Ambifunctional axially chiral 2,2',6,6'-tetrasubstituted biphenyls containing nucleophilic (or basic) functional groups juxtaposed with hydrogen-bond donors were synthesized and their properties studied. Applications for the prepared biaryls as potential organocatalysts for enantioselective carbon-carbon bond forming reactions were examined. Processes investigated included: aldol, Michael, nitroaldol (Henry), and Baylis-Hillman reactions.
The novel amidoamine...
A concern which has restricted the use of parthenocarpic pickling cucumbers in the
United States has been firmness of fruit processed by brining. Fruit firmness and defects
of parthenocarpic and nonparthenocarpic pickling cucumbers were evaluated in 1992 and
1993. Fruits were produced with or without pollination by growing plants with...
The Central American Free Trade Agreement (CAFTA) is between the United States and Costa Rica, Nicaragua, Honduras, Guatemala, El Salvador and the Dominican Republic. CAFTA was decided in Costa Rica by a national referendum in 2007, after years of delay that left Costa Rica as the only country to have...
How the direct and indirect effects of species interactions cascade to affect community structure, functioning, and stability is a fundamental question in ecology. In temperate kelp forests, species interactions, in conjunction with environmental processes, produce rich spatiotemporal dynamics.
Arguably the most dramatic of these are abrupt shifts in community state,...
The United States is struggling to improve the educational attainment of high school students in order to meet workforce needs and remain internationally competitive. Fewer than 80% of U.S. students graduate from high school despite 30 years of policy initiatives aimed at improving graduation rates. This study focuses on completion...
Information about social and economic attributes of fisheries, fishing communities, and fishery participants is important for marine resource management because the focuses of agency efforts are on managing society's impacts to the marine environment. This thesis addresses two questions. First, what are the perspectives of managers, scientists, and commercial and...
In recent decades, local governments have desired to increase community engagement in collaborative governance processes, such as community visioning and strategic planning, in an effort to develop policies that are inclusive and supportive of those who live in the community. A key component of the community visioning process is the...
A central challenge for ecology is to understand the dynamic nature of species interactions. A classic approach to community ecology assumes that individuals within a species are functionally identical and that consumer-resource dynamics can be predicted solely by using species abundances. However, one species can consist of multiple functional groups,...
Recent scientific studies show that framing climate change as a health issue rather than an environmental issue were more persuasive with American audience members (Maibach et. al., 2010; Maibach et. al. 2014). Also in 2014, a survey on respiratory healthcare providers and found that a large percentage believed that climate...
Globally, access to safe, reliable drinking water sources is a major challenge of this generation. Protected sources of drinking water provide communities with a sustainable, vital resource, yet many public water suppliers lack legal authority over their source water protection (SWP) area, especially in surface water systems. Absence of legal...