While the d⁰ transition-metal POMs of Group V (V⁵⁺, Nb⁵⁺, Ta⁵⁺) and Group VI (Mo⁶⁺, W⁶⁺) have been known for more than a century, the actinyl peroxide POMs, specifically those built of uranyl triperoxide or uranyl dihydroxidediperoxide polyhedra, were only realized within the last decade. While virtually every metal on...
We, for the first time, employ magnesiothermic reaction to convert microwave-irradiated graphite oxide to pure graphene. The magnesiothermic reaction raises the carbon to oxygen atomic ratio from 22.2 to 165.7 and maintains a high surface area. The new strategy demonstrates an efficient method for obtaining highly pure graphene materials.
Assembly of nanocrystals is considered one of the most promising approaches to design nano-, microstructures, and complex mesoscopic architectures. A variety of strategies to induce nanocrystal assembly have been reported, including directed assembly methods that apply external forces to fabricate assembled structures. In this study ZnO nanocrystals were synthesized in...
The aggregation of 12 nm citrate-stabilized gold nanoparticles (cit-AuNPs) in the presence of four
different natural organic matter (NOM) isolates and a monovalent electrolyte (KCl) was evaluated using
time-resolved dynamic light scattering. All four NOM isolates stabilized the cit-AuNPs with respect to
aggregation. However, specific effects varied among the different...
There is increasing evidence that aging is affected by biological (circadian) clocks – the internal mechanisms that coordinate daily changes in gene expression, physiological functions and behavior with external day/night cycles. Recent data suggest that disruption of the mammalian circadian clock results in accelerated aging and increased age‐related pathologies such...
A series of combined measurements was made at the Naval Air Station North Island (NASNI) Installation Restoration Site 5, Unit 2 during July and August 2013. Combined measurements included CO₂ respiration rate, CO₂ radiocarbon content to estimate chlorinated hydrocarbon (CH) mineralization and a zone of influence (ZOI) model. CO₂ was...
Carbon 1s photoelectron asymmetry parameters β for the chlorinated and the methyl carbon atom of CH₃CH₂Cl, CH₃CHCl₂, and CH₃CCl₃ have been measured using synchrotron radiation in the 340-600 eV energy range. We provide experimental evidence that the intramolecular scattering strongly affects beta values, even far from the ionization threshold. The...