Index Catalog // ScholarsArchive@OSU

Modulation of the chelatable Zn pool in the brain by diethyldithiocarbamate is associated with behavioral impairment in adult zebrafish

Creator:: Braga, Marcos M., Silva, Emerson S., Rico, Eduardo P., Pettenuzzo, Leticia F., Oliveira, Diogo L., Dias, Renato D., Rocha, João B. T., Calcagnotto, Maria Elisa, Tanguay, Robert L., Souza, Diogo O., and Rosemberg, Denis B.
Abstract:: The study of the effects of diethyldithiocarbamate (DEDTC) in some diseases is in focus for many years. However, DEDTC is a metal chelator that can present neurotoxicity as side effects. Here we investigate the effect of DEDTC on brain Zinc (Zn) content and behavior. To address this issue we used...
Resource Type:: Article
Full Text:: Research, 4(2), 317-325. doi:10.1039/C4TX00111G 10.1039/C4TX00111G Royal Society of Chemistry Accepted

Combined radiocarbon and CO₂ flux measurements used to determine in situ chlorinated solvent mineralization rate

Creator:: Boyd, T. J., Montgomery, M. T., Cuenca, R. H., and Hagimoto, Y.
Abstract:: A series of combined measurements was made at the Naval Air Station North Island (NASNI) Installation Restoration Site 5, Unit 2 during July and August 2013. Combined measurements included CO₂ respiration rate, CO₂ radiocarbon content to estimate chlorinated hydrocarbon (CH) mineralization and a zone of influence (ZOI) model. CO₂ was...
Resource Type:: Article
Full Text:: ), 683-692. doi:10.1039/c4em00514g 10.1039/c4em00514g Royal Society of Chemistry Version of Record

Facile synthesis of one-dimensional peapod-like Sb@C submicron-structures

Creator:: Luo, Wei, Lorger, Simon, Wang, Bao, Bommier, Clement, and Ji, Xiulei
Abstract:: We demonstrate a novel synthetic route to fabricate a one-dimensional peapod-like Sb@C structure with disperse Sb submicron-particles encapsulated in carbon submicron-tubes. The synthetic route may well serve as a general methodology for fabricating carbon/metallic fine structures by thermally reducing their carbon-coated metal oxide composites.
Resource Type:: Article
Full Text:: peapod-like Sb@C submicron-structures. Chemical Communications, 50(41), 5435-5437. doi:10.1039

Synthesis and charge transport studies of stable, soluble hexacenes

Creator:: Purushothaman, Balaji, Parkin, Sean R., Kendrick, Mark J., David, Daniel, Ward, Jeremy W., Yu, Liyang, Stingelin, Natalie, Jurchescu, Oana D., Ostroverkhova, Oksana, and Anthony, John E.
Abstract:: Acenes larger than pentacene are predicted to possess enticing electronic properties, but are insoluble and prone to rapid decomposition. Utilizing a combination of functionalization strategies, we present stable, solution processable hexacenes and an evaluation of their hole and electron transport properties.
Resource Type:: Article
Full Text:: : DOI: 10.1039/c0xx00000x www.rsc.org/chemcomm Dynamic Article Links ► COMMUNICATION This

Catalytic Kinetic Resolution of a Dynamic Racemate: Highly Stereoselective β-Lactone Formation by N-Heterocyclic Carbene Catalysis

Creator:: Johnston, Ryne C., Cohen, Daniel T., Eichman, Chad C., Scheidt, Karl A., and Cheong, Paul Ha-Yeon
Abstract:: This study describes the combined experimental and computational elucidation of the mechanism and origins of stereoselectivities in the NHC-catalyzed dynamic kinetic resolution (DKR) of α-substituted-β-ketoesters. Density functional theory computations reveal that the NHC-catalyzed DKR proceeds by two mechanisms, depending on the stereochemistry around the forming bond: 1) a concerted, asynchronous...
Resource Type:: Article
Full Text:: -heterocyclic carbene catalysis. Chemical Science, 5(5), 1974-1982. doi:10.1039/C4SC00317A 10.1039/C4SC00317A

JiXiulei[David]ChemistryNewLowVoltagePlateauNa3V2(PO4)(3).pdf

Creator:: Jian, Zelang, Sun, Yang, Hu, Yong-Sheng, and Ji, Xiulei
Abstract:: A low-voltage plateau at ∼0.3 V is discovered during the deep sodiation of Na₃V₂(PO₄)₃ by combined computational and experimental studies. This new low-voltage plateau doubles the sodiation capacity of Na₃V₂(PO₄)₃, thus turning it into a promising anode for Na-ion batteries.
Full Text:: -ion batteries. Chemical Communications, 51(29), 6381-6383. doi:10.1039/c5cc00944h 10.1039/C5CC00944H

ChangChih-Hung(Alex)ChemicalBiologicalEnvironmentalEngineeringHighRateSynthesis.pdf

Creator:: Kim, Ki-Joong, Li, Yong Jun, Kreider, Peter B., Chang, Chih-Hung, Wannenmacher, Nick, Thallapally, Praveen K., and Ahn, Ho-Geun
Abstract:: The reaction conditions for the synthesis of Cu-BTC (BTC = benzene-1,3,5-tricarboxylic acid) were elucidated using a continuous-flow microreactor-assisted solvothermal system to achieve crystal size and phase control. A high-rate synthesis of Cu-BTC metal-organic frameworks with BET surface area of more than 1600 m²/g (Langmuir surface area of more than 2000...
Full Text:: :10.1039/c3cc46049e 10.1039/c3cc46049e Royal Society of Chemistry Accepted Manuscript http

Two-step continuous-flow synthesis of CuInSe₂ nanoparticles in a solar microreactor

Creator:: Kreider, Peter B., Kim, Ki-Joong, and Chang, Chih-Hung
Abstract:: A novel method of copper indium diselenide nanoparticle (CuInSe₂ NP) synthesis using a two-step, continuous flow, solar microreactor is reported here. This method allows for exceedingly fast heating and short reaction times using only radiative heat transfer from simulated, concentrated solar radiation. Chalcopyrite and sphalerite CuInSe₂ phases have both been...
Resource Type:: Article
Full Text:: ₂ nanoparticles in a solar microreactor. RSC Advances, 4(27), 13827-13830. doi:10.1039/C4RA00467A 10.1039

KimKi-JoongChemBioEnvEngPlasmonics-Enhanced.pdf

Creator:: Kim, Ki-Joong, Chong, Xinyuan, Kreider, Peter B., Ma, Guoheng, Ohodnicki, Paul R., Baltrus, John P., Wang, Alan X., and Chang, Chih-Hung
Abstract:: Combined plasmonic nanocrystals and metal–organic framework thin-films are fabricated for sensing gases in the near-infrared range. This nanocomposite thin-film shows a highly sensitive response in near-infrared absorption, which is attributed to preconcentration of gas molecules in metal–organic framework pores causing close proximity to the electromagnetic fields at the plasmonic nanocrystal...
Full Text:: Chemistry C, 3(12), 2763-2767. doi:10.1039/C4TC02846E 10.1039/C4TC02846E Royal Society of Chemistry

FullmerLaurenChemistryContrastingIonAssociation.pdf

Creator:: Fullmer, Lauren B., Molina, Pedro I., Antonio, Mark R., and Nyman, May
Abstract:: Small-angle X-ray scattering (SAXS) studies of aqueous [Ta₆O₁₉]⁸⁻ compared to prior studies of aqueous [Nb₆O₁₉]⁸⁻ reveals key differences in behaviour, which is likely at the root of the difficultly in developing polyoxotantalate chemistry. Specifically, where contact ion-pairing dominates between [Nb₆O₁₉]⁸⁻ and its counterions, solvent-separated ion-pairing between [Ta₆O₁₉]⁸⁻ and its counterions...
Full Text:: and Nb polyoxometalates. Dalton Transactions, 43(41), 15295-15299. doi:10.1039/C4DT02394C 10.1039

ScholarsArchive@OSU

Modulation of the chelatable Zn pool in the brain by diethyldithiocarbamate is associated with behavioral impairment in adult zebrafish

Combined radiocarbon and CO₂ flux measurements used to determine in situ chlorinated solvent mineralization rate

Facile synthesis of one-dimensional peapod-like Sb@C submicron-structures

Synthesis and charge transport studies of stable, soluble hexacenes

Catalytic Kinetic Resolution of a Dynamic Racemate: Highly Stereoselective β-Lactone Formation by N-Heterocyclic Carbene Catalysis

JiXiulei[David]ChemistryNewLowVoltagePlateauNa3V2(PO4)(3).pdf

ChangChih-Hung(Alex)ChemicalBiologicalEnvironmentalEngineeringHighRateSynthesis.pdf

Two-step continuous-flow synthesis of CuInSe₂ nanoparticles in a solar microreactor

KimKi-JoongChemBioEnvEngPlasmonics-Enhanced.pdf

FullmerLaurenChemistryContrastingIonAssociation.pdf

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