The purpose of this project was to study the reactions of 1-(α-pyridyl)-3-buten-1-ol (compound I) and to determine whether or
not the products of some of its reactions are quinolizinium salts.
Reaction of compound I with bromine or iodine yields halide
salts (when no external cooling is applied) instead of the...
Part I
The pyrolysis of cis- and trans- 1, 2-divinyl-1- trimethylsiloxy -
cyclohexane, II- and III-TMS, under the same conditions as the
pyrolysis of cis-l-vinyl -1-trimethylsiloxycyclooct-3-ene, I-TMS,
confirms that a sequence of concerted reactions for the rearrangement
of II- and III-TMS to trans-l-trimethylsiloxycyclodec-3-ene,
IV-TMS, is a viable pathway in the...
This thesis objective is to examine the relationship between individuals' goal orientations (learning-prove, learning-avoid, performance-prove, and performance-avoid) and the extent to which they provide knowledge. Included in this document is a review of literature pertaining to knowledge sharing and goal orientations. The author surveyed 64 College of Pharmacy students at...
Non-radial measure of technical efficiency of fish farms in Oyo State was examined using Data Envelopment Analysis (DEA). Use of the non-radial measures to calculate overuse of inputs by inefficient fish farmers was demonstrated and the potential for reducing inputs used by improving efficiency was evaluated. Ordinary Least Square (OLS)...
This analysis determines the impact of campaign contributions on Senators' legislative activity on the Energy Policy Act of 2003, identifies organizations within the power policy-planning network, and examines the social netwrok of the energy industry and its relationship with the power policy-planning network. After describing the research methods used for...
In this Letter, we investigate the slow-light effect of subwavelength diffraction gratings via the Rayleigh anomaly using a fully analytical approach without needing to consider specific grating structures. Our results show that the local group velocity of the transmitted light can be significantly reduced due to the optical vortex, which...
The retro-ene reaction of 2-vinylcyclohexanols occurs readily
in the vapor phase at 400-450° producing unsaturated carbonyl
compounds in good yields. The starting- materials were prepared in
general by the carbenoid addition reaction of ethyl diazoacetate,
appropriately substituted cyclohexene, and copper catalyst to
produce bicyclic esters which were reduced to the...
The potassium salts of a series of 1-vinylcycloalk-3-en-l-ols were found to undergo ring expanding [1, 3]-sigmatropic shifts at 25° when dissolved in hexamethylphosphoramide (HMPA) or 1, 2-dimethoxyethane (DME) with 18-crown-6. The yields and reaction rates were compared with those of the corresponding Siloxy-Cope ring expansions. These anionic cases showed about...
Levee management has historically been considered a local governance issue. Many users of the Portland International (PDX) airport may have no knowledge that the airport is in a floodplain and is protected by a hundred year old levee. This study asked survey respondents across the U.S. how much they would...
This study examines the association of household characteristics with forest product consumption and other benefits derived from community forest in Nepal. The analysis is based on random sample data of 80 households from a Community Forest User Groups of Baghmara Community Forestry (BCF) in Nepal. Using an OLS regression to...