The ternary system (Bi₀.₅Na₀.₅)TiO₃-(Bi₀.₅K₀.₅)TiO₃-Bi(Mg₀.₅Ti₀.₅)O₃ (BNT-BKT-BMgT) was explored along the [75-(x 2) ]Bi₀.₅Na₀.₅TiO₃ - [25-(x 2)]Bi₀.₅K₀.₅TiO₃ - [x]Bi(Mg₀.₅Ti₀.₅)O₃ composition line. Thin films were fabricated using chelated mixing route solutions spin cast onto platinized silicon substrates. Processing parameters such as: excess cation molar%, solution molality, and crystallization temperatures, for composition where x=0,...
Domesticated cats frequently use their sense of smell to navigate their environment, convey social cues, and communicate with other individuals. In applied contexts, cat owners are often encouraged to leave items holding their scent with their cat in periods of absence with the aim of reducing stress. The purpose of...
Polyoxometalates are discrete anionic oxo clusters of the Group V and VI transition metals that can be conceptualized as molecular metal oxides. Because they are pairable with any alkali cation, a great deal of fundamental chemistry can be gleaned from their study, including solubility trends and insight into cation binding...
As the CMOS process scales down to submicron, digital circuit performance improves, while reduced supply voltage and lower transistor intrinsic gain make it difficult to implement analog circuits in a power efficient manner. Therefore, it has become advantageous to shift more analog signal processing functions conventionally realized in voltage (analog)...
Marine diatoms are unicellular photosynthetic organisms that produce unique nanomaterials, energy dense lipid-molecules, and specialty carbohydrate molecules that can be all extracted from a single microorganism. The centric marine diatom Cyclotella sp. was used as a model organism for cultivation in a biorefinery system, where multiple co-products can be harvested...
The scale of pest and disease dispersal is often larger than the scale of individual farms. Therefore, an individual grower’s response to pests and diseases can affect and is affected by their surrounding growing region. Individual growers are also not isolated, and engage in various forms of information gathering, sharing,...
The focus of this thesis is developing materials for thin-film transistors (TFTs). Cu₃SbS₄ is explored as p-channel layer. Cu₃SbS₄ TFTs show p-type, depletion-mode behavior with a small amount of gate-controlled modulation of the channel conductance. This behavior is consistent with Hall measurements indicating a mobility of 17 cm²V⁻¹s⁻¹ and hole...
Polyoxometalates are a rapidly growing class of discrete metal oxide clusters with a wide range of applications including functional materials. These anionic clusters of the group V and VI transition metals are inexpensive and non-toxic. Within group V polyoxometalates, niobium and tantalum chemistry has been underdeveloped owing to their unique...
Racial/ethnic discrimination and HIV/AIDS conspiracy beliefs may contribute to disparities in use and satisfaction with healthcare services and engaging in safer sex practices. Previous studies that examined racial/ethnic discrimination and HIV/AIDS conspiracy beliefs focused primarily on African Americans with few studies focusing on Latinos. This study used longitudinal data from...
In this dissertation, I describe the experimental investigation in electron diffraction of molecules in superfluid helium droplets. The project is part of an overall scheme called ‘single molecule serial electron diffraction imaging’ (SS-EDI), with the ultimate goal of building an apparatus to determine atomic structures from oriented macromolecules. In SS-EDI,...