This thesis consists of three manuscripts related to the methodology of evaluating charring behavior in cross laminated lumber panel specimens subjected to fire performance tests on cross-laminated lumber panel specimens. The topic of the first manuscript is the measurement of char rates of unprotected CLT layups fabricated with ponderosa pine...
A new approach towards a total synthesis of paeoniflorigenin is discussed. The approach involves the application of regio- and stereoselective [2+2] photocycloaddition for the preparation of a key intermediate, cyclobutanone 86, and model studies on diiodosamarium (Sm12) mediated pinacol coupling of a diketone. Intermolecular [2+2] photocycloaddition of a,13unsaturated lactam 33...
Hop cell wall material (CWM) extracted from hop leaves (hamulus lupulus) was
purified and characterized. The total sugar content, uronic acid content and
monosaccharide composition of the CWM were determined. Galacturonic acid is the
major component in the CWM. A mixture of unsaturated oligogalacturonides were
released from purified hop CWM...
School forests in South Korea are trees and vegetation areas within schoolyards, and they provide natural environments for schools and neighborhoods. After the Korea Forest Service (KFS) and local governments create these school forests, the management of school forests transfers to the host schools. Some studies suggest that experiences with...
A class of inorganic thin-film transistor (TFT) semiconductor materials has emerged involving oxides composed of post-transitional cations with (n-1)d¹⁰ns⁰ (n≥4) electronic configurations. This thesis is devoted to the pursuit of topics involving the development of these materials for TFT applications: Deposition of zinc oxide and zinc tin oxide semiconductor
layers...
Natural convection provides a means for circulating fluids without the use of pumps. This type of system is of great interest for a wide variety of applications, including solar heaters, process industry, and nuclear reactors. Natural convection will play a vital role in the area of passive safety and reliability,...
The reactions of cyclodeca-1, 2, 5, 8-tetraene with mercuric salts
in solvents of varying nucleophilicity are described. Instead of forming
the usual oxymercuration products reported for reactions of olefins
and allenes with mercuric salts, the major products obtained in the
present cases result from the initial electrophilic addition of the...
A method for separation and characterization of individual anthocyanins was
developed. High Performance Liquid Chromatography (HPLC) with a polymer based
reversed-phase column was used to separate the pigments while on-line Photodiode
Array Detection (PDA) was employed to record the UV and Visible spectrum of the
individual peaks. Spectral information obtained...