The dipyridophenazine (dppz) based ruthenium polypyridyl complexes are known as molecular ‘light-switches’ for DNA. This property is poised to serve in diagnostic and therapeutic applications, but the poor cellular uptake restricts their use in live cells. Herein, we show that the cellular uptake, and more interestingly and surprisingly, the nuclear...
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observed between the two chiral
forms of Ru(II) complexes. This represents the first report of an
A selective and label-free biosensor for detection of the explosive compound 2,4,6-trinitrotoluene (TNT) in aqueous solution was developed based on the principle of photoluminescence quenching of upon immunocomplex formation with antibody-functionalized diatom frustule biosilica. The diatom frustule is an intricately nanostructured, highly porous biogenic silica material derived from the shells...
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biosilica was measured by this principle. We report the fabrication,
selectivity, and sensitivity of this
Shrimp shell powders (SSP) were fermented by successive two-step fermentation of Serratia marcescens B742 and Lactobacillus plantarum ATCC 8014 to extract chitin. Taguchi experimental design with orthogonal array was employed to investigate the most contributing factors on each of the one-step fermentation first. The identified optimal fermentation conditions for extracting...
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infrared spectrometer (FT-IR), and X-ray diffraction (XRD) assays. 86
Base on our best knowledge, no
A major issue in non-inferiority trials is the controversial assumption of constancy,
namely that the active control has the same effect relative to placebo as in previous studies
comparing the active control with placebo. The constancy assumption is often in doubt, which
has motivated various methods that ‘discount’ the control...
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effects δ01.x/
and δÅ01.x/ to differ. Thus assumption (3) no long holds, and equation (4) is generally
We report vibrational information of both the first electronically excited state and the ground
cationic state of jet-cooled triphenylene via the techniques of resonantly enhanced multiphoton
ionization (REMPI) and zero kinetic energy (ZEKE) photoelectron spectroscopy. The first excited
electronic state S₁ of the neutral molecule is of A₁' symmetry and...
In this dissertation, I present electronic spectra of a few polycyclic aromatic hydrocarbons (PAHs): tetracene, pentacene, pyrene, benzo[g,h,i]perylene and benzo[a]pyrene using resonantly enhanced multiphoton ionization (REMPI) and zero kinetic energy (ZEKE) photoelectron spectroscopy. The work of tetracene and pentacene also combine a laser desorption source with a ZEKE spectrometer, demonstrating...
In this dissertation, I describe spectroscopic studies of jet-cooled polycyclic aromatic hydrocarbons (PAH) and one nitrogen substituted PAH (PANH) using pulsed field zero kinetic energy (ZEKE) photoelectron spectroscopy and resonantly enhanced multiphoton ionization (REMPI) spectroscopy. Recently, there has been a demand for far-infrared (FIR) spectral information of astrophysically relevant molecules...
We report zero kinetic energy (ZEKE) photoelectron spectroscopy of benzo[a]pyrene (BaP) via resonantly enhanced multiphoton ionization (REMPI). Our analysis concentrates on the vibrational modes of the first excited state (S₁) and those of the ground cationic state (D₀). Similar to pyrene, another peri-condensed polycyclic aromatic hydrocarbon we have investigated, the...
We report zero kinetic energy (ZEKE) photoelectron spectroscopy of benzo[h]quinoline (BhQ) via resonantly enhanced multiphoton ionization (REMPI) through the first electronically excited state S₁. From the simulated REMPI spectra with and without Herzberg–Teller coupling, we conclude that vibronic coupling plays a minor but observable role in the electronic excitation to...
Joseph Reddeford Walker conducted
a party of men across the Sierra Nevada to the
Pacific coast of California in 1833. Previous
interpretations of the portion of the route
from Humboldt Sink, Nevada, to the San Joaquin
River, California, are not satisfactory. A
body of descriptions of the terrain traversed
exists...
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sufficient body of information
2
concerning the travels of this party, there has been as yet
no common