Solvent free microwave extraction (SFME) has been demonstrated to be feasible in extraction of essential oils from botanical materials. The benefits are no need for any solvent aside from the water naturally in the botanical material and a significant reduction in environmental impact for large scale production processes. However, the...
This thesis summarizes an investigation into the need for removing extractives
from herbaceous biomass feedstocks prior to their chemical characterization. Switchgrass
(Panicum virgatum), was used in this study as a representative herbaceous biomass
feedstock. The influence of extractives on the chemical analysis of switchgrass was done
by comparing the composition...
Using phenolic scavengers different methods were examined to determine the optimum conditions for extracting polyphenol oxidase (PPO) from d'Anjou pears. Efficiency of the extraction was evaluated based on browning of the extract, PPO activity per g of pear tissue, absorption scan of 410 nm to -240 nm, and the isozyme...
The amine extraction process is evaluated for pulse column
operation. A 0.1 M solution of Primene JM-T (a commercial mixture
of tertiary-alkyl primary amines) in a kerosene-base diluent is
the extractant for thorium feed in aqueous acidic sulfate solutions.
Equilibrium isotherms at room temperature are presented at
aqueous acidities of...
The extraction of tantalum fluoride complexes by large cationic
extractants (tetraphenylarsonium ion, TPA, and crystal violet) and
by methyl isobutyl ketone (MIBK) has been investigated as a function
of fluoride concentration using ¹⁸² Ta as tracer. Extractions by the
cationic extractants into chloroform were carried out in the absence
of...
Manual and automatic solvent extraction techniques were used
to concentrate organic material from natural waters. Field and
laboratory extractions were compared to determine the most probable
method and best solvents for efficient concentration of organic
material from estuarine and sea waters.
The large scale extraction processes utilizing extractors made
from...
Columbia River sediment was irradiated with ultraviolet light to
determine if organic material could be removed without altering the
sorptive properties of the hydrous oxides of iron and manganese.
A laboratory preparation of Zn-65 spiked hydrous ferric oxide
was subjected to ultraviolet irradiation in order to assess the photochemical
effect...
Spent nuclear fuel (SNF) resultant from the generation of nuclear power is a chemically and radiologically diverse system which is advantageous to chemically process prior to geologic disposal. Hydrometallurgy is the primary technology for chemical processing for light water reactor spent fuels, where spent fuel is dissolved in an acid...
The development of microfluidic devices for heavy metal extraction is presented in this dissertation. Various research areas, covering subjects from photochromic compound syntheses to microchip fabrication techniques are explored to develop microfluidic devices capable of extracting heavy metal ions from drinking water. Through integration of the beneficial characteristics of both...
The development of micro total analysis systems (µTAS), also called “lab-on-a-chip”, or microfluidic analysis systems, is presented in this dissertation. Various research areas, covering subjects from magnetic particles synthesis to novel microchip fabrication techniques, are explored to develop a lab-on-a-chip system capable of performing magnetic bead-based bioassays. These devices are...
The objectives of this research were to investigate the optimal conditions for anthocyanins extraction from different anthocyanin rich fruit and to develop microencapsulation formulation for improving stability of anthocyanin extracts. In the extraction optimization study, two extraction methods, "conventional solvent extraction (CE)" and "ultrasound-assisted extraction (UE)" for three different anthocyanin-rich...
Continuous liquid-liquid two-phase separation is needed in microfluidic devices. Due to the small characteristic lengths of microreactors, phenomena such as mass transport via molecular diffusion occur within seconds. Typically, discrete slugs of an extract are created within microchannels for high specific interfacial area to achieve intensified mass transfer. A challenge...
Analytical chemistry is an essential qualitative and quantitative tool to describe foods and biomaterials and their changes during production, processing and distribution. In this work, rapid analytical procedures for the extraction and quantification of components in fluid milk and diatom fermentation broth were developed. Analytical methods to measure the concentration...
In-situ vapor extraction is performed by applying a pressure differential across a hydrophobic porous membrane that forms a wall of the channel as a means of reducing the local quality of flow boiling within the channel. As the local quality is reduced, the heat transfer capability can be improve while...