The rare earth elements (REEs) with their systematically varying properties are powerful tracers of continental inputs, particle scavenging intensity and the oxidation state of seawater. However, their generally low (similar to pmol/kg) concentrations in seawater and fractionation potential during chemical treatment makes them difficult to measure. Here we report a...
Radiogenic isotopes of hafnium (Hf) and neodymium (Nd) are powerful tracers for water mass transport and trace metal cycling in the present and past oceans. However, due to the scarcity of available data the processes governing their distribution are not well understood. Here we present the first combined dissolved Hf...
Perdeutero-spiropentane (C₅D₈) has been synthesized, and infrared and Raman spectra are reported for the first time. Wavenumber assignments are made for most of the fundamental vibrational states. Gas phase infrared spectra were recorded at a resolution (0.002 cm⁻¹) sufficient to resolve individual rovibrational lines and show evidence of strong Coriolis...
Perdeutero-spiropentane (C₅D₈) has been synthesized and infrared and Raman spectra are reported for the first time. Wavenumber assignments are made for most of the fundamental vibrational modes. Gas phase infrared spectra were recorded at a resolution (0.002 cm⁻¹) sufficient to resolve individual rovibrational lines and show evidence of strong Coriolis...
A previous study showed that ammonia oxidation by the Thaumarchaeota Nitrosopumilus maritimus (group 1.1a) was resistant
to concentrations of the C₈ 1-alkyne, octyne, which completely inhibits activity by ammonia-oxidizing bacteria. In this study, the
inhibitory effects of octyne and other C₂ to C₁₀ 1-alkynes were evaluated on the nitrite production...
Plant wax lipids and lignin phenols are the two most common classes of molecular markers that are used to trace vascular plant-derived OM in the marine environment. However, their ¹³C and ¹⁴C compositions have not been directly compared, which can be used to constrain the flux and attenuation of terrestrial...
An interlaboratory study of Mg/Ca and Sr/Ca ratios in three commercially available carbonate reference
materials (BAM RS3, CMSI 1767, and ECRM 752-1) was performed with the participation of
25 laboratories that determine foraminiferal Mg/Ca ratios worldwide. These reference materials containing
Mg/Ca in the range of foraminiferal calcite (0.8 mmol/mol to...
Current compression perpendicular-to-grain (C⊥) design values for wood members are based on mean stress obtained from ASTM D143 specimen. The standard ASTM test with metal on wood bearing has limited applicability in modern construction assemblies with C⊥ loading scenarios. Previous work has shown that end-bearing conditions and wood-on-wood C⊥ bearing...
It is hypothesized that the circulation of the tropical Pacific Ocean and atmosphere satisfies the equations of a simple coupled model to within errors having specified covariances, and that the Tropical Atmosphere–Ocean array (TAO) measures the circulation to within errors also having specified covariances. This hypothesis is tested by finding...
The investigation of the consequences of trying to blend tropical Pacific observations from the Tropical Atmosphere–Ocean (TAO) array into the dynamical framework of an intermediate coupled ocean–atmosphere model is continued. In a previous study it was found that the model dynamics, the prior estimates of uncertainty in the observations, and...