This dissertation describes patterns in epiphytic macrolichen community composition along a nitrogen deposition gradient in the Yosemite region of the Sierra Nevada in California. This region is part of the largest federal air quality Class 1 designated air-shed in the western United States, covering the entire crest of the Sierra...
Drought and mandatory water restrictions are limiting the availability of irrigation water in many important blueberry growing regions and new strategies are needed to maintain yield and fruit quality with less water. Three potential options for reducing water use, including deficit irrigation, irrigation cut-offs, and crop thinning, were evaluated for...
Sulfur-coated urea (SCU), a slow release nitrogen fertilizer,
may be economically competitive with conventional fertilizers, but
little is known of the mechanism of urea release from SCU and the
environmental factors which affect the urea release rate. Objectives
of this thesis were: (1) to determine factors which affect the rate...
Systems biology is a powerful approach which considers and sheds light on all of the puzzle pieces which make up complex biological processes, and is an effective alternative to unraveling these processes using traditional molecular approaches alone. It is a natural companion approach for computational biology, which leverages the power...
PART I. The preparation of (-)-ibogamine (1) in fourteen steps from benzoquinone and in 10% overall yield is a powerful illustration of the value of the asymmetric Diels-Alder reaction as a starting point in a multistep synthesis. All four cycloadducts, 70, 77, 84 and 96, obtained with the (S)-BINOL-TiCl₂ complex...
Young children with developmental disabilities (< 12 years old) participate less in physical activity (PA) and experience motor skill deficits compared to young children without disabilities (Jung, Leung, Schram, & Yun, 2018; Liu, Hamilton, Davis, & ElGarhy, 2014; Whyatt & Craig, 2012). When taking account of a bi-directional relationship between...
Oxidative dysfunction can affect dairy animals during periods of heightened stress, particularly during the transition from pregnancy to lactation and during diseases, such as intramammary infection (IMI), and can contribute to increased inflammation, immune dysfunction, and cell death. As such, methods for ameliorating oxidative stress and restoring redox regulation may...
Soils are the largest terrestrial pool of carbon, therefore it is critical to understand
what controls soil carbon efflux to the atmosphere in light of current climate uncertainty.
The primary efflux of carbon from soil is soil respiration which is typically categorized
into autotrophic and heterotrophic respiration. These two components...
The ethyl acetate extract of the culture filtrate of the marine Ascomycete,
Leptosphaeria oraemaris (Linder) yielded a novel metabolite
designated by the common name leptosphaerin. An x-ray crystallographic
structure analysis was disproved by the synthesis of 3-acetoxy-S-(1,2-dihydroxyethyl)-
3-pyrrolin-2-one 1, starting with N,N-dibenzylhydroxylamine
47 and D-mannitol 44. Oxidation of 47 followed...
Background: Prenatal care (PNC) is an important preventive health service that can influence the health of the four million women who give birth annually in the United States, and the health their infants. Despite efforts to increase women’s access to PNC services, significant disparities in PNC utilization and maternal/child health...