Metal and hydrogen ion acidity and extreme nitrate concentrations typical of
Department of Energy (DOE) legacy waste sites pose formidable challenges to
successful implementation of in situ bio-immobilization. Intermediate-scale (~ 2.5 m),
flow through models of an in situ bio-barrier were constructed to investigate U and Tc
removal from groundwater...
This research focused on the enhanced reductive dechlorination of trichloroethene (TCE) and its surrogate, trichlorofluoroethene (TCFE), using two bioremediation methods in anaerobic conditions. Two anaerobic bioremediation studies were conducted to investigate the effects of microbial communities in the presence of different electron acceptors and donors during anaerobic reductive dechlorination of...
Chlorinated aliphatic hydrocarbons (CAHs) such as vinyl chloride (VC) and 1,-2 dichioroethane (DCA), are wide-spread groundwater pollutants found at many contaminated field sites around the world. Quantitative tools are needed to determine the in situ rates of VC and DCA transformation to ethene in contaminated groundwater. The objective of this...
The transformation of 1,1,1 -trichioroethane (1,1,1 -TCA) and 1,1 -dichioroethene (1,1 -
DCE) was evaluated in a continuous flow column reactor using a mixed culture that grew
on butane. The column was packed with aquifer materials and groundwater obtained
from the in-situ bioremediation test site at Moffett Field, CA. The...
Aquifers are an important storage location and source of fresh groundwater. They may become polluted by a number of contaminants including mobile divalent radionuclides such as strontium-90 which is a byproduct of uranium fission. A method for remediating such divalent radionuclides is sequestration through co-precipitation into calcium carbonate. Calcium carbonate...
Halogenated organic compounds have had widespread and massive applications in industry, agriculture, and private households, for example, as degreasing solvents, flame retardants and in polymer production. They are released to the environment through both anthropogenic and natural sources. The most common chlorinated solvents present as contaminants include tetrachloroethene (PCE, perchloroethene)...
Groundwater at Oak Ridge National Laboratory's Field Research Center (FRC) is contaminated with U(VI) and Tc(VII), has pH values as low as 3.3, and nitrate concentrations as high as 120 mM. The objective of this research was to determine if in-situ bio-immobilization is a viable treatment alternative for this water....
A pilot scale demonstration of a biological permeable barrier was conducted in a pentachlorophenol-contaminated aquifer at a wood preserving facility. A permeable reactor was constructed to fit within a
large diameter well. Arranged in series, a cylindrical reactor 24" x 36" (0.61 x 0.91m) (diameter x height)
was partitioned to...