A practical and versatile instrument has been developed both to
optimize the chemistry of bio- and chemiluminescence reactions and to
measure ultra-trace quantities of associated analytes. The instrument
consists of a pneumatic flow injection system linked to a detection cell and a
signal processing and readout system. The disk-like cell...
An automated instrument based on a single-board microcomputer
was developed for use in voltammetric analyses. Operator input of
numerous experiment parameters allows any type of voltammetric
analysis to be implemented and multiple scans to be run unattended.
A three operational amplifier potentiostat is used to control
the cell voltage and...
Sulfide is an important species to measure in environmental water samples. The
spectrophotometric detection method for reduced sulfur species (sulfide) based on
generation of methylene blue was adapted to work in an apparatus utilizing microfluidic
PDMS mixing and observation cells with flow channels in the 100 μm range. The
benefits...
The effects of possible operating variables such as flow rate, surface temperature, bulk temperature, solids contents, sulfate addition and pH on the fouling of sulfite spent evaporators were studied. The study pointed out that the Ca⁺⁺ concentration difference between heated surface and bulk is the most important factor for fouling...
Two related techniques, based upon ion-exchange solid phase extraction, have been
developed for the determination of arsenic speciation. The inorganic arsenic species
arsenite (As(III)) and arsenate (As(V)) are separated by anion-exchange and detected with
graphite furnace atomic absorption spectrophotometry (GFAAS) with a nickel matrix
modifier. The first separation technique, which...
The development and optimization of a single-phase derivatization
technique for small ring aromatics in water are presented. Also
described are the design, optimization and application of a remote
reaction chamber for fiber optic sensing.
Aqueous solutions of the major aromatic compounds in gasoline are
derivatized to o-nitrosophenol-Cu complexes with a...
A novel, portable, filter fluorometer was developed for the determination of chloroform and TCE at environmentally-relevant levels when coupled with improved sampling techniques and reagents. Reagents selective for the TCE or chloroform convert these toxic species into fluorescent species that can be monitored. The fluorometer is based on LED excitation...
My thesis examines how the American identity is constructed through thinking shaped by deception and domination, as James Baldwin argues in the corpus of his work. I rely on the work of Eddie Glaude Jr., Sean Kim Butorac, and Joel Schlosser to forward love in Baldwin’s political vision as being...
The recent development of the laser has made possible
communications with a beam of coherent light.
Since coherent light offers great advantages over radio
in the areas of beam directivity and information capacity,
optical communication systems have been proposed
for many uses.
The first section of this thesis gives a...
William James came of age at a time of great social and intellectual change in the United States. During this period, new professional identities proliferated, and a new culture of professionalization developed with important ramifications for conceptions of individual and social identity. Professionalization was also closely related to key intellectual...