The seasonality of sea surface temperatures (SST) estimated from the alkenone-U[superscript K’]₃₇ index has been a debated issue since the development of the sediment trap time series data from 34 sampling locations, we show that the maximum alkenone flux in sediment traps varies markedly across the oceans, only on latitude...
Branched glycerol dialkyl glycerol tetraethers (brGDGTs) of purportedly terrestrial origin are frequently detected in marine sediments, even in remote ocean sites where no direct impact from land erosion via rivers takes place. At these places, the most likely explanation for the presence of brGDGTs is in situ production or eolian...
The degradation of organic carbon in subseafloor sediments on continental margins contributes to the largest reservoir of methane on Earth. Sediments in the Andaman Sea are composed of ~ 1% marine-derived organic carbon and biogenic methane is present. Our objective was to determine microbial abundance and diversity in sediments that...
This manuscript describes the role of non-classical hydrogen bonds (NCHBs), specifically C–H···O interactions, in modern synthetic organic transformations. Our goal is to point out the seminal examples where C–H···O interactions have been invoked as a key stereocontrolling element and to provide predictive value in recognizing future and/or potential C–H···O interactions...
Grasslands account for a large proportion of global terrestrial productivity and play a critical role in carbon and water
cycling. Within grasslands, photosynthetic pathway is an important functional trait yielding different rates of productivity
along environmental gradients. Recently, C₃-C₄ sorting along spatial environmental gradients has been reassessed by
controlling for...
A previous study showed that ammonia oxidation by the Thaumarchaeota Nitrosopumilus maritimus (group 1.1a) was resistant
to concentrations of the C₈ 1-alkyne, octyne, which completely inhibits activity by ammonia-oxidizing bacteria. In this study, the
inhibitory effects of octyne and other C₂ to C₁₀ 1-alkynes were evaluated on the nitrite production...
Plant wax lipids and lignin phenols are the two most common classes of molecular markers that are used to trace vascular plant-derived OM in the marine environment. However, their ¹³C and ¹⁴C compositions have not been directly compared, which can be used to constrain the flux and attenuation of terrestrial...
The placement of ‘Pseudomonas butanovora’ in the genus Thauera was proposed previously, based on 16S rRNA gene sequence analysis, upon further studies of taxonomical characteristics. In this study, physiological characteristics and DNA–DNA reassociation data are presented and the transfer of ‘P. butanovora’ to the genus Thauera is proposed. The original...
Assessing impacts of future anthropogenic carbon emissions is currently impeded by uncertainties in our knowledge of equilibrium climate sensitivity to atmospheric carbon dioxide doubling. Previous studies suggest 3 K as best estimate, 2–4.5 K as the 66% probability range, and non-zero probabilities for much higher values, the latter implying a...
Perdeutero-spiropentane (C₅D₈) has been synthesized, and infrared and Raman spectra are reported for the first time. Wavenumber assignments are made for most of the fundamental vibrational states. Gas phase infrared spectra were recorded at a resolution (0.002 cm⁻¹) sufficient to resolve individual rovibrational lines and show evidence of strong Coriolis...