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Filtering by: Committee Member Johnson, J. G. Remove constraint Committee Member: Johnson, J. G. Subject Stereochemistry Remove constraint Subject: Stereochemistry

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  • Towards the Routine Computational Investigation of Complex Organocatalysis and Reaction Processes

    Creator:
    Ogba, O. Maduka
    Abstract:
    In this Dissertation, the mechanism and stereomechanics of complex organocatalysis and reaction processes are disclosed. The technologies and protocols currently being developed and utilized to efficiently investigate these systems using theory are highlighted. A detailed computational study of peptide-catalyzed acylations is disclosed. In particular, the magnitude of all possible non-bonding...
    Resource Type:
    Dissertation
    Full Text:
    ., Int. Ed. 2000, 39, 1352. 
 11 Hajos, Z. G.; Parrish, D. R. J. Org. Chem. 1974, 39, 1615. 12 List, B

  • Development of Methods for Stereoselective Carbon-Carbon Bond Formation

    Creator:
    Wu, Zhenhua
    Abstract:
    Three distinct methods to achieve the stereoselective synthesis of carbon-carbon bonds were investigated, encompassing: (i) the formation of axially chiral biaryl molecules by enantioselective Suzuki cross-coupling, (ii) the synthesis of α-phenylalkylboronic esters by enantioselective chain extension, and (iii) the stereospecific synthesis of alkenes by eliminative cross-coupling of enantioenriched sp³-hybridized carbenoids....
    Resource Type:
    Dissertation