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Filtering by: Creator Poulter, Benjamin Remove constraint Creator: Poulter, Benjamin Resource Type Masters Thesis Remove constraint Resource Type: Masters Thesis

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  • The photodecomposition of t-butyl bicyclo [7.1.0] decane-2-percarboxylate

    Creator:
    McRitchie, Donna Louise
    Abstract:
    This paper describes the synthesis of t-butyl bicyclo[7.1.0] decane-2-percarboxylate and its photolytic decomposition. The title compound was found to undergo simple homolytic cleavage when exposed to light of 2537 A; producing the cyclodecyl radical, carbon dioxide, and t-butoxy radical. The largest percentage of products arose from an intimate radical pair...
    Resource Type:
    Masters Thesis
    Full Text:
    . Poulter and Winstein (29) have suggested that rings of this size may even twist into unfavorable