Methane is a product of biogeochemical processes which respond to changes in climate. The history of atmospheric methane is recorded by ice cores providing insight into past changes in these biogeochemical processes. This dissertation is comprised of three studies which focus on centennial- and millenial-scale variability of methane from ice...
Two methanotrophs, M. trichosporium OB3b and M. buryatense 5GB1, were encapsulated using two methods to investigate the potential of methane conversion for biofuel production. Ca-alginate and low melt agarose were used to immobilize the methanotrophs for batch and continuous flow column testing. Varying protein concentrations, residence times, and immobilization methods...
Atmospheric pressure plasma is non-thermal at millimeter to micrometer separations. It represents an alternative low exergy initiator of many chemical reactions. In many instances heat, light or sound are not efficient providers of the necessary energy to overcome chemical activation barriers. The focus of this research is applying dc nonthermal...
The spectrophone method for the study of vibrational relaxation
has been claimed to possess a distinct advantage over the more commonly
used ultrasonic techniques in that it permits the relaxation of
the various infrared-active vibrational modes in a polyatomic molecule
to be studied separately. A discussion of the rate equations...
Quantifying the mass transport through marine sediments, and the geochemical response to such flow with numerical models has become a common and powerful approach for geochemical data interpretation. In this dissertation, I developed and applied transport-reaction models to unravel complex and interdependent reactions involving carbon, sulfur and silica transformations in...
Marine sediments contain an abundance of methane that is biologically produced
and plays a significant role in the global carbon cycle. Microbes responsible for the
carbon cycle in marine sediments, and the processes that they carry out, need to be
characterized in order to fully understand the role of this...