Current frameworks for analyzing forest carbon offset projects in disturbance-prone western forests often fail to address the dynamic nature of carbon pathways through time. They do not account for the probability of loss due to wildfire, which can influence the prediction of carbon storage at the end of a planning...
The arithmetic portions of almost all modern processor architectures are of very similar design. We use the term "traditional" to describe this design, the primary characteristics of which are native support for integer and floating-point number types and special disjoint instructions and hardware for each supported type. Decades of refinement...
Historical forest harvesting practices were reviewed in the original Alsea Watershed Study where they found increased energy
loading to the stream and produced higher stream temperatures. This was an important early research site that led to the
development of contemporary forest management practices to protect water quality and fish habitat...
These data contain temperature readings from dataloggers launched in Deer Creek, Flynn Creek, and Needle Branch from 2006 to 2010. These loggers were apart of the Alsea Watershed Revisisted Study Revisited articles, but the data was incomplete due to logging gaps, temperature spikes, or other issues. The "Thermistor Functionality" datasets...
Forest harvesting practices can expose mineral soils, decrease infiltration capacities of soils, disturb the stream bank and channel, and increase erosion and fine sediment supply to stream channels. To reduce nonpoint source sediment pollution associated with forest management activities and to maintain the high water quality typically provided from forests,...
In salmon-rich, northern coastal environments brown bears can occur at high densities and exert wide-ranging effects on ecosystem processes. Bear consumption of seasonally available fruit may provide important seed dispersal services to plants, and by extension, influence the ecology of seed consumers such as small mammals. In this study, we...
Enantioenriched sp³-hybridized carbenoid reagents CR1R2MX (X = nucleofuge, M = electrofuge) of different types were investigated for the synthesis of polysubstituted alkyl chains by iterative stereospecific reagent-controlled homologation (StReCH) and for the stereospecific connective synthesis of alkenes by eliminative cross-coupling.
In the first part, putative enantioenriched α-chloroalkyllithiums (CHRLiCl) were employed...
An intramolecular variant of the modified-Julia olefination was demonstrated by the synthesis of α,β-unsaturated lactones in a mild and (Z)-selective fashion. The lynchpin reagent (benzothiazol-2-sulfonyl) acetic acid was synthesized in a straightforward fashion in 86% overall yield from commercially available 2-mercaptobenzothiazole via conversion to ethyl (benzothiazol-2-ylthio)acetate by base mediated alkylation...
Woody biomass transportation costs and market values/costs are strongly correlated with the woody biomass moisture content. Properly managing moisture content can potentially lead to economic and environmental advantages in biomass energy markets. Good management requires accurate moisture content measurements. Therefore, availability of accurate, precise, reliable, and efficient tools to assess...
Sulfoxide-ligand exchange (SLE) and asymmetric halogen-metal exchange (AHME) processes were separately examined for the enantioselective synthesis of functionalized alpha-haloalkylmetal (carbenoid) reagents. Carbenoids derived from SLE were used to effect stereospecific reagent-controlled homologation (StReCH) of boronic esters and those generated via AHME were engaged in Darzens-type chemistry with aldehydes.
Abstract for...
7,7'-Dihydroxy-8,8'-biquinolyl (azaBINOL) was prepared from 7-hydroxyquinoline via N,N-dimethyl O-quinol-7-yl carbamate by directed ortho-metallation followed by FeCl₃-mediated oxidative coupling of the 8-lithioquinoline intermediate. Saponification of the resulting dicarbamate provided crystalline (±)-azaBINOL in 56% overall yield. 6,6'-Bis(dimethylaminocarbonyl)-7,7'-dihydroxy-8,8´-biquinolyl was prepared from the same dicarbamate by a double anionic-Fries rearrangement in 43% yield. 7,7'-Bis(diethylamino-carbonyloxy)-6,6'-diiodo-8,8´-biquinolyl...
Aromatic heterocycles are core structural motifs in natural products, pharmaceuticals and biological polymers. Indoles, in particular, represent a significant subclass of aromatic heterocycles, both in terms of sheer numbers, but also in biological and pharmaceutical relevance. As such, new methodologies for the synthesis of indoles represent an important and continually...
We examined long-term changes in daily streamflow associated with forestry practices with two datasets (this one and the original Alsea Streamflow dataset (1972) over a 60-year period (1959–2017) in the Alsea Watershed Study, Oregon Coast Range, Pacific Northwest, USA. In this contemporary period, 2006 to 2017 (12 water years), data...
Three distinct methods to achieve the stereoselective synthesis of carbon-carbon bonds were investigated, encompassing: (i) the formation of axially chiral biaryl molecules by enantioselective Suzuki cross-coupling, (ii) the synthesis of α-phenylalkylboronic esters by enantioselective chain extension, and (iii) the stereospecific synthesis of alkenes by eliminative cross-coupling of enantioenriched sp³-hybridized carbenoids....
This paper presents qualitative results from interviews with knowledge workers about their recovery strategies after interruptions. Special focus is given to when these strategies fail due to the nature of the interruption and existing computer support. Potential solutions offered by participants to overcome some of these problems are presented. These...
This study examines potential interactions among the environmental variables likely to
affect larval walleye pollock Theragra chalcogramma feeding in the sea. Walleye pollock larvae were
sampled from Shelikof Strait, Gulf of Alaska, and from the eastern Bering Sea, with corresponding
environmental data. Variables used in our study were time spent...
Mutations in the metallo-protein Cu/Zn-superoxide dismutase (SOD1) cause amyotrophic lateral sclerosis (ALS) in humans and an
expression level-dependent phenotype in transgenic rodents. We show that oral treatment with the therapeutic agent diacetyl-bis(4-methylthiosemicarbazonato)copper[superscript II] [Cu[superscript II](atsm)] increased the concentration of mutant SOD1 (SOD1G37R) in ALS model mice, but paradoxically improved locomotor...
Development of marine heat waves (MHWs) in the Chile-Peru Current System (CPCS) is influenced by multiple physical processes at the air-sea interface whose individual role in these destructive events is difficult to infer. We identified MHW events from sea surface temperature (SST) anomalies from time periods of extreme ocean warming...
Phytoplankton and microzooplankton comprise the base and the first link of the marine food web, respectively. These microbes are key drivers of marine carbon and nutrient cycles. Phytoplankton convert atmospheric CO₂ into organic carbon, and microzooplankton consume phytoplankton, packaging phytoplankton carbon into particulate forms that have a variety of fates:...