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Filtering by: Creator Vellucci, Jessica K. Subject Alkaloids -- Synthesis

Total Synthesis of Goniomitine : Development of Aminal and α-Amino Radicals in the Synthesis of Nitrogen-Rich Natural Products

Creator:

Vellucci, Jessica K.

Abstract:

Aminal radical intermediates were generated by the method of radical translocation and reacted in C-C bond forming reactions with electronically deficient alkenes (Schiedler et al. Org. Lett. 2012, 14, 6092). Aminal radical intermediates can participate in inter- and intra-molecular reactions using both Bu3SnH and (TMS)₃SiH as hydride donors. Carbon–carbon bonds...

Resource Type:

Dissertation

Full Text:

THE DISSERTATION OF Jessica K. Vellucci for the degree of Doctor of Philosophy in Chemistry