At Site-300, Lawrence Livermore National Laboratory (LLNL), CA,
trichloroethene (TCE) is present along with tetraalkoxysilanes such as tetrabutoxysilane
(TBOS) and tetrakis(2-ethylbutoxy) silane (TKEBS), as subsurface contaminants.
Intrinsic transformation of TCE to cis-dichloroethene (c-DCE) was observed in the
groundwater at locations co-contaminated with TBOS or TKEBS. Attenuation of TBOS
and TKEBS...
The transformation of 1,1,1 -trichioroethane (1,1,1 -TCA) and 1,1 -dichioroethene (1,1 -
DCE) was evaluated in a continuous flow column reactor using a mixed culture that grew
on butane. The column was packed with aquifer materials and groundwater obtained
from the in-situ bioremediation test site at Moffett Field, CA. The...
Batch microcosm studies were carried out to screen for microorganisms from the
subsurface of Hanford DOE site that could cometabolically transform chloroform (CF)
under aerobic conditions. The potential need for CF bioremediation at the Hanford site
has resulted from the large release of carbon tetrachloride (CT) to the subsurface, of...
This research focused on the enhanced reductive dechlorination of trichloroethene (TCE) and its surrogate, trichlorofluoroethene (TCFE), using two bioremediation methods in anaerobic conditions. Two anaerobic bioremediation studies were conducted to investigate the effects of microbial communities in the presence of different electron acceptors and donors during anaerobic reductive dechlorination of...
Aquifers are an important storage location and source of fresh groundwater. They may become polluted by a number of contaminants including mobile divalent radionuclides such as strontium-90 which is a byproduct of uranium fission. A method for remediating such divalent radionuclides is sequestration through co-precipitation into calcium carbonate. Calcium carbonate...
A pilot scale demonstration of a biological permeable barrier was conducted in a pentachlorophenol-contaminated aquifer at a wood preserving facility. A permeable reactor was constructed to fit within a
large diameter well. Arranged in series, a cylindrical reactor 24" x 36" (0.61 x 0.91m) (diameter x height)
was partitioned to...
In situ bioremediation of pentachlorophenol-contaminated ground water in a sequential anaerobic-aerobic down borehole permeable barrier reactor requires a non-toxic primary substrate for dichlorophenol cometabolism. Serum bottle tests comparing the effectiveness of eight primary substrates for aerobic dichlorophenol degradation showed phenol to be the most effective followed by imitation vanilla flavoring,...
Groundwater resources have become seriously threatened
due to improper use by industrial, municipal, and even public
sectors. Widespread contamination of aquifer systems has
jeopardized human health and the environment and methods for
restoring these systems are needed. Biological and chemical
in situ remediation, where contaminants are degraded within
the natural...