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Filtering by: Committee Member Humprey, Philip E. Remove constraint Committee Member: Humprey, Philip E. Subject Alkenes -- Synthesis Remove constraint Subject: Alkenes -- Synthesis

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  • Development of Methods for Stereoselective Carbon-Carbon Bond Formation

    Creator:
    Wu, Zhenhua
    Abstract:
    Three distinct methods to achieve the stereoselective synthesis of carbon-carbon bonds were investigated, encompassing: (i) the formation of axially chiral biaryl molecules by enantioselective Suzuki cross-coupling, (ii) the synthesis of α-phenylalkylboronic esters by enantioselective chain extension, and (iii) the stereospecific synthesis of alkenes by eliminative cross-coupling of enantioenriched sp³-hybridized carbenoids....
    Resource Type:
    Dissertation
    Full Text:
    the targeted alkene [(E)- or (Z)- isomer] as determined by choice of carbenoid stereochemical pairing