Many bridges along the Gulf Coast of the United States were damaged by recent hurricanes, and many more are susceptible to similar damage. This research examines performance of common anchorage connection details for AASHTO Type III prestressed concrete girders used by some transportation agencies. Full-scale specimens were fabricated and tested...
The first part of this manuscript is about the total synthesis of the aspidosperma alkaloids leuconoxine, melodinine E and mersicarpine. Our synthetic strategy used a radical translocation-conjugate addition cascade to construct the core of the natural product. Specifically, a vinyl radical was generated from the homolysis of the C–I bond...
We map the regional physiography and surficial lithology (Surficial Geologic Habitat or
SGH) over the continental margin of Oregon. This thesis develops, describes, and
implements an iterative interpretive method to map seafloor habitat types from disparate
geological and geophysical datasets including: bathymetric images, sidescan sonar
images, seismic reflection profiles, sediment...
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AN ABSTRACT OF THE THESIS OF
Christopher G. Romsos for the
Organic compounds which contain one or more nitrogen atoms are especially important as they are disproportionately represented among biologically active molecules. As a result, significant effort has been focused on the development of methods for the synthesis of nitrogenous molecules. We identified the aminal as an under-explored functional group. Despite...
Aminal radical intermediates were generated by the method of radical translocation and reacted in C-C bond forming reactions with electronically deficient alkenes (Schiedler et al. Org. Lett. 2012, 14, 6092). Aminal radical intermediates can participate in inter- and intra-molecular reactions using both Bu3SnH and (TMS)₃SiH as hydride donors. Carbon–carbon bonds...
G.K. Chesterton once stated, “I am concerned with a certain way of looking at life, which was created in me by the fairytales, but has since been meekly ratified by the mere facts….The only words that ever satisfied me as describing Nature are the terms used in the fairy book,...
The bimolecular reaction of two carbenoid species resulting in the formation of a carbon-carbon double bond (pi-system), referred to herein as carbenoid eliminative cross-coupling (CEXC), involves a series of three fundamental steps: (i) ate-complex formation (transmetalation), (ii) 1,2-metalate rearrangement, and (iii) beta-elimination. All three steps are stereospecific and so the...
We took the back-propagation algorithms of Werbos for recurrent and feed-forward neural networks and implemented them on machines with graphics processing units (GPU). The parallelism of these units gave our implementations a 10 to 100 fold increase in speed. For nets with less than 20 neurons the machine performed faster...
From 1925 to 1930, Ernest H. Wiegand, a professor of Horticultural Products at Oregon State Agricultural College, developed an improved brining process for cherries. Brined cherries are used in the production of maraschino and glacé cherries, which already had a sizable market in the United States by the 1920s. This...