This thesis describes the development of a new enantioselective synthetic method employing chiral cis-2,5-diaminobicyclo[2.2.2]octane-based organometallic catalysts. The significance of this new method to organic synthesis is illustrated with preparation of enantioenriched products that are transformed to important pharmaceutical agents. Chapter 1 provides a brief historical overview of asymmetric catalysis, especially...
New ice cores retrieved from the Taylor Glacier (Antarctica) blue ice area contain ice and air spanning the Marine Isotope Stage (MIS) 5/4 transition, a period of global cooling and ice sheet expansion. Chronologies were determined for the ice and air bubbles in the new ice cores by visually matching...
This study involved the determination of the structural layer properties of
aggregate and asphalt surfaced pavements for use in the evaluation of pavement load
carrying capacity and the seasonal effects of moisture. This was achieved by the use
of Nondestructive Testing Methods (NDT) and backcalculation techniques. Pavement
surface deflection measurements...
The use of an adjacency matrix to determine distant (not maximal or
minimal) subgroup and supergroup relationships between crystallographic spacegroup
types is described. Full lists of space-group types that are supergroups and
subgroups for every space-group type were compiled. A list of the space-group
types connected to each space-group type...
Mankind is facing the spectre of a planet stripped of the resources necessary to sustain the human populations that currently exist-not to mention those unborn multitudes which seem certain to he added in the coming decades. Time is rapidly running out for scientists and engineers to find new resources to...