Air–sea coupling during coastal upwelling was examined through idealized three-dimensional numerical simulations with a coupled atmosphere–ocean mesoscale model. Geometry, topography, and initial and
boundary conditions were chosen to be representative of summertime coastal conditions off the Oregon coast. Over the 72-h simulations, sea surface temperatures were reduced several degrees near...
The solid solutions of InGa₁₋ₓFeₓCuO₄, InFeCu₁₋ₓMgₓO₄, and InGa₁₋ₓFeₓCu₁₋ₓMgₓO₄ were
synthesized and characterized through the use of X – ray and neutron diffraction, and DC –
magnetism measurements. All compositions of InGa₁₋ₓFeₓCuO₄ are single phase and crystallize
in the R3m space group, but a transformation to the spinel InFeMgO₄ structure was...
Includes general information about journal costs and costs of commercial versus society publications. Spreadsheet represents the journals in which faculty in the Chemistry Department most often publish and includes journal title, cost, impact factor, publisher, and information about whether the journal is published by a scholarly society or a for-profit...
Mapping out multidimensional potential energy surfaces has been a goal of
physical chemistry for decades in the quest to both predict and control chemical
reactivity. Recently a new spectroscopic approach called Femtosecond Stimulated Raman
Spectroscopy or FSRS was introduced that can structurally interrogate multiple
dimensions of a reactive potential energy...
The effect of quasi-hydrostatic pressure upon the ferromagnetic ground state of magnetodielectric, double-
perovskite La₂ MnNiO₆ is investigated using x-ray absorption spectroscopy and diffraction measurements in a
diamond anvil cell. The Mn-O-Ni superexchange interaction that gives rise to ferromagnetism in this cation-
ordered structure is stable to at least 38...
Background: There is a long-term interest in running the fission reaction backward, i.e., studying the "inverse fission" of uranium. The recent availability of beams of n-rich fission fragments has stimulated interest in this endeavor.
Purpose: To search for inverse fission in the reactions Sn-¹²⁴,Sn-¹3² + Mo-¹⁰⁰.
Method: In the Sn-¹²⁴...
We report an experimental and theoretical study of single-molecule inner-shell photoemission measured over an extended range of photon energies. The vibrational intensity ratios I (nu = 1)/I (nu = 0) from the C 1s photoelectron spectra of carbon monoxide, although mostly determined by the bond length change upon ionization, are...
Fusion excitation functions for the reactions of Sn-¹²⁴,Sn-¹³² with Ca-⁴⁰,Ca-⁴⁸ were measured at energies near and below the Coulomb barrier. Weak sub-barrier fusion enhancement accounted for by coupling to the first 2(+) and 3(-) states in the target and projectile was observed for Sn-¹²⁴,Sn-¹³² + Ca-⁴⁸. However, the Sn-¹²⁴,Sn-¹³² +...
X-ray photoemission spectroscopy is used in a great variety of research fields; one observable is the sample's stoichiometry. The stoichiometry can be deduced based on the expectation that the ionization cross sections for innershell orbitals are independent of the molecular composition. Here we used chlorine-substituted ethanes in the gas phase...
Three general types of swimbladders were found in the eight species of myctophids studied: gas-filled, fat-invested, and atrophied or reduced. Small specimens of all species had thin-walled, gas-filled swimbladders. Large specimens of Stenobrachius leucopsarus had fat-invested swim-bladders and large Diaphus theta had either gas-filled or atrophied swimbladders, as found by...
Abstract: Background: The cross section for forming a heavy evaporation residue in fusion reactions depends on the capture cross section, the fusion probability, P[subscript CN], i.e., the probability that the projectile-target system will evolve inside the fission saddle point to form a completely fused system rather than reseparating (quasifission), and...
The performance of an over 10 times larger microbial fuel cell (MFC) with double cloth electrode assembly (CEA) during 63 days of continuous operation demonstrates that the excellent performance of CEA-MFC can be further improved during scale-up. With a new separator material and U-shaped current collectors, the larger MFC produced...
We have studied the fission-neutron emission competition in highly excited ²⁷⁴Hs (Z = 108) (where the
fission barrier is due to shell effects) formed by a hot fusion reaction. Matching cross bombardments
(²⁶Mg + ²⁴⁸Cm and ²⁵Mg + ²⁴⁸Cm) were used to identify the properties of first chance fission of...
Over a 3.5-year period, 4 Rocky Mountain goats (Oreamnos americanus), housed at a single facility, developed clinical disease attributed to infection by Caprine arthritis encephalitis virus (CAEV). Ages ranged from 1 to 10 years. Three of the goats, a 1-year-old female, a 2-year-old male, and a 5-year-old male, had been...
While the d⁰ transition-metal POMs of Group V (V⁵⁺, Nb⁵⁺, Ta⁵⁺) and Group VI (Mo⁶⁺, W⁶⁺) have been known for more than a century, the actinyl peroxide POMs, specifically those built of uranyl triperoxide or uranyl dihydroxidediperoxide polyhedra, were only realized within the last decade. While virtually every metal on...
We, for the first time, employ magnesiothermic reaction to convert microwave-irradiated graphite oxide to pure graphene. The magnesiothermic reaction raises the carbon to oxygen atomic ratio from 22.2 to 165.7 and maintains a high surface area. The new strategy demonstrates an efficient method for obtaining highly pure graphene materials.
Assembly of nanocrystals is considered one of the most promising approaches to design nano-, microstructures, and complex mesoscopic architectures. A variety of strategies to induce nanocrystal assembly have been reported, including directed assembly methods that apply external forces to fabricate assembled structures. In this study ZnO nanocrystals were synthesized in...
The aggregation of 12 nm citrate-stabilized gold nanoparticles (cit-AuNPs) in the presence of four
different natural organic matter (NOM) isolates and a monovalent electrolyte (KCl) was evaluated using
time-resolved dynamic light scattering. All four NOM isolates stabilized the cit-AuNPs with respect to
aggregation. However, specific effects varied among the different...
There is increasing evidence that aging is affected by biological (circadian) clocks – the internal mechanisms that coordinate daily changes in gene expression, physiological functions and behavior with external day/night cycles. Recent data suggest that disruption of the mammalian circadian clock results in accelerated aging and increased age‐related pathologies such...
A series of combined measurements was made at the Naval Air Station North Island (NASNI) Installation Restoration Site 5, Unit 2 during July and August 2013. Combined measurements included CO₂ respiration rate, CO₂ radiocarbon content to estimate chlorinated hydrocarbon (CH) mineralization and a zone of influence (ZOI) model. CO₂ was...
Carbon 1s photoelectron asymmetry parameters β for the chlorinated and the methyl carbon atom of CH₃CH₂Cl, CH₃CHCl₂, and CH₃CCl₃ have been measured using synchrotron radiation in the 340-600 eV energy range. We provide experimental evidence that the intramolecular scattering strongly affects beta values, even far from the ionization threshold. The...
A central goal of green chemistry is to avoid hazard in the design of new chemicals. This objective is best achieved when information about a chemical's potential hazardous effects is obtained as early in the design process as feasible. Endocrine disruption is a type of hazard that to date has...
In 1959 the British Ornithological journal, The Ibis, published a centenary commemorative volume on the history of ornithology in Britain. Over the previous few decades, the contributors to this volume had helped focus the attention of ornithologists on the methods, priorities, and problems of modem biology, specifically the theory ofevolution...
The yields of over 200 projectile-like fragments (PLFs) and target-like fragments (TLFs) from the interaction of (E[subscript]c.m.=450 MeV) Xe¹³⁶ with a thick target of Pb²⁰⁸ were measured using Gammasphere and off-line γ-ray spectroscopy, giving a comprehensive picture of the production cross sections in this reaction. The measured yields were compared...
Background: Multinucleon transfer reactions have recently attracted attention as a possible path to the synthesis of new neutron-rich heavy nuclei.
Purpose: We study transfer reactions involving massive nuclei with the intention of understanding if the semi-classical model GRAZING coupled to an evaporation and fission competition model can satisfactorily reproduce experimental...
The effect of the Coriolis interaction upon the sharing of energy between rotational and vibrational excitation
during an electronic transition is considered with particular emphasis on recoil-induced excitation during
photoionization. If there is a large change in equilibrium bond length upon ionization, then Coriolis coupling
leads to a significant transfer...
Although much has been written describing the
various reactions to the origin of Species in America, the Mormon reaction to Darwinism has been largely ignored. This dissertation will recount the history of this reaction as exemplified by the life and works of B. H. Roberts. Roberts's intellectual pursuits early in...
Forty-five young adult males were given 30 trials of Isometric
knee extension and 30 trials of isometric knee flexion. Each trial
consisted of a maximum of three second exertion followed by a 10
second intertrial rest interval. Subjects were ranked on the basis
of the mean of the first three...
This chapter describes a mass spectrometry-based strategy that facilitates the unambiguous identification and characterization of proteins modified by lipid peroxidation-derived 2-alkenals. The approach employs a biotinylated hydroxyl amine derivative as an aldehyde/keto reactive probe in conjunction with selective enrichment and tandem mass spectrometric analysis. Methodological details are given for model...
Gravity measurement program in Oregon / John V. Thiruvathukal and Joseph W. Berg, Jr. -- The principle of discovery and the problems arising therefrom / Raymond B. Holbrook.
High-resolution infrared absorption spectra have been analyzed for two bicyclo[111]pentane isotopologues, C₅H₈ (-d₀) and C₅H₇D (-d₁), where in the latter the D-atom replaces a hydrogen on the C₃ symmetry axis such that the molecular symmetry is reduced from D₃ₕ to C₃ᵥ. Two (a"₂) parallel bands, v₁₇ and v₁₈, of bicyclopentane-d₀...
This paper is a continuation of earlier work in which the high resolution infrared spectrum of [1.1.1]propellane was measured and its k and l structure resolved for the first time. Here we present results from an analysis of more than 16,000 transitions involving three fundamental bands v₁₀ (E' - A'₁),...
We report the use of MIL-120 as a water-stable and cost-effective metal-organic framework (MOF) for selectively capturing CO₂ from wet flue gas. Synthesized using inexpensive and environmentally benign reagents in water, MIL-120 possesses one-dimensional pores decorated with hydroxyl-bridged Al(III) ions and benzene rings with an interstitial spacing of 4.78 Å....
The purpose of this research was to study the impact
phenomena of a tennis ball striking a hard surface.
Stroboscopic photography was used to collect the ball's
impact images from seven angles of incidence, ranging from
-23 degrees to -70 degrees with zero, top and back initial
spin respectively.
Through...
"It is the purpose of this paper, through a brief review of the history of Astoria, to construct a framework of the physical history of the city, to place each published geologist in his correct historical setting within the city, and to reestablish his locales so as to be presently...
In this dissertation, we describe a spectroscopic study of metal clusters and metal-ligand complexes using pulsed field ionization zero kinetic energy (PFI-ZEKE) photoelectron spectroscopy and mass analyzed threshold ionization (MATI) spectroscopy. Vibrational resolved spectra of sodium dimer, Na•NH₃, Na•(NH₃)₂ are presented. These spectra provide a direct measurement of the ionization...
A novel method of copper indium diselenide nanoparticle
(CuInSe₂ NP) synthesis using a two-step, continuous flow,
solar microreactor is reported here. This method allows for
exceedingly fast heating and short reaction times using only
radiative heat transfer from simulated, concentrated solar
radiation. Chalcopyrite and sphalerite CuInSe₂ phases have
both been...
Acenes larger than pentacene are predicted to possess enticing electronic properties, but are insoluble and prone to rapid decomposition. Utilizing a combination of functionalization strategies, we present stable, solution processable hexacenes and an evaluation of their hole and electron transport properties.
The potent antitumor agent phorboxazole A was synthesized from six subunits comprising C1-C2 (115), C3-C8 (98), C9-C19 (74), C20-C32 (52), C33-C41 (84) and C42-C46 (85). Tetrahydropyrans B and C containing cis-2,6-disubstitution were fabricated via palladium(II)-mediated intramolecular alkoxycarbonylation which, in the case of tetrahydropyran C, was carried out with catalytic palladium(II)...
The price of gold has risen from $60.35 per ounce in mid-November, 1972, to $91.25 per ounce in mid-April, 1973. The present high price has caused considerable speculation as to the underlying reasons for the sudden increase and what effect it may have on the international monetary situation. This precious...
The dipolar cylcoadditions of ortho-nitrophenyl alkynes with aryl nitrile oxides has been demonstrated. A range of substituents are tolerated on the alkyne. These reactions proceed with excellent levels of regioselectivity. Subsequent functionalization of the isoxazole scaffold has been demonstrated.
The metal organic framework, MOF-74(Ni), was synthesized in a continuous flow microwave-assisted reactor obtaining a high space-time yield (~90 g h⁻¹ L⁻¹) and 96.5% conversion of reagents. Separation of the nucleation and growth steps was performed by using uniform and rapid microwave heating to induce nucleation, which allowed a substantial...
Mammalian cysteine dioxygenase (CDO) is a mononuclear non-heme iron protein that catalyzes 2 the conversion of cysteine (Cys) to cysteine sulfinic acid (CSA) by an unclarified mechanism. 3 One structural study revealed a Cys-persulfenate (or Cys-persulfenic acid) formed in the active 4 site, but quantum mechanical calculations have been used...
Mammalian cysteine dioxygenase (CDO) is a mononuclear non-heme iron protein that catalyzes 2 the conversion of cysteine (Cys) to cysteine sulfinic acid (CSA) by an unclarified mechanism. 3 One structural study revealed a Cys-persulfenate (or Cys-persulfenic acid) formed in the active 4 site, but quantum mechanical calculations have been used...
Full Text:
, Corvallis, OR 97331 8
b
Department of Molecular Medicine, 618 Tower Rd, Cornell University, Ithaca, NY
Mammalian cysteine dioxygenase (CDO) is a mononuclear non-heme iron protein that catalyzes 2 the conversion of cysteine (Cys) to cysteine sulfinic acid (CSA) by an unclarified mechanism. 3 One structural study revealed a Cys-persulfenate (or Cys-persulfenic acid) formed in the active 4 site, but quantum mechanical calculations have been used...
Full Text:
is weaker than that of the Cys93 Sγ, consistent with the iron having 5
decreased occupancy. We
Refractive indices of In₂O₃, In₂₋ₓSnₓO₃, InBO₃ and 2 different gahnite crystals (ZnAl₂O₄ and Zn.₉₅Fe.₀₅Al₂O₄) were measured at wavelengths of 435.8 to 643.8 nm and were used to calculate n at λ = 589.3 nm ( nD ) and at λ = ∞ (n∞) using the one-term Sellmeier equation 1/(n²-1) =...