Organic compounds which contain one or more nitrogen atoms are especially important as they are disproportionately represented among biologically active molecules. As a result, significant effort has been focused on the development of methods for the synthesis of nitrogenous molecules. We identified the aminal as an under-explored functional group. Despite...
The enantioselective total synthesis of quinolizidine-containing natural product cermizine D and formal syntheses of senepodine G and cermizine C has been achieved. These natural products are members of the lycopodium alkaloids, which have attracted significant attention due to their exciting biological activities and the diverse structural scaffolds. Key steps in...
Complex organic transformations, such as the addition of pyrrole to ketene using planar chiral organocatalyst (*PPY), the four-component anhydride- Manniach reactions, and the site-selective desymmetrization of meso-1,2-diol, are remarkable synthetic reactions that provide high yield and high selectivity. However, the exact mechanism and origins of stereocontrol for theses synthetic organic...
The scale of pest and disease dispersal is often larger than the scale of individual farms. Therefore, an individual grower’s response to pests and diseases can affect and is affected by their surrounding growing region. Individual growers are also not isolated, and engage in various forms of information gathering, sharing,...
Managing Microdochium patch on intensively manicured annual bluegrass putting greens is a challenge for turfgrass professionals in cool-humid climates similar to the Pacific Northwest. Fungicides are the predominant means to mitigate damage caused by this fungal pathogen, however pesticide restrictions are making it even more challenging to suppress Microdochium patch....
Structure-property relationships have always underpinned the field of solid state chemistry; dependable structural descriptions are integral to understanding and controlling the physical properties of inorganic compounds old and new. While a handful of crystal structures are celebrated for their versatility, flexibility, and functionality, the existence of more exotic structures is...
Azaspiracid-1, a novel marine toxin that contains 9 rings and 20 stereogenic centers, has drawn considerable attention from synthetic groups worldwide due to its structural complexity, which includes a unique trioxabisspiroketal fused to a tetrahydrofuran ring (ABCD rings), a piperidine-tetrahydrofuran spiroaminal system fused to a 2,9-dioxabicyclo[3.3.1]nonane system (FGHI rings), a...
The goal of this research was to determine if controlled atmosphere (CA) storage could be used to extend the market period of fresh Pacific Northwest blueberries and to evaluate the effects different storage atmospheres have on fruit quality. Furthermore, this research also investigated heat and mass transfer characteristics during cooling...
The semi-arid sagebrush steppe ecosystem is one of the largest biomes in
North America. The steppe provides critical habitat and forage for wildlife and is
economically important to recreation and livestock industries. However, the ecosystem
is threatened primarily due to several negative effects associated with expansion of the
exotic annual...
Ponderosa pine (Pinus ponderosa) and lodgepole pine (Pinus contorta var. murrayana) forests of south-central Oregon have been extensively researched over the last century. However, little information has been reported on overstory composition and stand structure shifts associated with fire exclusion within inter-mixed ponderosa pine and lodgepole pine stands of the...