Tropical peatlands cover an estimated 440,000 km² (~10% of global peatland area) and are significant in the global
carbon cycle by storing about 40–90 Gt C in peat. Over the past several decades, tropical peatlands have experienced
high rates of deforestation and conversion, which is often associated with lowering the...
Vibrio cholerae, an etiological agent of cholera, circulates between aquatic reservoirs and the human gastrointestinal tract. The
type II secretion (T2S) system plays a pivotal role in both stages of the lifestyle by exporting multiple proteins, including cholera
toxin. Here, we studied the kinetics of expression of genes encoding the...
The regiodivergent O- to C- or N-carboxyl transfer of pyrazolyl carbonates is described, with DMAP giving preferential N-carboxylation and triazolinylidenes promoting selective C-carboxylation (both with up to >99 : 1 regioselectivity). An enantioselective O- to C-carboxyl variant using NHC catalysis is demonstrated (up to 92% ee), while mechanistic and DFT studies outline...
Developmental changes in the carotenoids and volatile compounds of Pinot noir grape berries were investigated in this study from pea size to harvest during 2012. HPLC analysis showed continued decrease of lutein, β-carotene, neochrome a and neoxanthin continued to decrease during berry development, with rapid decrease of lutein and (9′z)-neoxanthin...
Evidence of shifting dominance among major forest disturbance agent classes regionally to globally has been emerging in the literature. For example, climate-related stress and secondary stressors on forests (e.g., insect and disease, fire) have dramatically increased since the turn of the century globally, while harvest rates in the western US...
Carbon isotopically based estimates of CO₂ levels have been generated from a record of the photosynthetic fractionation of ¹³C (≡εp) in a central equatorial Pacific sediment core that spans the last ~255 ka. Contents of ¹³C in phytoplanktonic biomass were determined by analysis of C37 alkadienones. These compounds are exclusive...
Analysis of observations and sensitivity experiments with a new three-dimensional global model of stable carbon isotope cycling elucidate processes that control the distribution of delta C-13 of dissolved inorganic carbon (DIC) in the contemporary and preindustrial ocean. Biological fractionation and the sinking of isotopically light delta C-13 organic matter from...
Sediments from five Leg 167 drill sites and three piston cores were analyzed for C[subscript ORG] and CaCO₃. Oxygen isotope stratigraphy on benthic foraminifers was used to assign age models to these sedimentary records. We find that the northern and central California margin is characterized by k.y.-scale events that can...
To test the hypothesis that embryogenesis depends upon α-tocopherol (E) to protect embryo polyunsaturated fatty acids (PUFAs) from lipid peroxidation, new methodologies were applied to measure α-tocopherol and fatty acids in extracts from saponified zebrafish embryos. A solid phase extraction method was developed to separate the analyte classes, using a...