Air–sea coupling during coastal upwelling was examined through idealized three-dimensional numerical simulations with a coupled atmosphere–ocean mesoscale model. Geometry, topography, and initial and
boundary conditions were chosen to be representative of summertime coastal conditions off the Oregon coast. Over the 72-h simulations, sea surface temperatures were reduced several degrees near...
The solid solutions of InGa₁₋ₓFeₓCuO₄, InFeCu₁₋ₓMgₓO₄, and InGa₁₋ₓFeₓCu₁₋ₓMgₓO₄ were
synthesized and characterized through the use of X – ray and neutron diffraction, and DC –
magnetism measurements. All compositions of InGa₁₋ₓFeₓCuO₄ are single phase and crystallize
in the R3m space group, but a transformation to the spinel InFeMgO₄ structure was...
Includes general information about journal costs and costs of commercial versus society publications. Spreadsheet represents the journals in which faculty in the Chemistry Department most often publish and includes journal title, cost, impact factor, publisher, and information about whether the journal is published by a scholarly society or a for-profit...
Mapping out multidimensional potential energy surfaces has been a goal of
physical chemistry for decades in the quest to both predict and control chemical
reactivity. Recently a new spectroscopic approach called Femtosecond Stimulated Raman
Spectroscopy or FSRS was introduced that can structurally interrogate multiple
dimensions of a reactive potential energy...
The effect of quasi-hydrostatic pressure upon the ferromagnetic ground state of magnetodielectric, double-
perovskite La₂ MnNiO₆ is investigated using x-ray absorption spectroscopy and diffraction measurements in a
diamond anvil cell. The Mn-O-Ni superexchange interaction that gives rise to ferromagnetism in this cation-
ordered structure is stable to at least 38...
Background: There is a long-term interest in running the fission reaction backward, i.e., studying the "inverse fission" of uranium. The recent availability of beams of n-rich fission fragments has stimulated interest in this endeavor.
Purpose: To search for inverse fission in the reactions Sn-¹²⁴,Sn-¹3² + Mo-¹⁰⁰.
Method: In the Sn-¹²⁴...
We report an experimental and theoretical study of single-molecule inner-shell photoemission measured over an extended range of photon energies. The vibrational intensity ratios I (nu = 1)/I (nu = 0) from the C 1s photoelectron spectra of carbon monoxide, although mostly determined by the bond length change upon ionization, are...
Fusion excitation functions for the reactions of Sn-¹²⁴,Sn-¹³² with Ca-⁴⁰,Ca-⁴⁸ were measured at energies near and below the Coulomb barrier. Weak sub-barrier fusion enhancement accounted for by coupling to the first 2(+) and 3(-) states in the target and projectile was observed for Sn-¹²⁴,Sn-¹³² + Ca-⁴⁸. However, the Sn-¹²⁴,Sn-¹³² +...
X-ray photoemission spectroscopy is used in a great variety of research fields; one observable is the sample's stoichiometry. The stoichiometry can be deduced based on the expectation that the ionization cross sections for innershell orbitals are independent of the molecular composition. Here we used chlorine-substituted ethanes in the gas phase...
Three general types of swimbladders were found in the eight species of myctophids studied: gas-filled, fat-invested, and atrophied or reduced. Small specimens of all species had thin-walled, gas-filled swimbladders. Large specimens of Stenobrachius leucopsarus had fat-invested swim-bladders and large Diaphus theta had either gas-filled or atrophied swimbladders, as found by...
Abstract: Background: The cross section for forming a heavy evaporation residue in fusion reactions depends on the capture cross section, the fusion probability, P[subscript CN], i.e., the probability that the projectile-target system will evolve inside the fission saddle point to form a completely fused system rather than reseparating (quasifission), and...
The performance of an over 10 times larger microbial fuel cell (MFC) with double cloth electrode assembly (CEA) during 63 days of continuous operation demonstrates that the excellent performance of CEA-MFC can be further improved during scale-up. With a new separator material and U-shaped current collectors, the larger MFC produced...
We have studied the fission-neutron emission competition in highly excited ²⁷⁴Hs (Z = 108) (where the
fission barrier is due to shell effects) formed by a hot fusion reaction. Matching cross bombardments
(²⁶Mg + ²⁴⁸Cm and ²⁵Mg + ²⁴⁸Cm) were used to identify the properties of first chance fission of...
Over a 3.5-year period, 4 Rocky Mountain goats (Oreamnos americanus), housed at a single facility, developed clinical disease attributed to infection by Caprine arthritis encephalitis virus (CAEV). Ages ranged from 1 to 10 years. Three of the goats, a 1-year-old female, a 2-year-old male, and a 5-year-old male, had been...
While the d⁰ transition-metal POMs of Group V (V⁵⁺, Nb⁵⁺, Ta⁵⁺) and Group VI (Mo⁶⁺, W⁶⁺) have been known for more than a century, the actinyl peroxide POMs, specifically those built of uranyl triperoxide or uranyl dihydroxidediperoxide polyhedra, were only realized within the last decade. While virtually every metal on...
We, for the first time, employ magnesiothermic reaction to convert microwave-irradiated graphite oxide to pure graphene. The magnesiothermic reaction raises the carbon to oxygen atomic ratio from 22.2 to 165.7 and maintains a high surface area. The new strategy demonstrates an efficient method for obtaining highly pure graphene materials.
Assembly of nanocrystals is considered one of the most promising approaches to design nano-, microstructures, and complex mesoscopic architectures. A variety of strategies to induce nanocrystal assembly have been reported, including directed assembly methods that apply external forces to fabricate assembled structures. In this study ZnO nanocrystals were synthesized in...
The aggregation of 12 nm citrate-stabilized gold nanoparticles (cit-AuNPs) in the presence of four
different natural organic matter (NOM) isolates and a monovalent electrolyte (KCl) was evaluated using
time-resolved dynamic light scattering. All four NOM isolates stabilized the cit-AuNPs with respect to
aggregation. However, specific effects varied among the different...
There is increasing evidence that aging is affected by biological (circadian) clocks – the internal mechanisms that coordinate daily changes in gene expression, physiological functions and behavior with external day/night cycles. Recent data suggest that disruption of the mammalian circadian clock results in accelerated aging and increased age‐related pathologies such...
A series of combined measurements was made at the Naval Air Station North Island (NASNI) Installation Restoration Site 5, Unit 2 during July and August 2013. Combined measurements included CO₂ respiration rate, CO₂ radiocarbon content to estimate chlorinated hydrocarbon (CH) mineralization and a zone of influence (ZOI) model. CO₂ was...
Carbon 1s photoelectron asymmetry parameters β for the chlorinated and the methyl carbon atom of CH₃CH₂Cl, CH₃CHCl₂, and CH₃CCl₃ have been measured using synchrotron radiation in the 340-600 eV energy range. We provide experimental evidence that the intramolecular scattering strongly affects beta values, even far from the ionization threshold. The...
A central goal of green chemistry is to avoid hazard in the design of new chemicals. This objective is best achieved when information about a chemical's potential hazardous effects is obtained as early in the design process as feasible. Endocrine disruption is a type of hazard that to date has...
In 1959 the British Ornithological journal, The Ibis, published a centenary commemorative volume on the history of ornithology in Britain. Over the previous few decades, the contributors to this volume had helped focus the attention of ornithologists on the methods, priorities, and problems of modem biology, specifically the theory ofevolution...
The yields of over 200 projectile-like fragments (PLFs) and target-like fragments (TLFs) from the interaction of (E[subscript]c.m.=450 MeV) Xe¹³⁶ with a thick target of Pb²⁰⁸ were measured using Gammasphere and off-line γ-ray spectroscopy, giving a comprehensive picture of the production cross sections in this reaction. The measured yields were compared...
Background: Multinucleon transfer reactions have recently attracted attention as a possible path to the synthesis of new neutron-rich heavy nuclei.
Purpose: We study transfer reactions involving massive nuclei with the intention of understanding if the semi-classical model GRAZING coupled to an evaporation and fission competition model can satisfactorily reproduce experimental...
The effect of the Coriolis interaction upon the sharing of energy between rotational and vibrational excitation
during an electronic transition is considered with particular emphasis on recoil-induced excitation during
photoionization. If there is a large change in equilibrium bond length upon ionization, then Coriolis coupling
leads to a significant transfer...
Although much has been written describing the
various reactions to the origin of Species in America, the Mormon reaction to Darwinism has been largely ignored. This dissertation will recount the history of this reaction as exemplified by the life and works of B. H. Roberts. Roberts's intellectual pursuits early in...