We report on physical mechanisms behind the temperature-dependent optical absorption, photoluminescence (PL), and photoconductivity in spin-coated films of a functionalized anthradithiophene (ADT) derivative, ADT-triethylsilylethynyl (TES)-F, and its composites with C₆₀ and another ADT derivative, ADT-TIPS-CN. Measurements of absorption and PL spectra, PL lifetimes, and transient photocurrent were performed at temperatures...
Discussions of ecopoetics often seek to investigate how poetics as a form can be rendered more ecological, often in contrast to nature poetry. These conversations tend to concentrate on this generic contrast and the formal qualities of an ecological poetics. Ecopoetics as a field emerged largely as a response to...
This dissertation outlines two approaches for improving the efficiency and reducing the cost of photovoltaic energy generation. First, the structures of known binary copper and iron compounds are used to choose the promising compositions Fe₂XS₄ (X = Si, Ge), Cu₃TaQ₄ (Q = Se, Te), and BaCuQ'F (Q' = S, Se,...
Fire-prone landscapes are not well studied as coupled human and natural systems (CHANS) and present many challenges
for understanding and promoting adaptive behaviors and institutions. Here, we explore how heterogeneity, feedbacks, and external
drivers in this type of natural hazard system can lead to complexity and can limit the development...
We report on the effect of various guest molecules added to a functionalized anthradithiophene (ADT) host on photoexcited charge carrier dynamics in solution-deposited thin films, from ~100 ps to >100 μs after photoexcitation with 100 fs laser pulses. An addition of 2 and 5 wt % of C60 to a...
Disasters result from hazards affecting vulnerable people. Most disasters research by anthropologists focuses on vulnerability; this article focuses on natural hazards. We use the case of wildfire mitigation on United States Forest Service lands in the northwestern United States to examine social, political, and economic variables at multiple scales that...
In situ photoemission spectroscopy experiments are used to characterize the interface between ZnTe and the wide band gap p-type semiconductor BaCuSeF. The contact is characterized by a null valence-band offset, a large conduction-band offset, and a chemically graded interface. By applying the transitivity rule for band offset and on the...
BaCuChF (Ch=S,Se,Te) surfaces and BaCuSeF interfaces with zinc phthalocyanine (ZnPc) were studied by photoelectron spectroscopy. BaCuChF compounds oxidize when exposed to ambient atmosphere. Se capping layers were studied as a means to produce representative surfaces for photoelectron spectroscopic measurements. Decapped BaCuSeF surfaces remain O-free and C-free when the Se layer...
In this thesis we construct compatible discretizations of Maxwell's equations. We use the term compatible to describe numerical methods for Maxwell's equations which obey many properties of vector Calculus in a discrete setting. Compatible discretizations preserve the exterior Calculus ensuring that the divergence of the curl and the curl of...
Certain chlorinated insecticides can be identified by electron capture gas-liquid chromatographic (EC-GLC) analysis of the prepared sample before and after treatment with ultraviolet irradiation, Upon U.V. treatment, characteristic degradation products arise from the insecticides investigated. Comparison of the degradation pattern obtained by EC-GLC of unknown and authentic insecticides provides an...
The reason for the initial rise in atmospheric
CO₂ during the last deglaciation remains unknown. Most recent
hypotheses invoke Southern Hemisphere processes such
as shifts in midlatitude westerly winds. Coeval changes in
the Atlantic meridional overturning circulation (AMOC) are
poorly quantified, and their relation to the CO₂ increase is
not...
The reason for the initial rise in atmospheric
CO₂ during the last deglaciation remains unknown. Most recent
hypotheses invoke Southern Hemisphere processes such
as shifts in midlatitude westerly winds. Coeval changes in
the Atlantic meridional overturning circulation (AMOC) are
poorly quantified, and their relation to the CO₂ increase is
not...
Full Text:
atmospheric CO2 rise inferred from carbon isotopes (δ
13C)
A. Schmittner1 and D. C. Lund2
1College of Earth
Two modifications to an existing scheme of tidal
mixing are implemented in the coarse resolution ocean component
of a global climate model. First, the vertical distribution
of energy flux out of the barotropic tide is determined
using high resolution bathymetry. This shifts the levels of
mixing higher up in the...