The topics in this dissertation are centered around the way that trees respond to environmental stress in the climates where they occur. Though forests across the planet are expected to experience change in local climate due to historic and ongoing anthropogenic greenhouse gas emissions, the effects of climate change will...
Previous research has shown significant improvements in standard measurements of student learning in traditional classroom settings when constructivist instruction techniques are skillfully applied as opposed to its traditional counterpart, direct instruction. The purpose of this study is to apply the concept of constructivism in musical instruction. The working hypothesis is...
Since the discovery of molecular chirality in 1848, this notion has had a substantial impact on medicine, biology, and chemistry. Extensive effort has been directed towards the construction of chiral molecules that contain sp³ hybridized stereogenic centers. In contrast, less effort has been dedicated to molecules that are chiral by...
Political Polarization in the United States is at a level higher today than at any point in the past few decades. Possible causes of this rise in polarization have been provided from various sources, including explanations such as mass media and income inequality. Through historical analysis and a wide literature...
Organic compounds which contain one or more nitrogen atoms are especially important as they are disproportionately represented among biologically active molecules. As a result, significant effort has been focused on the development of methods for the synthesis of nitrogenous molecules. We identified the aminal as an under-explored functional group. Despite...
The first part of this manuscript is about the total synthesis of the aspidosperma alkaloids leuconoxine, melodinine E and mersicarpine. Our synthetic strategy used a radical translocation-conjugate addition cascade to construct the core of the natural product. Specifically, a vinyl radical was generated from the homolysis of the C–I bond...
Drone strikes have become a defining strategy in the US War on Terror. Since the first combat drone strike in 2001, the executive branch has intentionally increased the deployment of drones for counterterrorism operations throughout the Middle East and North Africa. This thesis explores the moral and legal justifications for...
Aminal radical intermediates were generated by the method of radical translocation and reacted in C-C bond forming reactions with electronically deficient alkenes (Schiedler et al. Org. Lett. 2012, 14, 6092). Aminal radical intermediates can participate in inter- and intra-molecular reactions using both Bu3SnH and (TMS)₃SiH as hydride donors. Carbon–carbon bonds...
Dearomatization reactions exist broadly in biosynthesis and chemical synthesis. The highly functionalized atoms of arenes can be masked by it aromaticity, and upon dearomatization, those reactive atoms can be readily applied to bond formation and further manipulation. The total synthesis of (–)-cephalotaxine and (–)- homoharringtonine is described via an oxidative...
U.S. foreign policy during the period between World War II and the Vietnam War has been described as part of a “nation-‐building” or “liberal” grand strategy. This thesis contends that understanding U.S. efforts to influence the internal affairs of sovereign states through the spread of liberal values and institutions during...