Organic semiconductors are a promising alternative to the traditional inorganic semiconductors, such as silicon. Organics are solution-processable, low-cost, sustainable, and have interesting optoelectronic properties. One such property is the formation of exciton-polaritons, quantum quasi-particles formed by an electron-hole pair in the semiconductor and a photon. This process can be induced...
Organic semiconducting materials have emerged in the last few decades as viable alternatives to inorganics in broad applications from field effect transistors to LEDs to solar cells. Organics provide many benefits over inorganics such as flexibility, sustainability, and reduced cost. However, these materials are more susceptible to degradation in the...
Understanding charge transfer in organic semiconductors is important for developing devices like organic light emitting diodes and flexible electronics. Optical tweezers have been used in many disciplines for trapping, manipulating, and analyzing microscopic objects such as microspheres, micro-organisms, and other colloidal particles. Using optical tweezers, studies have measured the average...
We measure the charging and discharging of two organic materials, PCBM and ADT-TES-F. These materials are studied through the noncontact method of particle trapping known as Optical Tweezers, where an IR laser is used to constrain the motion of a coated or noncoated silica sphere while its positional data is...
Xylindein is an organic pigment derived from Chlorociboria aeruginascens and C. aeruginosa fungi that has shown promise as an organic semiconductor. Preliminary estimates of charge carrier mobilities (CCMs) on the order of 0.1 cm2/Vs were calculated from early tests on xylindein thin films, and photocurrents were also observed under laser...
The behavior and application of organic semiconductor materials depend strongly on their molecular structure, and molecular interactions. Several studies of intermolecular interactions in functionalized polyacene materials are presented. The degree and onset of aggregation of a functionalized anthradithiophene derivative was studied as a function of concentration in two different host...
Studies of light-matter interactions in organic semiconductors and in optical tweezer trapping of nanoparticles are presented. In the research related to organic semiconductor materials, a variety of novel materials and their composites have been characterized, and physical mechanisms behind their optoelectronic properties have been established. Three novel functionalized hexacene derivatives...
The continued development of organic semiconductor materials relies on an understanding of the relationship between optoelectronic properties, molecular structure, and molecular interaction. Several detailed studies of electronic properties in functionalized polyacene materials are presented. A computational model which allows the extraction of charge generation and transport properties from experimental data...
Organic photovoltaics are being explored as the next generation material for semiconducting and optoelectronic devices but are limited by their stability and efficiency. One new candidate is crystallized Anthradithiophene (ADT), which is a promising photo-voltaic material due to its high quantum yield and adjustable side groups. The side derivatives TES-F,...
The results of an investigation into carrier dynamics in several novel functionalized and solution-processable pentacene and anthradithiophene derivatives are reported. Measurements were made of real-time photoresponse of polycrystalline thin films of these materials to ultrafast laser pulses, on picosecond to microsecond time-scales, as well as measurements of dark current and...
The spalting fungus Scytalidium cuboideum secretes a red pigment that produces naphthoquinonic crystals that are a photonic material candidate. The molecule can pack together in different configurations resulting in amazingly different optical properties. I developed a procedure (slowly evaporating the solvent) to preferentially grow two of these configurations, which have...