Surface heat flux components are estimated at a midshelf site over the northern California shelf using moored measurements from the 1981-1982 Coastal Ocean Dynamics Experiment (CODE) and the 1988-1989 Shelf Mixed Layer Experiment (SMILE). Time series of estimated fluxes extend from early winter through summer upwelling conditions, allowing examination of...
Azaspiracid-1, a novel marine toxin that contains 9 rings and 20 stereogenic centers, has drawn considerable attention from synthetic groups worldwide due to its structural complexity, which includes a unique trioxabisspiroketal fused to a tetrahydrofuran ring (ABCD rings), a piperidine-tetrahydrofuran spiroaminal system fused to a 2,9-dioxabicyclo[3.3.1]nonane system (FGHI rings), a...
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I would like to thank my committee members, Prof. Paul R. Blakemore, Prof.
Christopher M. Beaudry
This study was conducted to determine if there were
possible areas of student individuality and uniqueness
that might contribute to successful completion of distance
education courses as compared to successful completion of
traditional classroom courses. Five areas of possible
differences were identified and studied: 1) differences
between the number of...
Studies toward the total synthesis of (+)-providencin (1), a highly oxygenated cembranoid dipterpene with a unique bicyclo[12.2.0]hexadecane skeleton and pronounced biological activity, are described. These studies resulted in the synthesis of advanced intermediates 320 and 332 which contain all of the carbon atoms of 1. In a first generation approach...
Stream temperatures were monitored on seven low-elevation western Oregon streams immediately after clearcut harvesting and 14-17 years later in two studies that examined buffer designs. One study on four streams used no-tree buffers with all trees next to the stream harvested within the clearcut units. The second study on three...
Pharmaceuticals, molecular catalysts, and secondary metabolites often contain nitrogen. The problems faced synthesizing compounds which contain nitrogen was because of the Lewis base reactivity of nitrogen lone pairs, and the acidic protons of some nitrogenous functional groups. We developed two methods for the synthesis of nitrogeous compounds. Additionally, we successfully...
The effect of some factors that can affect quality characteristics of broccoli
florets in storage was evaluated. Quality characteristics of broccoli florets with
different rates of field nitrogen (N) application (0, 90, 180, and 270 Kg N/ha from
urea) were evaluated in modified atmosphere packaging (MAP) (B-900 Cryovac
film) storage...
Enantioenriched sp³-hybridized carbenoid reagents CR1R2MX (X = nucleofuge, M = electrofuge) of different types were investigated for the synthesis of polysubstituted alkyl chains by iterative stereospecific reagent-controlled homologation (StReCH) and for the stereospecific connective synthesis of alkenes by eliminative cross-coupling.
In the first part, putative enantioenriched α-chloroalkyllithiums (CHRLiCl) were employed...
The bimolecular reaction of two carbenoid species resulting in the formation of a carbon-carbon double bond (pi-system), referred to herein as carbenoid eliminative cross-coupling (CEXC), involves a series of three fundamental steps: (i) ate-complex formation (transmetalation), (ii) 1,2-metalate rearrangement, and (iii) beta-elimination. All three steps are stereospecific and so the...