In the most challenging nuclear power plant accidents, transient critical heat flux (CHF) is a primary phenomenon that drives peak cladding temperature and ultimately fuel failure. It is not yet determined whether the use of steady-state CHF methods can accurately predict transient CHF under the conditions of a blowdown due...
A molecular approach to metal oxides allows to the study to fundamental bonding and formation behavior for such metals. Moreover, the molecular nature of such oxides or metal-oxo clusters allows the possibility of exploitation of the properties of the parent oxides. The tetravalent metals, in specific, (M=Zr, Hf, Ce, Th,...
This dissertation presents a study of structure-property relationships within 3d/4d metal oxides containing precious metals through detailed structure refinements using high-resolution neutron and X-ray diffraction data along with exploration of the resultant properties.
Oxides of 4d or 5d transition metals tend to show new topological phases due to significant spin-orbit...
Solid state inorganic oxides play an important role in next generation electronics based on their stability, versatility, and enhanced properties over other materials. However, in order to design or tune these materials for a desired functionality it is necessary to fully understand the structure behind the properties exhibited. This dissertation...
Understanding structural evolution in solids as composition changes is essential to materials properties prediction. Such structure-properties relationships are the theme of solid state chemistry. Materials scientists and chemists have utilized an abundance of simple crystal structures to enhance understanding of chemical and structural origins of properties in materials for decades....
Due to the high cost of precursor materials, complex oxides of 4d and 5d transition metals are under-studied compared to their 3d counterparts. Recent studies have shown that oxides containing heavier transition metals can exhibit exotic electronic states due to presence of strong spin-orbit coupling. The goal of this dissertation...
A dual-mode engine has been developed where in one mode all engine cylinders fire normally, providing locomotion for the vehicle. In the other mode, one cylinder of the engine is used to compress low pressure residential natural gas (NG), in multiple stages, to a standard U.S. compressed natural gas (CNG)...
Given the current abundant supply and cheap price of natural gas (NG) in the United States, there is a significant opportunity to use this fuel for transportation. However, there are few fueling stations for consumers. To address this need, a dual-mode engine has been developed where in one mode all...