A new approach towards a total synthesis of paeoniflorigenin is discussed. The approach involves the application of regio- and stereoselective [2+2] photocycloaddition for the preparation of a key intermediate, cyclobutanone 86, and model studies on diiodosamarium (Sm12) mediated pinacol coupling of a diketone. Intermolecular [2+2] photocycloaddition of a,13unsaturated lactam 33...
There is a new possibility of generating deep ultraviolet laser radiation from a solid-state source. With recent advances in material development, a new nonlinear optical crystal provides a greater damage threshold than current materials making higher conversion efficiencies possible.
This thesis examines the possibility of using this crystal to generate...
The Open Modeling Environment (OME) is a tool developed to address some known shortcomings in ecological System Dynamics (SD) modeling research. OME provides a common set of methods for interacting directly with spatial information, reducing the need for modelers to create their own methods for doing so. The environment is...
This study explores No Child Left Behind's required timetable for English language learners (ELLs) to reach English language proficiency within five years, as outlined in the Annual Measurable Achievement Outcomes (AMAOs), despite the lack of research evidence to support this as a reasonable expectation. Analysis was conducted on the archived...
The purpose of this research project was to gain a deeper understanding of the
lived experience of faculty of color. More specifically, this project explores how
diversity-related workload expectations impact faculty of color who work in
predominantly white community colleges. Known by various descriptors, the term
used in this research...
Asymmetric tensor fields are useful for understanding fluid flow and solid deformation. They present new challenges, however, for traditional tensor field visualization techniques such as hyperstreamline placement and glyph packing. This is because the physical behavior of tensors inside real domains where eigenvalues are real is fundamentally different from the...
Ferrites have been used for various high frequency applications as bulk
materials. These applications, however, are limited to large dimension devices. In
this thesis, thin film ferrites were deposited from a low temperature solution-based
deposition process that is suitable for micro-scale high frequency applications. The
low temperature nature of this...
Much work is presently being done concerning small scale heterogeneities in the
earth's crust. These heterogeneities range from pores in sedimentary rocks up to
fluctuations in the density and seismic constants of the earth's crust with scale lengths
of kilometers. The ability to study and quantify these heterogeneities using seismic...
While primary use of Global Navigation Satellite System (GNSS) is positioning, navigation, and timing (PNT), various GNSS applications have emerged over the past decades that includes GNSS meteorology. GNSS meteorology is the remote sensing of the atmospheric constituents in the neutral atmosphere – mostly in the troposphere - using GNSS...