Recent efforts show that microchannel technologies have much to offer the field of nanomanufacturing: the structuring of matter on the order of one billionth of a meter. During the synthesis of nanomaterials, microchannel reactors take advantage of large surface-to-volume ratios to accelerate heat and mass transport. This accelerated transport allows...
Nonthermal plasmas generate high concentrations of excited species that can simultaneously exist at high energy and far from thermodynamic equilibrium, making them useful tools in chemistry and engineering. Microplasmas, roughly defined as plasmas that are generated within sub-millimeter dimensions, provide enhanced stability, improved excited species density, increased nonequilibrium properties, higher...
Recent advances in nanocrystalline materials production are expected to impact the development of next generation low-cost and/or high efficiency solar cells. For example, semiconductor nanocrystal inks are used to lower the fabrication cost of the absorber layers of the solar cells. In addition, some quantum confined nanocrystals display electron-hole pair...
Metal oxide nanocrystals have attracted significant interests due to their unique chemical, physical, and electrical properties which depend on their size and structure. In this study, a continuous flow microreactor system was employed to synthesize metal oxide nanocrystals in aqueous solution. Assembly of nanocrystals is considered one of the most...
In this work, continuous synthesis routes for binary nanoparticles using advantages of microchannel mixing (low diffusion distances and higher mass transfer) and fast heating rates provided by ultrasound induced heating are investigated. In addition, the application of silica nanoparticles in anti-reflective coatings on glass and understanding the structure property-performance correlation...
Microreactors offer high rates of heat transfer able to intensify highly endothermic biomass reforming reactions in supercritical water. In this study, two continuous flow microreactor configurations were used to gasify biomass constituents in supercritical water. The first reactor configuration was a micro diameter stainless steel or Hastelloy tube (508 µm...
Fischer-Tropsh Synthesis is a chemical process that converts CO and H₂ (syngas) into long stable hydrocarbon chains to use as fuel. This process suffers from large product distribution that requires expensive post processing. In this study, the reaction mechanism of hydrocarbon chain growth on Co is investigated on different surface...
Sulfur content in fuel is an increasingly important environmental concern. A
commonly used method for the removal of sulfur bearing species from fuel is
through hydrodesulphurization. However, due to the implementation of Ultra-Low
Diesel Sulfur (ULDS), deeper desulphurization techniques must be explored. In this
study, a single phase oxidative desulphurization...
Sulfur content in fuels is an increasingly critical environmental issue. Hydrodesulfurization removes sulfur from hydrocarbons; however, further desulfurization is necessary in fuels. New methods are required. In this study, micro-scaled single phase oxidative desulfurization is explored. An ultraviolet light-assisted micro-reactor is introduced for desulfurization of dibenzothiophene.
Dibenzothiophene is mixed with...
Atmospheric pressure plasma is non-thermal at millimeter to micrometer separations. It represents an alternative low exergy initiator of many chemical reactions. In many instances heat, light or sound are not efficient providers of the necessary energy to overcome chemical activation barriers. The focus of this research is applying dc nonthermal...