A method by which barrier heights in potential functions
hindering internal rotation in organic molecules can be obtained solely
from thermal data for the solid phase is studied. The observed
heat capacities are analyzed in terms of contributions from the lattice
vibrations, the intramolecular vibrations, the expansion of the lattice,...
Theoretical studies and experimental results are presented for the rotational motion of molecule's in crystalline solids. The group theory is solved for molecules of any symmetry matrix isolated at a site in a crystal field of any symmetry. As the potential terrier to rotation of the molecule relative to the...