Inorganic structures play an important role in materials due to their versatility and diversity. A complete understanding of the structure of a material is vital to enhance the creation of new materials that fill voids in research. The rational design of these compounds is driven by the exploitation of structure-property...
The
experimental
procedure
for
evaporating
silicon
monoxide
together
with
the
methods
for
measuring
the film
thickness
have
been
investigated.
The
effects
of
various
process
parameters
on
the
rate
of
deposition,
such
as
source
temperature
and
source-substrate
distance,
have
been
studied.
The
uniformity
of
silicon
monoxide
films
deposited
by
this
particular...
Vacuum evaporated dielectrics for use in MOS structures
were studied in this research project. Dielectric
films were deposited on substrates by electron bombardment
evaporation of sapphire and quartz source materials.
These deposited films were studied using infrared spectroscopy,
index of refraction, density, and dielectric constant
measurements. Etching tests were also...
The theoretical characteristics of space-charge-limited
currents in solids are reviewed, and a survey of
suitable dielectric materials and experimental space-charge-limited devices is presented.
The properties of the gold-silicon contact as used
in space-charge-limited devices were experimentally investigated.
It was found that the observed characteristics
could be explained on the basis...
Dielectric ceramics designed for capacitor applications for use in extreme environments, such as high temperatures, high voltages, or high-pressure environments, are in great demand. Existing capacitor technology fails to perform within these extreme conditions or such environments. The development of new dielectric ceramic materials for high temperature capacitor applications is...
In this thesis the concept of inhomogeneous
dielectrics is demonstrated for various optical coating
applications. Compositionally-varying silicon oxynitride
(SiON) dielectric layers, with the refractive index
varying as a function of position, are grown by computer-controlled
plasma-enhanced chemical vapor deposition
(PECVD) using silane, nitrogen, and nitrous oxide reactant
gases. Compositionally graded...
Accurate modeling and simulation of wave propagation in dispersive dielectrics such as water, human tissue and sand, among others, has a variety of applications. For example in medical imaging, electromagnetic waves are used to interrogate human tissue in a non-invasive manner to detect anomalies that could be cancerous. In non-destructive...
We developed a model to investigate the dielectric properties of the
BaTiO₃ − Bi(Zn₁/₂Ti₁/₂)O₃ (BT-BZT) solid solution, which is a relaxor ferroelectric and exhibits long range disorder. The model uses ab initio methods
to determine all polarization states for every atomic configuration of 2 x 2 x 2
supercells of...
Nanolaminate dielectrics combine two or more insulating materials in a many-layered film. These structures can be made to significantly outperform films composed of a single one of their constituent materials by adjusting the composition ratio, arrangement, and size of the component layers. In this work, atomic layer deposition (ALD) is...
Amorphous oxide semiconductor (AOS) thin-film transistors (TFTs) constitute the central theme of this thesis. Within this theme, three primary areas of focus are pursued.
The first focus is the realization of a transparent three-stage ring oscillator with buffered output and an output frequency in the megahertz range. This leads to...
Crystals of an incongruent-melting compound, Ba₃MgSi₂O₈, were grown by the flux method and its structure was determined by single crystal X-ray diffraction methods. Ba₃MgSi₂O₈ crystallizes in trigonal space group P-3[bar]m1 with a = 5.6123(3) Å, c = 7.2667(9) Å and Z = 1. Eu²⁺ ions prefer one crystallographic Ba site...
Periodic metal and metal-dielectric composite nanostructures have been of interest from the field of plasmonics and metamaterial fabrication. In order to exploit the behavior of these unique materials in the visible region of the optical spectrum, these structures need to be significantly shorter than the wavelength of response, and hence...
Since its discovery, the anomalous dielectric behavior of CaCu₃Ti₄O₁₂ (CCTO)
has drawn a great deal of attention for many possible applications in electronic
devices. The origin of the giant dielectric constant in CCTO was explained via an
internal barrier layer capacitor model, and it has been reported that the dielectric...
A new group of lead free piezoelectric perovskite solid solutions, (1-x)Bi(B'B")O₃-xABO₃, were obtained via solid-state processing techniques. The solubility of unstable perovskite Bi(B'B")O₃ compounds into stable perovskite compounds was found to be related to the tolerance factor of the ABO₃ perovskite endmembers. The morphotropic phase boundary (MBP) in perovskite solid...