The ternary system (Bi₀.₅Na₀.₅)TiO₃-(Bi₀.₅K₀.₅)TiO₃-Bi(Mg₀.₅Ti₀.₅)O₃ (BNT-BKT-BMgT) was explored along the [75-(x 2) ]Bi₀.₅Na₀.₅TiO₃ - [25-(x 2)]Bi₀.₅K₀.₅TiO₃ - [x]Bi(Mg₀.₅Ti₀.₅)O₃ composition line. Thin films were fabricated using chelated mixing route solutions spin cast onto platinized silicon substrates. Processing parameters such as: excess cation molar%, solution molality, and crystallization temperatures, for composition where x=0,...
The cleanliness of water is a major issue with regards to humanity's continued survival. The chlorination and chloro-amination of water is essential to the creation of microbiologically clean water. However these processes also give rise to oxidative byproducts such as nitrosamines. In particular, due to its high toxicity, N-Nitrosodimethylamine (NDMA)...
High performance dielectric materials are needed for high power SiC- or GaN-based electronics which combine the best features of high energy density, low dielectric loss and high reliability and for advanced high-speed and high-voltage energy storage where temperature stability plays an important role in material properties. An ideal capacitor for...
Automating pick-and-place operations for large steel castings in a foundry is challenging, particularly from a perception point of view. Accurately estimating the identity and orientation of a given part is an open and complex problem, especially if that part sits in a bin of very similar parts. The problem is...
New amplifier architectures are presented using non-traditional methods of biasing. Time-based dynamic biasing and signal-based dynamic biasing are discussed in the context of new architectures. This includes a new form of ring amplification with a dynamic deadzone, allowing for a structure whose coarse path does not consume static power.
The focus of this thesis is developing materials for thin-film transistors (TFTs). Cu₃SbS₄ is explored as p-channel layer. Cu₃SbS₄ TFTs show p-type, depletion-mode behavior with a small amount of gate-controlled modulation of the channel conductance. This behavior is consistent with Hall measurements indicating a mobility of 17 cm²V⁻¹s⁻¹ and hole...
This dissertation demonstrated that the electrical properties of complex oxide-based perovskite materials could be controlled through the careful modification of both material composition and structure. This was first shown through the modification of lead zirconate titanate (Pb(Zr0.52Ti0.48)O3, PZT) solid solutions with bismuth indate (BiInO3, BI) where the relative stability of...
Marine diatoms are unicellular photosynthetic organisms that produce unique nanomaterials, energy dense lipid-molecules, and specialty carbohydrate molecules that can be all extracted from a single microorganism. The centric marine diatom Cyclotella sp. was used as a model organism for cultivation in a biorefinery system, where multiple co-products can be harvested...
Polyoxometalates are discrete anionic oxo clusters of the Group V and VI transition metals that can be conceptualized as molecular metal oxides. Because they are pairable with any alkali cation, a great deal of fundamental chemistry can be gleaned from their study, including solubility trends and insight into cation binding...
In this dissertation, I describe the experimental investigation in electron diffraction of molecules in superfluid helium droplets. The project is part of an overall scheme called ‘single molecule serial electron diffraction imaging’ (SS-EDI), with the ultimate goal of building an apparatus to determine atomic structures from oriented macromolecules. In SS-EDI,...
As the CMOS process scales down to submicron, digital circuit performance improves, while reduced supply voltage and lower transistor intrinsic gain make it difficult to implement analog circuits in a power efficient manner. Therefore, it has become advantageous to shift more analog signal processing functions conventionally realized in voltage (analog)...
Recent sensor System-on-Chips (SoC) have enabled significant advances in energy-efficiency by incorporating various micro-powered building blocks. Unfortunately, most of these sensor systems do not address the high power cost associated with data storage and transmission, which in some cases vastly exceeds the power consumed by the rest of the SoC....
Polyoxometalates are a rapidly growing class of discrete metal oxide clusters with a wide range of applications including functional materials. These anionic clusters of the group V and VI transition metals are inexpensive and non-toxic. Within group V polyoxometalates, niobium and tantalum chemistry has been underdeveloped owing to their unique...
The aim of this research is to develop a fundamental understanding of the dominant defect species and the relevant defect equilibrium conditions for bismuth-containing perovskites to help guide the development of these materials for emerging applications. This is of paramount importance for many demanding applications, because ultimately the defect equilibria...
Domesticated cats frequently use their sense of smell to navigate their environment, convey social cues, and communicate with other individuals. In applied contexts, cat owners are often encouraged to leave items holding their scent with their cat in periods of absence with the aim of reducing stress. The purpose of...
Racial/ethnic discrimination and HIV/AIDS conspiracy beliefs may contribute to disparities in use and satisfaction with healthcare services and engaging in safer sex practices. Previous studies that examined racial/ethnic discrimination and HIV/AIDS conspiracy beliefs focused primarily on African Americans with few studies focusing on Latinos. This study used longitudinal data from...
Millions of acres of rangeland in the western U.S. is shared habitat by elk (Cervus canadensis), mule deer (Odocoileus hemionus), and cattle (Bos taurus). Potential competition between these ungulates for the same forage species can be understood from their diet composition. I used DNA metabarcoding methods with trnL primers to...
The scale of pest and disease dispersal is often larger than the scale of individual farms. Therefore, an individual grower’s response to pests and diseases can affect and is affected by their surrounding growing region. Individual growers are also not isolated, and engage in various forms of information gathering, sharing,...