Artificial substrates colonized by diatoms from Yaquina Estuary, Oregon, were exposed to solar visible radiation and three levels of ultraviolet radiation (UV-B, 290-320 nm). Flow-through microcosms were constructed inside a glasshouse to serve as chambers for the artificial substrates. The artificial substrates were sampled during three spring/summer experiments. Chlorophyll a...
In this dissertation, my research work on excited state dynamics of small organic molecules in solutions is presented. Using femtosecond stimulated Raman spectroscopy (FSRS) as the main experimental tool, the excited state hydrogen-bonding dynamics (ESHBD) of Coumarin 102, a common laser dye molecule, in ethanol solution is examined with <150...
This biological assessment (BA) documents the potential effects of existing Forest Service (FS) Land and Resource Management Plans (LRMPs), or 'Forest Plans' and Bureau of Land Management (BLM) Land Use Plans (LUPs) on the Canada Lynx (Lynx canadensis), hereafter referred to as the lynx. LRMPs and LUPs are collectively referred...
Ultrafast spectroscopy has recently gained momentum as a powerful, noninvasive characterization toolset capable of studying a diverse array of samples with applications in chemistry, physics, biology, engineering, and more. Two popular ultrafast spectroscopic techniques include femtosecond transient absorption (fs-TA) and femtosecond stimulated Raman spectroscopy (FSRS). The latter of these techniques...
In the past decades, femtosecond stimulated Raman spectroscopy (FSRS) has been gaining tremendous popularity in fundamental sciences stemming from chemistry to biology. It is capable of capturing both equilibrium and non-equilibrium structural information across a broad range of timescales with simultaneously high temporal and spectral resolutions. Femtosecond transient absorption spectroscopy...
Ultrafast spectroscopy can exploit the structure-function relationship of chemical- and biological-based systems. More specifically, femtosecond stimulated Raman spectroscopy (FSRS) provides ground- and excited-state vibrational information with simultaneously high spectral (spatial) and temporal resolutions. The electronic counterpart, femtosecond transient absorption (fs-TA), complements FSRS data analysis as part of a comprehensive approach...
The development of cross-laminated timber (CLT) panel technology has opened up new opportunities for wood in tall buildings. Several characteristics including seismic performance and speed of construction have raised interest among designers. As CLT gains acceptance in the industry, alternative structural solutions need to be investigated to improve performance of...
Fluorescent proteins (FPs) are luminescent biomolecules that emit characteristic hues upon irradiation. A group of calmodulin (CaM)-green FP (GFP) chimeras have been previously engineered to enable the optical detection of calcium ions (Ca²⁺). We investigate one of these genetically encoded Ca²⁺ biosensors for optical imaging (GECOs), GEM-GECO1, which fluoresces green...
As CMOS processes keep scaling down devices, the maximum operating frequencies of CMOS devices increase, and hence circuits can process very wide band signals. Moreover, the small physical dimensions of transistors allow the placing of many more blocks into a single chip, including highly accurate analog blocks and complicated digital...
Davidson Seamount, a volcano located about 80 km off the central California coast, has a volume of
~320 km³ and consists of a series of parallel ridges serrated with steep cones. Davidson was sampled and
its morphology observed during 27 ROV Tiburon dives. During those dives, 286 samples of lava,...
Cross-laminated timber (CLT) is a massive engineered wood product made of orthogonally bonded layers of solid-sawn lumber, and is intended for roof, floor, or wall applications. Although it was developed in Europe in the early 90s, CLT is relatively new to North America.
CLT products must be certified for structural...
Photoactivated biomedical tools like fluorescent biosensors and optogenetic proteins have increased in popularity due to the precision targeting and activation used for in vivo applications. In nature, the initially discovered parent proteins exhibit properties such as fluorescence quantum yield (FQY), fluorescence color, and photoswitching dynamics that are unfavorable in mammalian...
This dissertation presents nonlinear terahertz (THz) properties of carbon nanomaterials investigated by time-resolved high-field THz spectroscopy. In order to determine THz characteristics of nanomaterials, we performed THz power spectrum measurement, THz raster imaging, THz time-domain spectroscopy (THz-TDS) and time-resolved pump-probe experiment on two different types of single layer graphene and...
Global atmospheric pollution from chlorofluorocarbons has the
potential of causing significant reductions in the concentrations of
stratospheric ozone. If the production of chlorofluorocarbons were
to continue into the future at the rate prevalent in 1977, the
steady state reduction in total global ozone could be between five
percent to ten...
According to Blackwell, Miniard, and Engel (2001), "[c]ulture has a profound effect on why and how people buy and consume products and services" (p. 320). In the present study, Hofstede's classifications of national culture are used as a framework to examine the relationships among long-term orientation national culture (Taiwan and...
Femtosecond stimulated Raman spectroscopy (FSRS) is a powerful ultrafast technique which can track photoinduced excited state structural events on femtosecond (fs) to picosecond (ps) timescales. In addition to high temporal and spectral resolutions, FSRS provides a broad spectral window from ca. 100—2000 cm-1 for detection, enabling the direct mapping of...
In this dissertation, excited state proton transfer (ESPT) and its inhibition in solution and protein environments are revealed using both femtosecond transient absorption (fs-TA) spectroscopy and femtosecond stimulated Raman spectroscopy (FSRS). Using a tunable Raman pump to enhance transient vibrational features of the photoacidic chromophore HPTS in methanol and methanol...
During the Canterbury Earthquake Sequence (CES) in Christchurch, NZ, an estimated $15B in damages occurred due to liquefaction-induced phenomena, illustrating the importance of understanding site-specific responses to seismic ground motions, as well the importance of accurately predicting liquefaction severity. One potential method for improving the understanding of how a site...