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  • The heteroatom effect in intramolecular cyclizations of organoaluminum and -lithium compounds

    Creator:
    Smith, Michael James
    Abstract:
    Intramolecular cyclization of organometallic compounds represents a promising tool for synthesis in general. The use of strategically- placed heteroatoms in the cyclizing molecule can influence the stereochemistry and/or efficiency of an organometallic cyclization while providing for functionality in the cyclic product. The work described herein first concerns cyclizations of organolithiums....
    Resource Type:
    Dissertation
    Full Text:
    in the cyclizing organo- metallic compound, thereby influencing the stereochemistry, regio