Shan-Mei, a Tsou aboriginal village in Taiwan, is widely known as a legend of environmental conservation, where ecotourism has been successfully combined with integrated community development. Indigenous knowledge containing "ecological wisdom" and decision-making based on consensus are perceived to be the greatest contributors to this achievement. I conducted three months...
Sulfoxide-ligand exchange (SLE) and asymmetric halogen-metal exchange (AHME) processes were separately examined for the enantioselective synthesis of functionalized alpha-haloalkylmetal (carbenoid) reagents. Carbenoids derived from SLE were used to effect stereospecific reagent-controlled homologation (StReCH) of boronic esters and those generated via AHME were engaged in Darzens-type chemistry with aldehydes.
Abstract for...
In this dissertation, a novel method for analyzing computed transition states (TS) for organic reactions is disclosed. It introduces the use of localization-delocalization matrices as parameters in a linear free energy relationship to determine the transition state interactions responsible for differences in energy between the major and minor TS in...
The Mount Fubilan Intrusion is part of a geologically young hypabyssal stock in the Star Mountains of Papua New Guinea. This stock was mapped as the Ok Tedi Intrusive Complex and divided into four separate bodies: the Mount Fubilan, Sydney Intrusion, Kalgoorlie, and Ningi Intrusions. Hydrothermal fluids caused alteration of...
Iterative algorithms are simple yet efficient in solving large-scale optimization problems in practice. With a surge in the amount of data in past decades, these methods have become increasingly important in many application areas including matrix/tensor recovery, deep learning, data mining, and reinforcement learning. To optimize or improve iterative algorithms,...